• Title/Summary/Keyword: Epoxy Resins

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A Study on Partial Discharge Propeties of Interface Layer in-Mica-Epoxy Composite Material (마이카-에폭시 복합절연계 계면층의 부분방전 특성에 관한 연구)

  • 이은학;김태성;박종건;이덕출
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1991.10a
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    • pp.83-89
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    • 1991
  • The partial discharge properties of interface layer in Mica-Epoxy composite, which has been mainly used for the coil insulating material of high voltage machinery, are different from those of resins due to the abnormal interface layer to be presented between inorganic material and resin. Accordingly, the study on discharge of interface in composite insulting system is strongly requsted for not only an increasing of insulating strength, but also the basical information of diagnosis system for high voltage equipment. As a result, it has been confirmed that the interface is an abnormal resin layer and the contact states at interface is depended upon the density of silane aqueous solution. Pulse frequency at abnormal interface shows a linear increasing with enlargement of discharge quantity. Whereas, in case of normal interface, pulse frequency property represents exponential increasing at the point of saturating. A life model can be diagramed from results of time dependance of skewness, and a survival life time can be quantified from the life model suggested.

Dielectric Properties of Modified Epoxy Resins under Inhomogeneous Electric Field (개질된 에폭시 수지계의 불평등 전계하에서 절연특성)

  • An, Hyun-Soo;Shim, Mi-Ja;Kim, Sang-Wook
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1585-1587
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    • 1996
  • The dielectric properties of DGEBA/MDA/GN system under inhomoneous electric field were investigated. As GN contents increased, impact strength increased, but dielectric breakdown strength decreased. At $150^{\circ}C$, the dielectric breakdown strength decreased and uniformly maintained with the increment of distance between two electrodes. The life-time of epoxy resin increased with the decrement of applied voltage, but dielectric breakdown didn't occur below specific applied voltage.

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Synthesis of Epoxidized Soybean Oil (ESO) and its Blends with Tetrafunctional Epoxy Resins (Epoxidized soybean oil(ESO)의 합성 및 4 관능성 에폭시 수지/ESO 블렌드 시스템의 물성)

  • Lee, Jae-Rock;Jin, Fan-Long;Park, Soo-Jin
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2003.04a
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    • pp.180-183
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    • 2003
  • In this work. a potential inexpensive epoxy resin. epoxidized soybean oil (ESO) was synthesized and applied as a toughening agent for 4.4'-tetradiglycidyl diaminodiphenyl methane (TGDDM). The chemical structure of ESO was characterized by FT-IR, $^1H NMR, and ^{13}C NMR$ spectroscopy. The curing behaviors. thermal stabilities. fracture toughness. and flexural strength of TGDDM/ESO blend systems were investigated by using the dynamic DSC. thermogravimetric analysis (TGA). and flexural tests. The thermal stabilities of TGDDM/ESO blend systems were decreased with increasing ESO contents. whereas the critical stress intensity factor ($K_{IC}$) and flexural strength ($\sigma_f$) were increased with ESO contents up to 10 wt% ESO.

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Fabrication and its Application of Composite-Thermistor (Composite-Thermistor의 제작과 그의 응용)

  • Choi, Heon-Il;SaGong, Geon
    • Proceedings of the KIEE Conference
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    • 1988.07a
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    • pp.343-345
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    • 1988
  • In this paper the fabrication and application of Composite-Thermistor were studied. Composite-Thermistor specimens were made by conventional process. Some compounds of vanadium oxides and semiconductor oxides as a fillers were used to fabricate Composite-Thermistor, and Epoxy Resins are used as a polymer matrix. The results of resistivity-temperature characteristics were measured in the range from -100 ($^{\circ}C$) to 200($^{\circ}C$). The harder polymer, Eccogel series #1365-80 and Spurr Epoxy are more preferable compared to the Eccogel (1365-45) with some fillers.

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Photocure Reactions of Photoreactive Prepolymers with Cinnamate Groups

  • Kim, Whan-Gun
    • Bulletin of the Korean Chemical Society
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    • v.32 no.3
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    • pp.993-999
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    • 2011
  • The photoreactive prepolymers with multifunctional cinnamate and bisphenol Atype cinnamate groups that could perform photodimerization without photoinitiators were synthesized by the reaction of t-cinnamic acids (CAs) and epoxy resins. Their photocure reaction rates and the extent of reaction conversion were measured with Fourier transform infrared spectroscopy, and these increased with the intensity of UVirradiation. The experimental data of these reaction rates showed the characteristics of nth-order kinetics reaction, and all kinetic constants of each photoreactive polymer with this equation were summarized. Although the GTR-1800-HCA and KWG1-EP-HCA with hydroxyl group substituted cinnamate showed lower reaction conversion rates and rate constant than GTR-1800-CA and KWG1-EP-CAwith an unsubstituted cinnamate group, GTR-1800-MCAand KWG1-EP-MCAwith methoxy group substituted cinnamate showed similar and higher reaction conversion rates than the former, respectively. These results were explained in terms of segmental mobility for photopolymerization by molecular interactions.

