• Ocean and Polar Research
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• v.26 no.2
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• pp.175-185
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• 2004

To delineate Late Pleistocene paleoceanographic change of the West Pacific, we analyzed the oxygen and carbon isotopic ratios of two planktonic foraminifera species (G. sacculifer and N. dutertrei) from a piston core (KODOS-313) taken from the West equatorial Pacific, and they are compared with the published results of the East Pacific (ODP site 847 and RC 11-210), in terms of relative amounts and mass accumulation rates of $CaCO_3$ and eolian component, back to marine isotopic stage (MIS) 6. Differences in oxygen and carbon isotope values between two foraminifear species ($0.75%_{\circ}$ in ${\delta}^{18}O$, $0.05%_{\circ}$ in ${\delta}^{13}C$) are less than those of the East Pacific ($1.30%_{\circ}$ in ${\delta}^{18}O$, $0.14%_{\circ}$ in ${\delta}^{13}C$), which indicates smaller vertical contrasts in both temperature and nutrient between mixing-zone and thermocline in the West Pacific. Strong deviation in${\delta}^{18}O$ of G. sacculifer from SPECMAP suggests the carbonate fraction of KODOS-313 was subjected to partial dissolution by bottom water under lysocline. Lower accumulation rates of $CaCO_3$ and eolian component during glacial times are likely due to low sedimentation rate (ave. 0.75 cm/1000 yr) combined with carbonate dissolution in KODOS-313 site. However, the high $CaCO_3$ contents during the glacial periods clearly follow the general pattern of equatorial Pacific ocean.

• Journal of The Geomorphological Association of Korea
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• v.25 no.2
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• pp.43-61
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• 2018

Heterogeneous sedimentary deposits with different soil colors and various degree of hardness are exposed in its foredune and tidal zone due to the effects of recently accelerated coastal erosion along the Ujeon Coast in Jeung-do, Shinan-gun. This study was conducted on the assumption that these sedimentary deposits were developed in different timing and environments. Thus, we can infer the geomorphic development processes of the area based on evidences like the physicochemical characteristics of each sedimentary layer. Several analysis of these sedimentary depositssuch as grain size analysis, X-ray Fluorescence Measurement (XRF), and Loss on ignition (LOI) were performed on central (Ujeon A) and southern (Ujeon B) parts of the Ujeon Coast. I found that the foredune sedimentary deposits have four stages of geomorphic development processes. In the initial stage of development, during the peak of the Last Interglacial Period (MIS 5e), basal deposits were accumulated in the low-energy environment of subtidal zones. In the second stage, during the Last Glacial Period (MIS 4~MIS 2), eolian sedimentary layers were developed by terrestrial aeolian processes by which fine materials were transported from the Yellow Sea which became a dry land exposed by lowered sea level. In the third stage, various mechanism existed for the formation of each sedimentary layer. In the region of Ujeon A, sedimentary layers were developed in the littoral zone environment dominated by marine processes during the maximum phase of transgression in the Holocene. Meanwhile, the region of Ujeon B began to form eolian sedimentary layers during MIS 2. In the last stage, thick coastal dune deposits, covered all over the Ujeon Coast. During the late Holocene (0.7~0.6 ka), terrestrial processes kept dominating the region, developing typical eolian sedimentary layers.

• Korean Journal of Mineralogy and Petrology
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• v.33 no.3
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• pp.153-163
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• 2020

Mineral and geochemical analysis were conducted on two sections (~3.5 m) of red-brown claysilt sediments covering the gneiss and granite weathering zones in Suwon-si for establishing Quaternary paleoenvironmental changes in Korea. The sections were divided into four sedimentary layers (Unit 1-4) by vertical changes in mineral composition and chemical composition. The lowermost unit 1 was a sandy sediment with a high K-feldspar content with a significant contribution of weathered bedrock. Unit 2 was a transition layer showing intermediate characteristics. Unit 3 was a reddish brown clay-silt sediment, with a total clay content of 58% on average, and the main clay minerals were illite-smectite mixed layer minerals and hydroxy-interlayered vermiculite/smectite. Unit 3 contained almost no plagioclase, while the content of kaolin minerals derived by the plagioclase weathering was higher than in the other layers. Unit 4 had similar mineral composition and chemical properties to Unit 3, but had a higher content of plagioclase and chlorite and lower content of kaolin minerals. The chemical compositions of the sections were compared with those in other regions of Korea, suggesting the eolian origin of Units 3 and 4. The paleoenvironmental change in the sedimentary section of this region was interpreted as follows. Weathered products of gneiss and granite, which are bedrocks of this region, were eroded and deposited as sandy sediments in the periphery to form the lower layers (Unit 1, 2), followed by the deposition of the claysilty rich eolian sediments (Unit 3) during the glacial. Unit 3 was chemically weathered during the warm humid climate during the last interglacial, developing a reddish brown color. After that, a eolian sediment layer (Unit 4) was deposited during the last glacial.

