• Title/Summary/Keyword: Entropy model

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Fast Inverse Transform Considering Multiplications (곱셈 연산을 고려한 고속 역변환 방법)

  • Hyeonju Song;Yung-Lyul Lee
    • Journal of Broadcast Engineering
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    • v.28 no.1
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    • pp.100-108
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    • 2023
  • In hybrid block-based video coding, transform coding converts spatial domain residual signals into frequency domain data and concentrates energy in a low frequency band to achieve a high compression efficiency in entropy coding. The state-of-the-art video coding standard, VVC(Versatile Video Coding), uses DCT-2(Discrete Cosine Transform type 2), DST-7(Discrete Sine Transform type 7), and DCT-8(Discrete Cosine Transform type 8) for primary transform. In this paper, considering that DCT-2, DST-7, and DCT-8 are all linear transformations, we propose an inverse transform that reduces the number of multiplications in the inverse transform by using the linearity of the linear transform. The proposed inverse transform method reduced encoding time and decoding time by an average 26%, 15% in AI and 4%, 10% in RA without the increase of bitrate compared to VTM-8.2.

Performance Evaluation of ResNet-based Pneumonia Detection Model with the Small Number of Layers Using Chest X-ray Images (흉부 X선 영상을 이용한 작은 층수 ResNet 기반 폐렴 진단 모델의 성능 평가)

  • Youngeun Choi;Seungwan Lee
    • Journal of radiological science and technology
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    • v.46 no.4
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    • pp.277-285
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    • 2023
  • In this study, pneumonia identification networks with the small number of layers were constructed by using chest X-ray images. The networks had similar trainable-parameters, and the performance of the trained models was quantitatively evaluated with the modification of the network architectures. A total of 6 networks were constructed: convolutional neural network (CNN), VGGNet, GoogleNet, residual network with identity blocks, ResNet with bottleneck blocks and ResNet with identity and bottleneck blocks. Trainable parameters for the 6 networks were set in a range of 273,921-294,817 by adjusting the output channels of convolution layers. The network training was implemented with binary cross entropy (BCE) loss function, sigmoid activation function, adaptive moment estimation (Adam) optimizer and 100 epochs. The performance of the trained models was evaluated in terms of training time, accuracy, precision, recall, specificity and F1-score. The results showed that the trained models with the small number of layers precisely detect pneumonia from chest X-ray images. In particular, the overall quantitative performance of the trained models based on the ResNets was above 0.9, and the performance levels were similar or superior to those based on the CNN, VGGNet and GoogleNet. Also, the residual blocks affected the performance of the trained models based on the ResNets. Therefore, in this study, we demonstrated that the object detection networks with the small number of layers are suitable for detecting pneumonia using chest X-ray images. And, the trained models based on the ResNets can be optimized by applying appropriate residual-blocks.

Influence of pH on Chelation of BaCl2 and EDTA Using Isothermal Titration Calorimetry (등온적정열량계를 이용한 BaCl2와 EDTA 킬레이션 결합 반응의 pH 영향)

  • Ga Eun Yuk;Ji Woong Chang
    • Applied Chemistry for Engineering
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    • v.34 no.3
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    • pp.279-284
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    • 2023
  • Isothermal titration calorimetry (ITC) is a useful technique to obtain thermodynamic binding properties such as enthalpy, Gibbs free energy, entropy, and stoichiometry of the chelation reaction. A single independent binding site model was used to evaluate the thermodynamic binding properties in BaCl2 and ethylenediaminetetraacetic acid (EDTA) in Trince and HEPES buffers. ITC enables us to elucidate the binding mechanism and find an optimal chelation condition for BaCl2 and EDTA in the pH range of 7~11. Chelation of BaCl2 and EDTA is a spontaneous endothermic reaction. As pH increased, entropic contributions dominated. The optimal pH range is narrow around pH 9.0, where 1:1 binding between BaCl2 and EDTA occurs.

