• Polymer(Korea)
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• v.39 no.3
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• pp.426-432
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• 2015

Poly(ether sulfone) (PES) embedded diglycidylether of bisphenol-A (DGEBA) epoxy composites were fabricated for improving its mechanical properties and thermal stability. The mechanical properties such as tensile, flexural and impact strength of the composites changed significantly with the introduction of PES. The value of the fracture toughness of this composite also was increased remarkably about 24%. Thermal stability of PES/epoxy composites also improved 12%, which was calculated with integral procedural decomposition temperature (IPDT). From the differential scanning calorimeter (DSC) result, the curing temperature and curing heat decreased according to the increase of PES contents. These were attributed to the good distribution and the formation of the semi-interpenetrating polymer networks (semi-IPNs) composed of the epoxy network and linear PES.

• Journal of the Korean Society for Railway
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• v.12 no.6
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• pp.1059-1066
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• 2009

Recently, the amount of thermosetting plastic wastes has increased with the production of reinforced plastic composites and causes serious environmental problems. The epoxy resins, one of the versatile thermosetting plastics with excellent properties, cannot be melted down and remolded as what is done in the thermoplastic industry. In this research, a series of experiments that decompose epoxy resin and recover carbon fibers from carbon fiber reinforced epoxy composites applied to railway vehicles was performed. We experimentally examined various decomposition processes and compared their decomposition efficiencies and mechanical property of recovered carbon fibers. For the prevention of tangle of recovered carbon fibers, each composites specimen was fixed with a Teflon supporter and no mechanical mixing was applied. Decomposition products were analyzed by scanning electron microscope (SEM), gas chromatography mass spectrometer (GC-MS), and universal testing machine (UTM). Carbon fibers could be completely recovered from decomposition process using nitric acid aqueous solution, liquid-phase thermal cracking and pyrolysis. The tensile strength losses of the recovered carbon fibers were less than 4%.

• Composites Research
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• v.23 no.2
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• pp.24-30
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• 2010

Interfacial evaluation and hydrophobicity of Ni-nanopowder/epoxy composites were investigated for self-sensing and actuation. Contact resistance and resistivity were measured using gradient micro-specimens. The actuation of the composites in the electromagnetic field was studied with three wave functions, i.e., sine, triangle and square functions. Due tothe presence of hydrophobic domains on the heterogeneous surface, the static contact angle of Ni-nanopowder/epoxy nanocomposite wasabout $100^{\circ}$, which was rather lower than that for super-hydrophobicity. The dynamic contact angle showed the similar trend of static contact angle. Ni-nanopowder/epoxy composite was responded wellfor both self-sensing and actuation in electromagnetic field due to the intrinsic metal property of Ni-nanopowder. Displacement of the actuator of Ni-nanopowder/epoxy composite was evaluated to obtain the maximum and the optimum performance using laser displacement sensor as functions of the wave type, frequency, and voltage. Actuation of Ni-nanopowder/epoxy composites also increased as functions of applied frequency and voltage. Actuated strain increased more rapidly at sine wave with increasing voltage compared to those of triangle or rectangular waves.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2001.10a
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• pp.724-728
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• 2001

In this study, the dielectric breakdown of epoxy composites used for transformers was experimented and then its data were simulated by Weibull distribution probability. The dielectric breakdown characteristics origin in epoxy composites were examined and various effects of dielectric breakdown on epoxy composites were also discussed. As a result, first of all, speaking of dielectric breakdown properties, the more hardener increased the stronger breakdown strength at low temperature because of cross-linked density by the virtue of ester radical. And the breakdown strength of specimens with filler was lower than it of non-filler specimens because it is believed that the adding filler forms interface and charge is accumulated in it, therefore the molecular motility is raised, the electric field is concentrated, and the acceleration of electron and the growth of electron avalanche are early accomplished. In the case of filled specimens with treating silane, the breakdown strength become much higher since this suggests that silane coupling agent improves interfacial combination and relaxs electric field concentration. Finally, from the analysis of weibull distribution, it was confirmed that as the allowed breakdown probability was given by 0.1%, the applied field value needed to be under 21.5㎹/cm.