• Journal of the Mineralogical Society of Korea
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• v.30 no.1
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• pp.11-19
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• 2017

Reddish brown clay-silt sediments covered granitoid weathering crust in the Jangdongri area, Naju, Korea. Mineralogical and geochemical properties of the ~2 m sediment section were investigated. The sediments were composed mainly of quartz (50%) and clay minerals (45%) with minor contents of K-feldspar, goethite, hematite, and gibbsite. The clay minerals were illite, illite-smectite mixed-layers, vermiculite, hydroxy-Al vermiculite, kaolinite, and halloysite. Mineral composition varied little through the section with the minor upward enrichment of plagioclase and chlorite. Abundant illitic clay minerals indicated the remote source of the sediments because clays derived by granite weathering in Korea were dominated by kaolin minerals. A comparison with the mineral composition of Asian dust (Hwangsa) suggested that plagioclase and K-feldspar disappeared by chemical weathering after deposition, resulting in the quartz and clay-rich sediments. Plagioclase and chlorite altered to kaolin and vermiculite, respectively. Goethite and hematite derived by the weathering of iron-bearing minerals stained the sediment to reddish brown color. The mineralogical and geochemical properties of the reddish brown clay-silt sediments were consistent with those of eolian deposits identified in Korea, supporting eolian origin of the Jangdongri sediments, requiring future confirmation including age dating and isotopic analysis.

• Proceedings of the Mineralogical Society of Korea Conference
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• 2003.05a
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• pp.66-66
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• 2003

King George island, Antarctica, is mostly covered by ice sheet and glaciers, but the land area is focally exposed for several thousand years after deglaciation. For a mineralogical study of chemical weathering in the polar environment, glacial debris was sampled at the well-developed patterned ground which was formed by long periglaclal process. As fresh equivalents, recently exposed tills were sampled at the base of ice cliff of outlet glaciers and at the melting margin of ice cap together with fresh bedrock samples. Fresh tills are mostly composed of quartz, plagioclase, chlorite, and illite, but those derived from hydrothermal alteration zone contain smectite and illite-smectite. In bedrocks, chlorite was the major clay minerals in most samples with minor illite near hydrothermal alteration zone and interstratified chlorite-smectite in some samples. Smectite closely associated with eolian volcanic glass was assigned to alteration in their source region. Blocks with rough surface due to chemical disintegration showed weathering rinds of several millimeter thick. Comparision between inner fresh and outer altered zones did not show notable change in clay mineralogy except dissolution of calcite and some plagioclase. Most significant weathering was observed in the biotite flakes, eolian volcanic glass, sulfides, and carbonates in the debris. Biotite flakes derived from granodiorite were altered to hydrobiotite and vermiculite of yellow brown color. Minor epitactic kaolinite and gibbsite were formed in the cleaved flakes of weathered biotite. Pyrite was replaced by iron oxides. Calcite was congruently dissolved. Volcanic glass of basaltic andesite composition showed alteration rim of several micrometer thick or completely dissolved leaving mesh of plagioclase laths. In the alteration rim, Si, Na, Mg, and Ca were depleted, whereas Al, Ti, and Fe were relatively enriched. Mineralization of lichen and moss debris is of much interest. They are rich of A3 and Si roughly in the ratio of 2:1 to 3:1 typical of allophane. In some case, Fe and Ti are enriched in addition to Al and Si. Transmission electron microscopy of the samples rich of volcanic glass showed abundant amorphous aluminosilicates, which are interpreted as allophane. Chemical weathering in the King George Island is dominated by the leaching of primary phyllosilicates, carbonates, eolian volcanic glass, and minor sulfides. Authigenesls of clay minerals is less active. Absence of a positive evidence of significant authigenic smectite formation suggests that its contribution to the clay mineralogy of marine sediments are doubtful even near the maritime Antarctica undergoing a more rapid and intenser chemical weathering under more humid and milder climate.