Modeling of Thermodynamic Properties of Saturated state Hydrogen using Equation of State (상태방정식을 이용한 포화상태 수소의 열역학적 물성 모델링)

  • Bong-Seop Lee;Hun Yong Shin;Choong Hee Joe
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.550-554
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    • 2023
  • Fossil energy sources are limited in their sustainable use and expansion due to global warming caused by carbon dioxide emissions. Hydrogen is considered as a promising alternative to traditional fossil fuels. To ensure the stable long-term storage, it is necessary to accurately predict its thermodynamic properties at cryogenic temperatures. Therefore, this study aimed to investigate thermodynamic properties, such as saturated vapor pressure and density, enthalpy, and entropy of liquid and gas, using cubic equations of state that demonstrate relatively simple relationships. Among the three types of equations of state (Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK), and Peng-Robinson (PR)), the SRK model exhibited relatively accurate prediction results for various physical properties.

Thermotropic Liquid Crystalline Behavior of α,ω-Bis(4-nitroazobenzene-4'-carbonyloxy)alkanes (α,ω-비스(4-니트로아조벤젠-4'-카보닐옥시)알칸들의 열방성 액정 거동)

  • Jeong, Seung Yong;Hwang, Dong Jun;Ma, Yung Dae
    • Applied Chemistry for Engineering
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    • v.21 no.2
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    • pp.230-237
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    • 2010
  • A homologous series of linear liquid crystal dimers, ${\alpha},{\omega}$-bis(4-nitroazobenzene-4'-carbonyloxy)alkanes (NATWESn, n = 2~8, 10, the number of methylene units in the spacer) have been synthesized, and the thermal behavior of the series has been investigated. All the dimers formed enantiotropic nematic phases. The nematic-isotropic transition temperatures of the dimers and their entropy variation at the phase transition showed a large odd-even effect as a function of n. This behavior was rationalized in terms of the change in the average shape of the spacer on varing the parity of the spacer. The thermal stability and degree of order in the nematic phase and the magnitude of the odd-even effect of NATWESn were very similar to those of the corresponding ether compounds, while they were significantly different from those of the monomesogenic compounds, 4-{4'-(nitrophenylazo)phenoxy}alkanoyl chlorides and the side-chain liquid-crystalline polymers, the poly[1-{4-(4'-nitrophenylazo) phenoxycarbonylalkanoyloxy}ethylene]s. The results were discussed in terms of the 'irtual trimer model'by Imrie.

Influence of the CYP1A1 T3801C Polymorphism on Tobacco and Alcohol-Associated Head and Neck Cancer Susceptibility in Northeast India

  • Singh, Seram Anil;Choudhury, Javed Hussain;Kapfo, Wetetsho;Kundu, Sharbadeb;Dhar, Bishal;Laskar, Shaheen;Das, Raima;Kumar, Manish;Ghosh, Sankar Kumar
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.16
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    • pp.6953-6961
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    • 2015
  • Background: Tobacco and alcohol contain or may generate carcinogenic compounds related to cancers. CYP1A1 enzymes act upon these carcinogens before elimination from the body. The aim of this study was to investigate whether CYP1A1 T3801C polymorphism modulates the relationship between tobacco and alcohol-associated head and neck cancer (HNC) susceptibility among the northeast Indian population. Materials and Methods: One hundred and seventy histologically confirmed HNC cases and 230 controls were included within the study. The CYP1A1 T3801C polymorphism was determined using PCR-RFLP, and the results were confirmed by DNA sequencing. Logistic regression (LR) and multifactor dimensionality reduction (MDR) approaches were applied for statistical analysis. Results: The CYP1A1 CC genotype was significantly associated with HNC risk (P=0.045). A significantly increased risk of HNC (OR=6.09; P<0.0001) was observed in individuals with combined habits of smoking, alcohol drinking and tobacco-betel quid chewing. Further, gene-environment interactions revealed enhanced risks of HNC among smokers, alcohol drinkers and tobacco-betel quid chewers carrying CYP1A1 TC or CC genotypes. The highest risk of HNC was observed among smokers (OR=7.55; P=0.009) and chewers (OR=10.8; P<0.0001) carrying the CYP1A1 CC genotype. In MDR analysis, the best model for HNC risk was the three-factor model combination of smoking, tobacco-betel quid chewing and the CYP1A1 variant genotype (CVC=99/100; TBA=0.605; P<0.0001); whereas interaction entropy graphs showed synergistic interaction between tobacco habits and CYP1A1. Conclusions: Our results confirm that the CYP1A1 T3801C polymorphism modifies the risk of HNC and further demonstrated importance of gene-environment interaction.

