• 한국수소및신에너지학회논문집
• /
• 제13권2호
• /
• pp.101-109
• /
• 2002

This work was focused on the thermal decomposition of methane into hydrogen and carbon black without emitting carbon dioxide. Extensive experimental investigation on the thermal decomposition of methane has been carried out using a continuous flow reaction system with tubular reactor. The experiments were conducted at the atmospheric pressure condition in the wide range of temperature ($950-1150^{\circ}C$) and flow rate (250 - 1500 ml/min) in order to study their dependency on hydrogen yield. During the experiments the carbon black was successfully recovered as an useful product. Undesirable pyrocarbon was also formed as solid film, which was deposited on the inside surface of tubular reactor. The film of pyrocarbon in the reactor wall became thicker and thicker, finally blocking the reactor. The design of an efficient reactor which can effectively suppress the formation of pyrocarbon was thought to be one of the most important subjects in the thermal cracking of methane.

• 전기화학회지
• /
• 제2권2호
• /
• pp.81-87
• /
• 1999

Polyacrylonitrile(PAN)섬유를 원료로 여러 가지 조건하에서 탄소섬유를 제조하여 리튬이온 이차전지 음극 활물질로 사용하여, 전지의 충$\cdot$방전 특성과 전기화학적 특성을 고찰하였다. 음극활물질 제조에 있어서 고려한 주요한 변수들은 탄화 열처리 온도(HTT : heat treatment temperature), 탄화시의 가스분위기와 안정화(stabilization)시 섬유 축방향으로 가해주는 장력이며, 제조된 탄소섬유의 물성 및 전기적 특성 역시 조사하였다. 본 연구에서 사용한 열처리 온도 범위는 $700^{\circ}C\~1500^{\circ}C$로서, 처리온도가 상승 할 수록 전도성은 비례하여 향상되었으나, 900"C 범위는 아직 낮은 전도성을 보였다. 또한 처리온도 증가에 따라 충 방전효율은 증가하는 반면, 충 방전용량은 감소되는 경향을 보였다. 그리고 탄화시의 가스 분위기에 따라서 제조되는 음극활물질의 전지특성에 영향을 받았다. 특히, 다른 가스 분위기 하에서 제조된 PAN계 전극들의 측정된 리튬이온의 확산계수 값은 전지의 충$\cdot$방전 특성과 일치하는 결과를 보였다. 탄화시 서로 다른 가스분위기에서 탄소섬유 표면상에 형성된 다양한 기능기그룹(surface functional group)들이 리튬이온과의 비가역적 반응이 진행되는 사실을 간접적으로 확인하게 해준다. 산화분위기에서의 안정화시의 PAN섬유에 가해지는 장력은 가교 결합 중에 형성되는 분자의 배향을 유지시켜 주는 역할을 하는데, 안정화처리 후에도 섬유의 길이변화가 없는 장력조건 (fixed-length condition)에서 충 방전효율 및 용량과 사이클 안정성이 우수한 것으로 나타났다.

• 제어로봇시스템학회:학술대회논문집
• /
• 제어로봇시스템학회 2004년도 ICCAS
• /
• pp.1506-1510
• /
• 2004

A mobile robot system is developed to inspect the condition of industrial facilities under hot environment. The mobile robot is equipped with internal and external heat insulating material, an internal cooling mechanism, two CCD cameras, wireless communication devices for both the control and image signals, and an embedded controller. The portable controller is equipped with two joysticks for both the mobile robot and the inspection CCD camera, an LCD monitor, and several buttons. The developed mobile robot travels on the internal floor in hot furnaces by operators' joystick operation, captures the images of facilities in the furnaces using a zoom CCD camera, and sends the images to the portable controller through wireless communication. The mobile robot can be operated without any problem under hot environment less than 400$^{\circ}C$ in 30 minutes. This kind of automatic inspection mobile robot can be helpful to prevent significant troubles of industrial facilities without danger of human beings under harmful environment.

• Bulletin of the Korean Chemical Society
• /
• 제28권12호
• /
• pp.2299-2302
• /
• 2007

A series of quaternary ammonium-based ionic liquids (ILs) containing an alkyl carbonate group on the cation was first prepared and their physical and electrochemical properties including density, viscosity, thermal stability, electrochemical stability, and ionic conductivity were reported. These ILs exhibited wide electrochemical windows of at least 5.0 V and relatively high conductivities. In contrast to dialkyl-substituted ionic liquids, the ILs with an alkyl carbonate group on the cation showed much smaller drop in conductivities when mixed with a lithium salt, due to the interaction of lithium ions with carbonate groups. Upon interaction with a Li salt, the carbonyl stretching frequency of the carbonate group shifted to a lower frequency whereas the peak associated with C-O single bond moved to a higher frequency.

• 한국물환경학회지
• /
• 제26권5호
• /
• pp.781-788
• /
• 2010

A pilot study was performed to examine the feasibility of multiple stage of constructed wetland (CW) for nutrient removal. The system is composed of six wetland cells connected with water-ways. The hydraulic of wetland cells is designed as free water surface flow. The treatment capacity was $25m^3d^{-1}$ at HRT of about one day for each cell. The magnitude of nutrient removal was related with the length of wetlands and plant density. Total N and P removal rates were 1353 and $246mg\;m^{-2}d^{-1}$ respectively. The pilot-scale reactor was model as continuous flow system containing contribution of CSTR and PFR typed-reactors. The $k-C^*$ model equation was applied to predict N and P reduction. The result indicated the equation was well guided to estimate reduction of $NO_3-N$ and $PO_4-P$.

