• Title/Summary/Keyword: Epoxy composites

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A Study on the Crack Growth Behavior and Fracture Criterion of Glass/Epoxy Composites (Glass/Epoxy 복합재료의 파괴조건 및 균열진전거동)

  • 김정규;김도식
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.16 no.9
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    • pp.1681-1690
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    • 1992
  • The effects of the stress ratio and the fiber orientation(0.deg./90.deg. and .+-.45.deg.) to the load direction on the fracture behavior of the glass/epoxy plain woven composites were studied. The tests were carried out using compact tension specimens under both static and fatigue loading. The values of $k_{a}$ obtained from the energy release rate are independent of notch depth(a/w=0.2~0.6) for the 0.deg./90.deg. specimens, but decreases with an increase in a/w for the .+-.45.deg. specimens. And $k_{q}$ has higher values than $k_{ASTM}$ has been evaluated by the ASTM E399 test procedure. It is shown in the relation between fatigue crack growth rate da/dN and stress intensity factor range .DELTA.K using modified shape correction factor that da/dN decreases with a decrease in stress ratio and is lower for .+-..deg. specimens than for 0.deg./90.deg. These phenomena can be explained by the crack deflection to the load direction.n.n.

Effects of acid-anhydride hardener and postcuring heat-treatments on dielectric properties of epoxy composites (에폭시 복합체의 유전특성에 미치는 산무수물 경화제와 후경화 열처리의 영향)

  • 왕종배;이성일;이준웅
    • Electrical & Electronic Materials
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    • v.7 no.3
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    • pp.187-199
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    • 1994
  • In order to find an effect of structural changes due to variation of addition ratio of anhydride hardener and postcuring herat-treatments upon electrical properties of epoxy composites, the dielectric properties over a frequency range from 30[Hz] to l[MHz] were investigated in the temperature range of 20-180[.deg. C]. From the dielectric properties, the a peaks related with glass-transition phenomena of epoxy network appeared near 130[.deg. C], the conduction loss in high temperature region above 150[.deg. C] due to thermal dissociation of hardener started off with the low frequency side and the .betha. peak concerned with contribution of movable unreacted terminal epoxy groups and curing agents in the glass states concurred with the high-frequency side below 20[.deg. C]. And an effect of an hydride hardener upon structural changes and of postcuring heat treatments upon structural stability in epoxy composites would be explained through the estimation of the distribution of relaxation times and the activation energy for a .alpha. peak according to the WLF equations.

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Electrical and Mechanical Properties of Epoxy/Heterogeneous Inorganic Composites Materials for the Application of Electric Power GIS Appliances (친환경 GIS용 전력기기의 적용을 위한 에폭시 이종무기물 복합재료의 전기적, 기계적 특성)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.67 no.12
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    • pp.1633-1640
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    • 2018
  • Epoxy resin is a polar thermosetting polymer that is widely employed in different branches of industry and everyday life, due to their stable physical and chemical properties. Of all the polymer materials currently being used in the electrical insulation industry, epoxy resin is the most widely used kind, chosen as the base polymer material in the present study. Composites were prepared according to the mixing ratio (MS: MA, 1: 9, 3: 7, 5: 5, 7: 3, 9: 1)of mixture for Heterogeneous Minerals(Micro Silica:MS, Micro Alumina:MA) (MS+MA). We have investigated for AC electrical insulation breakdown characteristics and the dielectric properties (permittivity, dielectric loss, and conductivity) with frequency changes. The electrical AC insulation breakdown performance was improved with the increase of the mixing ratio of MS according to heterogeneous mineral material mixture(MS+MA). As Dielectric properties, the dielectric constant and dielectric loss increased with decreasing frequency and decreased with increasing MS content ratio of heterogeneous mineral mixture. Tensile strength and flexural strength according to the mixing ratio (MS + MA) of epoxy / heterogeneous mineral mixture were studied by mechanical properties. The performance of mechanical tensile and flexural strength was significantly improved as the fill contents ratio of MS increased.

The Effect of Surface Modification on the Disperisibilities and the Thermal Conductivities of Single-Walled Carbon Nanotube (SWCNT)/Epoxy Composites (표면 기능화된 단일벽 탄소나노튜브/에폭시 복합체의 분산 및 열전도도 특성)

  • Kim, Jiwon;Im, Hyungu;Kim, Jooheon
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.266-271
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    • 2011
  • Single-walled carbon nanotube (SWCNT)/Epoxy composites were prepared for improving thermal conductivities and dispersion of SWCNTs in the epoxy matrix. Composites obtained different types of SWCNTs which are pristine and functionalized of the SWCNTs by acid and amine treatments. Three types of SWCNTs were dispersed in diglycidyl ether of bisphenol A (DGEBA) and bisphenol F (DGEBF). Enhanced interaction between functional groups on SWCNT and epoxy resins was evidenced by an improvement in the dispersion of the SWCNTs in the epoxy matrix. Thermal conductivity of composites containing acid SWCNTs were found to be much better than those containing pristine and amine treated SWCNTs.