Repair and Strengthening Methods for Concrete Structures using Sprayed Fiber Reinforced Polymers - Strengthening Performance of Reinforced Concrete Beams - (Sprayed FRP 공법에 의한 콘크리트 구조물의 보수.보강법 개발에 관한 연구 - 철근콘크리트 보의 보강성능 평가 -)

  • Lee, Kang-Seok;Son, Young-Sun;Byeon, In-Hee;Lee, Moon-Sung;Na, Jung-Min;Lee, Li-Hyung
    • Proceedings of the Korea Concrete Institute Conference
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    • 2006.11a
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    • pp.133-136
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    • 2006
  • The main purpose of this study is to develop a Sprayed FRP repair and strengthening method, which is a new technique for strengthening the existing concrete structures by mixing carbon or glass shot fibers and the epoxy or vinyl ester resins with high-speed compressed air in open air and randomly spraying the mixture onto the concrete surface. At present, the Sprayed FRP repair and strengthening method using the epoxy resin has not been fully discussed. In this study, a series of experiments are carried out to evaluate the strengthening effects of the flexural and shear concret beams strengthened with the Sprayed FRP method. The results revealed that the strengthening effects of the flexural and shear specimens are similar, compared to those of the FRP sheet.

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Flash Point of p-xylene and Epoxy Resins Mixtures (파라크실렌과 에폭시수지 혼합물의 인화점에 관한 연구)

  • 윤희승;강민호;하동명;정국삼
    • Journal of the Korean Society of Safety
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    • v.15 no.3
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    • pp.78-82
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    • 2000
  • The flash point is an important property and hazardous index of a flammable liquid. The flash points are used by virtually all the environmental, health, and safety organizations in both government and industry to classify flammable liquids for safety and transportation regulations. The basics of all flash points behavior are concerned with the vapor pressure and explosive limits. The flash points of pure components and the mixture of solvents can be calculated with the use of the laws of Raoult, Dalton and Le Chatelier. In this paper, experimentally determined lower flash points of a p-xylene and epoxy resin system were compared with the calculated values by using Raoults law. Calculated lower flash points were in reasonable agreement with the observed values.

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Effects of mixed contents of carbon nanoreinforcements on the impact resistance of epoxy-based nanocomposites

  • Ayatollahi, M.R.;Naeemi, A.R.;Alishahi, E.
    • Structural Engineering and Mechanics
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    • v.56 no.2
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    • pp.157-167
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    • 2015
  • The impact behavior of epoxy-based nanocomposites reinforced with carbon nano tube (CNT), carbon nano fiber (CNF) and mixed contents of these nanoparticles was investigated using Izod impact test. The results showed that while the impact strength of nanocomposites containing 1 wt% of CNT and 1 wt% of CNF increased 19% and 13% respectively, addition of mixed contents of these nanofillers (0.5-0.5 wt%) demonstrated higher improvement (21%) in the impact resistance. The trend of the results is explained on the basis of different fracture mechanisms of nanocomposites. Furthermore, the fracture surface of specimens and the dispersion state of nanoenhancers have been studied using scanning electron microscopy (SEM) photographs.

Patch Plate Repair Method for Steel Structures Combining Adhesives and Stud Bolts

  • Ishikawa, T.;Ikeda, T.
    • International journal of steel structures
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    • v.18 no.4
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    • pp.1410-1419
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    • 2018
  • Recently, a repair method by bonding patch plates is being applied to corroded steel structures. However, one of the issues of patch plate bonding repair is the brittle debonding of the patch plates. Generally, when the delamination of the patch plates occurs, the composite effect acting between the steel members and patch plates abruptly decreases. Therefore, to prevent the brittle debonding of the patch plates, a repair method combining an adhesive and stud bolts is proposed. Till date, tensile and compressive tests have been performed for the proposed method. In this study, plate bending tests were conducted to verify the effectiveness of this method under bending conditions. Furthermore, two types of epoxy resin-based adhesives were prepared to evaluate the effectiveness of the proposed method with different adhesive properties. The test results show that the proposed method is able to prevent the brittle debonding of the patch plates in the case of both epoxy resins.

Calibration of Strain Gauge for Thermal Expansion Coefficientof Fiber Reinforced Composites at Cryogenic Temperature (극저온 환경에서의 섬유강화 복합재료의 열팽창 계수 측정을 위한스트레인 게이지의 보정에 관한 연구)

  • Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Um, Moon-Kwang
    • Progress in Superconductivity and Cryogenics
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    • v.12 no.3
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    • pp.1-6
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    • 2010
  • Since the fiber reinforced polymeric (FRP) composites are considered in next generation of space transportation systems, reliable thermal expansion properties should be well provided for structural design of composite materials. To obtain accurate mechanical behaviors at a cryogenic temperature, precise strain measurement and calibration must be provided. In this work, apparent strains (or thermal output) of temperature self-compensated strain gages were deliberately investigated for epoxy, CTBN modified epoxy and carbon fabric composite system from room temperature to liquid nitrogen temperature. Also, fourth-order thermal output curves were presented for the further calibration. The results showed that the thermal output is heavily dependent on test materials and a large amount of apparent strains were observed for the polymer resins.