• 디지털융복합연구
• /
• 제7권3호
• /
• pp.13-24
• /
• 2009

Technology Acceptance Model (TAM) has been a basis model for testing technology use. Post researches of TAM have been conducted with the updating the TAM by adding new independent variables in order to increase the explanatory power of the model. However, the problem is that different independent variables have to be required to keep the explanatory power whenever adopting particular technology. This might reduce the generality of the research model. Thus in order to increase the generality of the model, this study reviewed the previous researches and collected the independent variables used, and regrouped them into three basic independent constructs. New research model was designed with three basic independent constructs with three constructs selected for the involuntary information technology usage environment. Finally, this study concluded that new technology acceptance model could be used to explain the use of new technology without any adding new particular independent variables.

• 한국환경농학회지
• /
• 제24권4호
• /
• pp.334-340
• /
• 2005

This experiment was conducted to evaluate the nutrient loss and to assess the eutrophication into small stream by intensive rains in the steeped cornfield during cultivation. The crop cultivated was a soiling com (DW5969), and the experimental plots were divided into two parts that were 10 and 18% of slope degrees. The amount of T-N and T-P loss was calculated by analysis of surface run-off water quality, and was investigated the effect of eutrophication to small stream as a part of life cycle assessment (LCA) methodology application. For the surface run-off water quality, EC and T-N values were highest in first runoff event as compared to the other events and maintained the stage state with litter variations at every hour during the runoff period except for EC in the slope 18%. However, T-P concentration has been a transient stage after runoff event of July 27. Total surface run-off ratio was not significantly different with slope degrees, but amount of T-N and T-P losses at 18% of slope were high as $5.96kg\;ha^{-1}\;and\;0.65kg\;ha^{-1}$ as relative to 10% of slope degree, respectively. Furthermore, T-N losses from run-off water in the sloped cornfield 10 and 18% were approximately 9.8 and 12.5% of the N applied as fertilizer when the fertilizer applied at recommended rates after soil test, respectively. For the eutrophication impact to the small stream, it was shown that $PO_4$ equivalence and Eco-indicator value at 18% of slope degree were greater as much $6.11kg\;ha^{-1}$ and 0.81 as compared to the slope angle 10%, respectively. Therefore, it was appeared that each effect of nutrient losses, eutrophication and Eco-indicator value was enhanced according with higher slope degree.

• 한국물환경학회지
• /
• 제25권6호
• /
• pp.910-915
• /
• 2009

The ecohydrologic characteristics according to planting in riparian zone for the riparian restoration are analyzed in this research. The ecohydrologic components due to land use change in riparian zone from existing land cover to planted area such as pasture and wildrye are simulated in the test basin with the integrated SWAT-MODFLOW model. After analysis of change of the hydrologic properties such as surface flow, lateral flow, transpiration and soil water in riparian zone, it is revealed that soil water is one of the key factors and planting of wildrye can increase soil water in riparian zone. The simulation performance of the SWAT-MODFLOW model is validated in this study and it is expected that this model can be used to evaluate various riparian restoration scenarios.

• Journal of Electrical Engineering and Technology
• /
• 제6권6호
• /
• pp.883-887
• /
• 2011

Location-based service (LBS) is becoming an important part of the information technology (IT) business. Localization is a core technology for LBS because LBS is based on the position of each device or user. In case of outdoor, GPS - which is used to determine the position of a moving user - is the dominant technology. As satellite signal cannot reach indoor, GPS cannot be used in indoor environment. Therefore, research and study about indoor localization technology, which has the same accuracy as an outdoor GPS, is needed for "seamless LBS". For indoor localization, we consider the IEEE802.11 WLAN environment. Generally, received signal strength indicator (RSSI) is used to obtain a specific position of the user under the WLAN environment. RSSI has a characteristic that is decreased over distance. To use RSSI at indoor localization, a mathematical model of RSSI, which reflects its characteristic, is used. However, this RSSI of the mathematical model is different from a real RSSI, which, in reality, has a sensitive parameter that is much affected by the propagation environment. This difference causes the occurrence of localization error. Thus, it is necessary to set a proper RSSI model in order to obtain an accurate localization result. We propose a method in which the parameters of the propagation environment are determined using only RSSI measurements obtained during localization.

• Fisheries and Aquatic Sciences
• /
• 제10권4호
• /
• pp.226-229
• /
• 2007

Survival, tag retention and tag readability were compared among the control and three treatment groups of soft-shelled turtles, Pelodiscus sinensis Crother, 2000 (mean body $weight{\pm}SD$: $182.6{\pm}13.7\;g$), marked with visible implant fluorescent elastomer (VIFE) tags for 16 months. Mortality 4 to 16 months after tagging was attributed to collection and handling stress rather than to the tagging itself. Tags applied to the web surface between the fourth and fifth dactyl of the hindfoot appeared to have the highest retention rates, while adipose eyelid tagging had high tag readability but a high loss rate. We conclude that in soft-shelled turtles, the most suitable region for VIFE tagging is on the web surface between the fourth and fifth dactyls of the hindfoot.