Effect of $TiO_2$ Nanoparticle on the Mechanical and Thermal Properties of Epoxy Resin Composites (에폭시수지 복합재료의 기계적.열적 성질에 대한 $TiO_2$ 나노입자의 영향)

  • Moon, Y.J.;Choi, J.Y.;Kim, B.A.;Moon, C.K.
    • Journal of Power System Engineering
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    • v.14 no.4
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    • pp.68-75
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    • 2010
  • The effect of dispersion agent, the content and size of nanoparticle on the mechanical and thermal properties has been investigated in $TiO_2$ nanoparticle/epoxy resin composites(nanocomposites). The weight fraction of fabricated nanocomposites were 0, 1, 3, 5%, respectively. The glass transition temperature was lower than pure epoxy resin and decreased with the increasing of nanopaticle content. This is considered that the cross link of epoxy resin during solidification was hindered by the presence of nanoparticles. Nanocomposites of 3wt% content with dispersion agent showed the best tensile strength. The tensile strength of 20㎚ $TiO_2$ nanocomposites were higher than one of 200nm $TiO_2$ nanocomposites.

Properties of EMNC According to Addition Contents Variation for Nanosilica (2) -For Mechanical, Electrical Properties (나노 실리카 충진함량 변화에 따른 EMNC의 특성 연구 (2) -기계적, 전기적 특성 중심으로-)

  • Park, Jae-Jun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.11
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    • pp.886-894
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    • 2012
  • In order to develop electrical insulation materials, epoxy-nanosilica-microsilica mixture composites (ENMC) was synthesized, and mechanical properties such as their tensile and flexural strength, and AC insulation breakdown strength were investigated. Properties of mechanical strength and AC insulation breakdown strength are analyzed as scale and shape parameter with respect to weibull plot. Their tensile and flexural strength, AC insulation breakdown strength were compared original epoxy or EMC to ENMC. The 4 phr nano-silica addition and the 65 wt% micron-silica mixture composite (ENMC) was found to have the highest tensile and flexural strength. In the tensile strength was improved 29%, and flexural strength was improved 60.9% higher than those of the original epoxy. In the insulation breakdown strength, ENMC_4 phr was improved 17% and ENMC_5 phr was improved 15.8% higher than those of the EMC.

Prediction of engineering constants for plain and 8-hardness satin woven composites (평직 및 주자직 복합재료의 탄성계수 예측)

  • Byeon, Jun-Hyeong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.11
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    • pp.1757-1764
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    • 1997
  • The geometric and elastic models based on the unit cell have been proposed to predict the geometric characteristics and the engineering constants of plain and satin woven composites. In the geometric model, length and inclined angle of the yarn crimp and the fiber volume fraction of woven composites have been predicted. In the elastic model, the coordinate transformation has been utilized to transform the elastic constants of the yarn crimp to those of woven composites, and the effective elastic constants have been determined from the volume averaging of the constituent materials. Good correlations between the model predictions and the experimental results of carbon/epoxy and glass/epoxy woven composites have been observed. Based on the model, the effect of various geometric parameters and materials on the three-dimensional elastic properties of woven composites can be identified.

Microstructure and Electromagnetic Property of MWNT-added Glass Fabric/Epoxy Composites (다중벽 나노튜브가 첨가된 유리 직물 복합재료의 미세구조 및 전자기적 물성)

  • Lee sang-Eui;Lee Won-Jun;Kim Chun-Gon
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2004.04a
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    • pp.169-172
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    • 2004
  • We fabricated MWNT-added glass fabric/epoxy composites. We observed the distribution of MWNTs in the composites using scanning electron microscopy and conformed that most of MWNTs exist in matrix rich region and interface between yams in warp and fill directions. We also investigated the change of permittivities with MWNT concentrations. Only $1wt\%$ MWNTs leads to high permittivity and electromagnetic waves are impossible to be transmitted to more than $3wt\%$ MWNT-added composites, which means the characteristics of these composites are comparable to those of metals or carbon fiber-reinforced composites.

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Cut-off Grinding Characteristics of the Carbon Fiber Epoxy Composite Materials (탄소 섬유 에폭시 복합재료의 절단 연삭 특성)

  • Kim, Po-Jin;Choe, Jin-Gyeong;Lee, Dae-Gil
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.2 s.173
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    • pp.338-346
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    • 2000
  • Although the net-shape molding of composites is generally recommended, molded composites are frequently required cutting or grinding due to the dimensional inaccuracy for precision machine elements . During the composite machining operations such as cutting and grinding, the temperature at the cutting point may increase beyond the allowed limit due to the low thermal conductivity of composites, which might degrade the matrix of composite. Therefore, in this work, the temperature at the cutting point during cut-off grinding of carbon fiber epoxy composites was measured. The cutting force and surface roughness were also measured to investigate the cut-off grinding characteristics of the composites. The experiments were performed both under dry and wet grinding conditions with respect to cutting speed and feed rate. From the experimental investigation, the optimal conditions for the composite cut-off grinding were suggested.