• 한국주조공학회지
• /
• 제15권2호
• /
• pp.184-193
• /
• 1995

Effects of process parameters during thixocasting, such as solid volume fraction, mold temperature and extrusion ratio, on the mold filling behaviour and fluidity of Mg alloy(AZ91D) have been investigated. The semi-solid ingot held for 60 minutes at the semi-solid temperature range did not contain the equilibrium volume fraction of solid as expected from the phase diagram. Therefore, in order to obtain the desired solid fractions, and to suppress the exaggerated grain growth during heating, it was required to heat the ingot rapidly up to the temperature $10^{\circ}C$ higher than the semi-solid temperature suggested from the phase diagram for a specific volume fraction of solid. The experimental results show that mold filling behaviour and fluidity can be improved with the use of the higher mold temperature and the lower volume fraction of solid, but remain nearly unaffected by the change of extrusion ratio.

• 오토저널
• /
• 제5권1호
• /
• pp.79-88
• /
• 1983

A prediction of emission concentrations was made by calculating chemical equilibrium on the basis of an indicated pressure diagram in spark ignition engine using methanol as a fuel. A prediction according to Otto cycle was also made and for carbon dioxide, carbon monoxide and nitric oxide, emission test was performed using a conventional SI engine that was modified a little considering fuel characteristics. An investigation was made for those three cases-results from an indicated pressure diagram, Otto cycle and emission test. A good agreement between the measured values and the predicted ones existed for carbon dioxide and carbon monoxide, but not for nitric oxide. And good results existed for the other emission concentrations.

• Transactions on Electrical and Electronic Materials
• /
• 제7권3호
• /
• pp.108-111
• /
• 2006

The oxidizer-induced corrosion state and microstructure of surface passive metal-oxide layer greatly influenced on the removal rate of tungsten film according to the slurry chemical composition of different mixed oxidizers. In this paper, the actual polishing mechanism and pH-potential equilibrium diagram obtained from potentiodynamic polarization curve were electrochemically compared. An electrochemical corrosion effect implies that slurries with the highest removal rate (RR) have the high dissolution rate.

• 한국식품영양과학회지
• /
• 제27권5호
• /
• pp.1019-1025
• /
• 1998

Proteins and polysaccharides are major food macromolecules. Generally, the mixture of these macromolecules can be separated into two phases because of their thermodynamic incompatibility. Phase separ-ation is explained by equilibrium phase diagram, which comprises binodal curve, critical point, phase separation threshold, tie-line and rectilinear diameter. Phase separation of protein-polysacc-haride solution is affected by pH, temperature, ionic strength, molecular weight, molecular structure, etc. Membraneless osmosis has been developed to concentrate protein solutions, using the phase diagram constituted by proteins and polysaccharides. Protein-polysaccharide mixtures are very promising fat mimetics because solution of mixtures forms water-continuous system with two phase-separated gels, which give plastic texture and a fatty mouthfeel.

• 대한기계학회:학술대회논문집
• /
• 대한기계학회 2004년도 추계학술대회
• /
• pp.649-654
• /
• 2004

A physically simple but mathematically cumbrous problem of rotating heavy chain with one fixed top point is studied. Nonlinear equation of its two-dimensional shapes of relative equilibrium is obtained and solved numerically. A linear case of small displacements is analyzed in terms of Bessel functions. The qualitative and quantitative behavior of the problem is discussed with the help of bifurcation diagram. Dynamics of the two-dimensional model near the equilibrium positions is studied with the help of simulation using the absolute nodal coordinate formulation (ANCF). The equilibriums are found instable, and the reason of instability is explained using a variational principle.

• 천문학회보
• /
• 제3권
• /
• pp.18-23
• /
• 1978

The evolutionary tracks of a protostar of one solar mass under quasi-hydrostatic equilibrium are computed with mass-accretion time scales of $10^3,\;10^4,\;10^5\;and\;10^6$ years, and their resulting behaviors in the H-R diagram are discussed. It is found that there exists a critical time scale of mass accretion, which reverses the course of their evolutionary tracks. A value of the critical time scale appears to lie between $10^3\;and\;10^4$ years. The physical cause for the presence of the critical time scale is discussed. Finally, it is proposed that star formation requires at least several $10^3$ years before any star is born out of dark dense interstellar clouds.

• Bulletin of the Korean Chemical Society
• /
• 제23권6호
• /
• pp.811-817
• /
• 2002

Gibbs ensemble Monte Carlo simulations were performed to calculate the vapor-liquid coexistence properties for the binary mixtures $CO_2/CH_3OH$, $CO_2/C_2H_5OH$, and $CO_2/CH_3CH_2CH_2OH.$ The configurational bias Monte Carlo method was used in the simulation of alcohol. Density of the mixture, composition of the mixture, the pressure-composition diagram, and the radial distribution function were calculated at vapor-liquid equilibrium. The composition and the density of both vapor and liquid from simulation agree considerably well with the experimental values over a wide range of pressures. The radial distribution functions in the liquid mixtures show that $CO_2$ molecules interact more stogly with methyl group than methylene group of $C_2H_5OH$ and $CH_3CH_2CH_2OH$ due to the steric effects of the alcohol molecules.

• Macromolecular Research
• /
• 제11권1호
• /
• pp.53-61
• /
• 2003

A molecular-thermodynamic model is developed for the salt-induced protein precipitation. The protein molecules interact through four intermolecular potentials. An equation of state is derived based on the statistical mechanical perturbation theory with the modified Chiew's equation for the fluid phase, Young's equation for the solid phase as the reference system and a perturbation based on the protein-protein effective two body potential. The equation of state provides an expression for the chemical potential of the protein. In a single protein system, the phase separation is represented by fluid-fluid equilibria. The precipitation behaviors are simulated with the partition coefficient at various salt concentrations and degree of pre-aggregation effect for the protein particles. In a binary protein system, we regard the system as a fluid-solid phase equilibrium. At equilibrium, we compute the reduced osmotic pressure-composition diagram in the diverse protein size difference and salt concentrations.

• Korea-Australia Rheology Journal
• /
• 제18권2호
• /
• pp.99-102
• /
• 2006

Primitive chain network model for block copolymers is used here to simulate molecular dynamics in the entangled state with acceptable computational cost. It was found that i) the hooking procedure rearranging the topology of the entangled network is critical for the equilibrium structure of the system, and ii) simulations accounting for the different chemistry, i.e., with a biased hooking probability based on interaction parameter ${\chi}$ for selection of the hooked partner, generates a reasonable phase diagram.

• 정보저장시스템학회:학술대회논문집
• /
• 정보저장시스템학회 2005년도 추계학술대회 논문집
• /
• pp.177-178
• /
• 2005

The load/unload behavior of the hard disk drive slider is studied in terms of the air bearing static characteristics. The numerical continuation methods are applied to calculate suspension force - equilibrium position curve. The critical preloads of the femto size slider are analyzed. The hi-stability conditions are depicted on the skew angle - preload diagram. The perturbation method is used to check the stability of the solution branches.