• Elastomers and Composites
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• v.45 no.1
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• pp.12-16
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• 2010

In this work, the effect of hydrophobic treated silica on the water absorption, thermal stabilities, and mechanical properties of the epoxy nanocomposites were investigated as a function of the silica content. As filler, fumed silica treated by dimethyldichlorosilane was used. It was found that the silica was well dispersed in the epoxy resins by the melt-mixing method with the addition of a silane coupling agent. The water absorption of the nanocomposites decreased with an increase of the silica content due to the effect of hydrophobic treated silica. The thermal properties, such as thermal degradation temperature, glass transition temperature ($T_g$), and coefficient of thermal expansion (CTE), of the nanocomposites were improved by the addition of silica. Furthermore, the mechanical properties of the nanocomposites, that is, the tensile strength and modulus, were enhanced with increasing silica content. This was attributed to the physically strong interaction between silica and epoxy resins.

• Journal of the Korean Applied Science and Technology
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• v.35 no.3
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• pp.676-682
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• 2018

In order to study electrical properties of epoxy composites with various frequency. To measure of dielectric characteristics have been performed over a frequency range from 30[Hz] to 3[MHz] and a temperature range of $20[^{\circ}C]$, $100[^{\circ}C]$, $140[^{\circ}C]$. We observed values of dielectric constant and dissipation of the epoxy composites with various frequency. We were observed dielectric loss and dispersion in low frequency region. Also, we observed to decrease of the dielectric constant due to the effects of filler in high temperature region.

• Journal of the Korean Society of Propulsion Engineers
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• v.21 no.2
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• pp.32-40
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• 2017

In this study, the procedures for quantitative measurement of void contents of carbon fiber/epoxy composites were suggested. Two types of the composites were considered: autoclave cured composite and filament wound composite. Void contents of the composites were evaluated by the density of the composites and their constituents, which was determined from weights in the air and water, and the weight fraction and volume fraction of the constituents obtained from the digestion method and combustion method. The surfaces of filtered carbon fibers were examined by FE-SEM in order to investigate the validity of resin removal from the composites. According to the results, the resin in the composites could be fully removed by the digestion method and combustion method. Therefore, the weight fraction and volume fraction of the constituents, and void content of the composites could be quantitatively obtained by the suggested procedures.

• Transactions of the Korean Society of Mechanical Engineers
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• v.14 no.1
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• pp.37-42
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• 1990

Carbon fiber epoxy composite materials are widely used in the structures of aircrafts, robots and other machines because of their high specific stiffness, high specific strength and damping. In order for the composite materials to be used in the robot structure or machine element, bearing mounting and joining surfaces must be provided, which require accurate machining. In this paper, the machinability and tool wear characteristics of the milling operation of the carbon fiber epoxy composite materials were experimentally measured. The tool wear mechanism and the Taylor tool wear constants were determined. Also, the surface roughness of milling operation was measured w.r.t. cutting speed and feed.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.84-84
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• 2010

Nano particles (10nm SiO2) were silane-treated in order to modify the surface characteristics in a epoxy nanocomposite. Then. micro particles ($3{\mu}m$ SiO2) were poured into the epoxy nanocomposite using various mixing process and epoxy/ micro-and-nano- mixed composites (EMNC) were prepared. The thermal (Tg) and mechanical (tensile and flexural strength) properties were measured by DMA and UTM and the data was estimated by Weibull plot.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2003.10a
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• pp.111-114
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• 2003

Thermosets are highly cross-linked polymers with a three-dimensional molecular structure. The network structure gives rise to mechanical properties, however, one major drawback of thermosets, which also results from their network structure, is their poor resistance to impact and to crack initiation. In this study, to solve this problem, the reactive thermoplastics such as amine terminated polyetherimide (ATPEI), ATPEI-CTBN-ATPEI(ABA) triblock copolymer, CTBN-ATPEI(AB) diblock copolymer, and carboxyl group modified ATPEI was synthesized, after that blended with epoxy resin, and the carbon fiber reinforced composites were fabricated. The impact load, energy, and delamination were investigated by using drop weight impact test and C-scan test. As a results, the ABA/epoxy blend system showed good impact properties.