• Title/Summary/Keyword: Environmentally benign

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Novel Synthesis of 3-Phenyl-chromen-4-ones Using N-Heterocyclic Carbene as Organocatalyst: An Efficient Domino Catalysis Type Approach

  • Mishra, Priya;Singh, Sarita;Ankit, Preyas;Fatma, Shahin;Singh, Divya;Singh, Jagdamba
    • Bulletin of the Korean Chemical Society
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    • v.34 no.4
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    • pp.1070-1076
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    • 2013
  • Herein is reported a simple and efficient synthesis of isoflavones starting from various substituted phenacyl bromides and salicylaldehydes in presence of NHC. The mechanism involved domino catalysis type approach with consumption and regeneration of catalyst in two catalytic cycles. This method proved to be very lucrative and gives very good yield. The method described here represents an environmentally benign alternative to classical approach.

Base Catalysed Pyrimidine Synthesis Using Microwave

  • Kidwai, M.;Rastogi, S.;Saxena, S.
    • Bulletin of the Korean Chemical Society
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    • v.24 no.11
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    • pp.1575-1578
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    • 2003
  • An environmentally benign approach for the synthesis of 2-substituted-4,6-diaryl pyrimidines using inorganic solid supports for its catalytic role as well as an energy transfer medium is described. The methodology eliminates the usage of solvent during the reaction. The reaction time is brought down from hours to minutes along with yield enhancement. The rate enhancement and high yield is attributed to the coupling of solvent free conditions with microwaves. Further, the role of base is studied in the reaction and it is concluded that microwave assisted basic alumina catalysed reaction is the best in terms of catalysis as well as reaction time and yield.

Development of environmentally benign inorganic bacteriocide and studies of its efficacy (친환경 무기항균제 개발 및 효능 연구)

  • Kim, Han-Wool;Kim, So-Hyung;Park, Sun-Young;Lee, Mi-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.7 no.5
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    • pp.935-939
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    • 2006
  • The environmentally benign inorganic bacterioide was developed by using waste shell as a matrix and its efficacies against various bacteria were examined in this investigation. The inorganic bacteriocide inhibited strongly the growths of various bacteria such as S. aureus and E.coli. The inorganic bacteriocide also showed strong killing effect on the growth of P.acnes which causes the acne on human face. Moreover, this bacteriocide inhibited the activity of lipoxygenase prominently, indicating notable anti-inflammatory activity of the bacteriocide.

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Environmentally benign. Background-free protein staining in SDS-polyacrylamide gels using an counter ion-dye complex solution.

  • Jin , Li-Tai;Hwang, Sun-Young;Yoo, Gyurng-Soo;Choi, Jung-Kap
    • Proceedings of the PSK Conference
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    • 2002.10a
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    • pp.313.2-313.2
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    • 2002
  • Environmentally benign protein staining method in sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE) using both an acidic dye, zincon (ZC) and a basic dye. ethyl violet (EV) is described. It is based on a counter ion-dye staining technique that employs oppositely charged two dyes to form an ion-pair complex. The selective binding of the free dye molecules to proteins in an acidic solution produces bluish violet colored bands. It is a rapid procedure, involving only fixin and staining steps that are completed in 45 min. (omitted)

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International Movement on Rural Ice-village for 21st Century for an Environmentally Benign Agriculture (친환경농업을 위한 21세기 농촌형 "생태마을"의 국제적 동향)

  • 손상목
    • Korean Journal of Organic Agriculture
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    • v.9 no.2
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    • pp.39-54
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    • 2001
  • For the development of Eco-village in Korean rural area, it was focussed to introduce the rural style which has been developed intensively in European countries such as Denmark, England and Germany. As the main concept for Eco-village it was explained briefly in the paper on the renewable energy(wind power park, bio-mass and solar energy collector and heating system), eco-architecture, methane gas device, living machine(wastewater treatment facility) and organic farming. It was also discussed how important the basic standard and guidelines for organic agriculture to run Eco-village environmentally soundly as a whole system and why it is so much essential for the system. For this reason major principles of international applicable standard for organically grown foods by FAO/WHO Codex alimentarius was also shortly described. In the paper the Eco-village concept was considered as a suitable model for Environmental Agriculture Districts Project which Korean government is going to establish at rural area in the near future. In conclusion it was suggested that the positive participation of organic farmers, enthusiastic engagement of inhabitants and support strategy of government/NGO groups might play very important role for successful management of Eco-village ecologically benign and economically sustainable after establishment.

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Evaluate the expected price of HTS transformer for introducing into korean power system (초전도변압기의 계통적용을 위한 예상 시장진입가격 추정)

  • Kim, Jong-Yul;Lee, Seung-Ryul;Yoon, Jae-Young
    • Proceedings of the KIEE Conference
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    • 2004.11b
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    • pp.176-178
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    • 2004
  • HTS (High Temperature Superconducting) Transformer has the several useful characteristics in the viewpoints of technical and economical. Especially, an HTS transformer replaces the copper wire coils in a conventional transformer with lower loss HTS wire In addition, inexpensive, environmentally benign liquid nitrogen replaces the conventional oil as the electrical insulation (dielectric) and provides the necessary cooling for the HTS transformer Therefore, the Life-cycle cost of an HTS transformer is much more attractive than conventional because it is more energy efficient, lighter in weight, smaller in size, and environmentally compliant. HTS transformer can be the best way to replace with conventional transformer in the future. In this paper, we investigate the expected price of HTS transformer to have a merit in viewpoint of economic aspect. First, life-cycle cost of conventional transformer is calculated and based on this, the expected price of HTS transformer is evaluated, which HTS transformer is competitive against conventional transformer.

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Green Control of Silver Nanoparticle Size by Adjusting the Quantity of Water in Glycerol

  • Lim, Jong Kuk
    • Journal of Integrative Natural Science
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    • v.14 no.1
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    • pp.6-10
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    • 2021
  • New materials are very useful due to their wide range of applications, however, they also have caused new pollutants that damage our environment. Chemists have been conscious of the severity of these environmental problems and a great deal of effort has been put into developing environmentally benign chemical processes to synthesize new materials (green synthesis). We also have reported a green synthesis method of synthesizing silver nanoparticles using water-glycerol solution in a previous study. While conducting further research, we have recently discovered that the size of silver nanoparticles is proportional to the quantity of water present in glycerol. This method is completely benign and ecofriendly pathway, as the size of silver nanoparticles is adjusted solely by controlling the quantity of water added to glycerol, without extra additives and energy.

Montmorillonite K-10 Clay as an Efficient Reusable Heterogeneous Catalyst for the Solvent-Free Microwave Mediated Synthesis of 5-Substituted 1H-Tetrazoles

  • Marvi, Omid;Alizadeh, Abdolhamid;Zarrabi, Saeid
    • Bulletin of the Korean Chemical Society
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    • v.32 no.11
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    • pp.4001-4004
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    • 2011
  • Various 5-substituted 1H-tetrazole derivatives were synthesized in a simple and environmentally benign method from the reaction of aryl and benzyl nitriles with sodium azide in solvent-free media using montmorillonite K-10 clay as solid recyclable heterogeneous acidic catalyst and microwave irradiation in good yields and short reaction times.