• Journal of the Mineralogical Society of Korea
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• v.15 no.1
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• pp.22-32
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• 2002

Mineral composition and chemistry of the clay minerals in the three cores from the continental shelves of South Shetland Islands (NCS09) and Anberse Island (GC98-2), and from the fjord of King George Island (A10-01) were determined by X-ray diffraction and electron microprobe analysis in search of the distributions and origin of the clay minerals in the Antarctic marine sediments. Smectite content is relatively high in NCS09 regardless of core depths (av. 8.3%), but low in GC98-2 (1.1%). In Al0-01, smectite content is higher in the upper section than in the lower section. Kaolinite was not detected from all the cores in this study Yellow to yellowish green clay granules were commonly scattered in the sediments of NCS09 cores. The clays contain 16.97% and 2.53% $Fe_2$$O_3$와 $K_2$O. Average structural formula of the clay indicates ferrian beidellite . The (Fe, K)-rich smectite of NSC09 must have been derived from relatively young basaltic volcanics altered by reaction with seawater near Shetland Islands by glacial erosion or eolian process related to volcanic eruption. GC98-2 nearer to Antarctic continent is very low in smectite content. In A10-01, the lower diamicton was deposited from the glacial erosion of smectite-free ancient volcanics in the interior of King George Island, while the upper section was derived from the smectite-bearing terrestrial debris and eolian materials after retreat of glaciers in Marian Cove and ice cover in Barton Peninsula. Thehigh K contents of smectites suggest the interstratification of illite and smectite layers, which might be observed by future TEM lattice fringe imaging.

• 한국해양학회지
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• v.22 no.3
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• pp.119-129
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• 1987

Sediments in the cores from the KONOD-1 area consist mainly of authigenic smectite and clinoptilolite, and terrigenous minerals of illite, chlorite, kaolinite, quartz, and plagioclase. The authigenic minerals become dominant over the terrigenous minerals with increasing depth. Clinoptilolite occurs at the deeper core depth because its formation is slower than that of smectite. The vertical distribution of minerals indicates that the eolian influence, probably in the late Oligocene, diluted the abundance if smectite in near-surface sediments. This vertical distribution pattern may also have been affected by progressive dissolution of authigenic minerals in the near surface sediments.

• Journal of the Korean Geographical Society
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• v.44 no.4
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• pp.463-480
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• 2009

The weathering properties and provenance of loess-paleosol sequence deposited on gravel layer of river terrace in Bongdong-eup, Wangju-gun, Jeonbuk Province are examined using soil analysis, magnetic susceptibility measurement, grain size and element analysis. The Bongdong section consists of, from top to bottom, Layer 1(paleosol), Layer 2(loess), Layer 3(paleosol) and the gravel layer of river terrace. The magnetic susceptibility values show the systematic variations in the sequence and the results of grain size analysis reveal that the sequence was deposited by not fluvial or slope process, but eolian process, and that contains finer materials than the Daecheon loess and Chinese Loess Plateau. Among the results of soil analysis, organic contents indicate systematic variations similar to the magnetic susceptibility. The wet soil colors further reflect the characteristics of the sequence rather than the dry soil colors. Based on the analytical results of major and rare earth elements, the eolian materials contained in the sequence were deposited by the materials originated from the areas where the Chinese Loess Plateau has been originated or the reworked materials from the Chinese Loess Plateau, and after the depositions, the materials experienced the intensive chemical weathering under the humid-warm climatic conditions in the Korean Peninsula.

• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.255-260
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• 2007

The loess on the Chinese loess plateau is not only the accumulation of Asian dust but also the source materials of Hwangsa. The eolian carbonates of the loess were dissolved and reprecipitated to form secondary pedogenic carbonates by the post-depositional weathering during the interglacial time. Mineralogical analysis shows that the secondary calcites are composed mostly of a nanosized fibrous calcite with rather constant width ($30{\sim}50nm$) and highly variable length. The nano calcite is the major authigenic mineral, which occurs as the fine-grained matrix of the loess and paleosol. The nano calcite was recently reported in the Hwangsa, where it was originated from the source regions of Chinese loess plateau.

• Journal of the Mineralogical Society of Korea
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• v.31 no.4
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• pp.287-293
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• 2018

Amorphous silica ($SiO_2$) silt grains were found in some soils of Korean Peninsula. Scanning electron microscopy of polished section of soils revealed ellipsoidal amorphous $SiO_2$ grains with numerous submicron pores concentrated in the interior. Their amorphous structure was confirmed by lattice imaging and electron diffraction under transmission electron microscope. Amorphous $SiO_2$ grains were not found in the eolian sediment of the Chinese loess plateau. Although the origin of the amorphous $SiO_2$ grain is uncertain, they are likely either phytolith or weathering product of volcanic ash. The amorphous $SiO_2$ silt grains are not useful as a tracer of long-range transport mineral dust in soils.