A nationwide analysis of mammalian biodiversity hotspots in South Korea (전국단위의 포유류 생물다양성우수지역 분석 연구)

  • Kim, Jiyeon;Kwon, Hyuksoo;Seo, Changwan;Kim, Myungjin
    • Journal of Environmental Impact Assessment
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    • v.23 no.6
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    • pp.453-465
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    • 2014
  • Hotspots are top sites in terms of species diversity as the most threatened and most diverse sites which have been used to select priority areas for reserves. The purpose of this paper is to identify biodiversity hotspots through analyzing nationwide spatial patterns of species richness and rarity of Korean mammals. Four endangered mammals and eleven common mammals were selected as target species. Environmental variables as model input data were consisted of topography, distance, and vegetation structure etc. and Maxent was used to develop species distribution models for target species. Species richness and rarity were used as index of biodiversity. The results of this study were as follows. Firstly, hotspots of species richness for endangered mammals were in high elevation and steep mountain areas. However, species richness for whole mammals were high in low elevation of mountains. Secondly, distribution pattern of species rarity for endangered mammals were similar as richness. However, hotspots of species rarity for whole mammals were a little different from species richness. Species rarity was high in both low and high elevation of mountain areas. This study will provide the useful information for a biodiversity assessment, a habitat conservation, a national ecological network plan, and the management of protected areas.

Adsorption Equilibrium, Kinetics and Thermodynamic Parameters Studies of Bismarck Brown R Dye Adsorption on Granular Activated Carbon (입상 활성탄에 대한 비스마르크 브라운 R 염료의 흡착평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong-Jib
    • Applied Chemistry for Engineering
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    • v.24 no.3
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    • pp.327-332
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    • 2013
  • Batch experiments were carried out for adsorption equilibrium, kinetics and thermodynamic parameters of the brilliant brown R onto granular activated carbon. The operating variables studied were the initial dye concentration, contact time and temperature. Experimental equilibrium adsorption data were fitted to Langmuir and Freundlich adsorption isotherm by linear regression method. The equilibrium process was well described by Freundlich isotherm model and from the determined separation factor (1/n), granular activated carbon could be employed as an effective treatment for the removal of bismarck brown R. From kinetic experiments, the adsorption processes were found to confirm the pseudo second order model with a good correlation and the adsorption rate constant ($k_2$) increased with increasing adsorption temperature. Thermodynamic parameters like the activation energy, change of Gibbs free energy, enthalpy, and entropy were also calculated to predict the nature of adsorption in the temperature range of 298~318 K. The activation energy was determined as 8.73 kJ/mol for 100 mg/L. It was found that the adsorption of bismarck brown R on the granular activated carbon was physical process. The negative Gibbs free energy change (${\Delta}G$ = -2.59~-4.92 kJ/mol) and the positive enthalpy change (${\Delta}H$ = +26.34 kJ/mol) are indicative of the spontaneous and endothermic nature of the adsorption process.

Selection of the Optimal Location of Traffic Counting Points for the OD Travel Demand Estimation (기종점 수요추정을 위한 교통량 관측지점의 적정위치 선정)

  • 이승재;이헌주
    • Journal of Korean Society of Transportation
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    • v.21 no.1
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    • pp.53-63
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    • 2003
  • The Origin-Destination(OD) matrix is very important in describing transport movements in a region. The OD matrix can be estimated using traffic counts on links in the transport network and other available information. This information on the travel is often contained in a target OD matrix and traffic counts in links. To estimate an OD matrix from traffic counts, they are the major input data which obviously affects the accuracy of the OD matrix estimated, Generally, the quality of an estimated OD matrix depends much on the reliability of the input data, and the number and locations of traffic counting points in the network. Any Process regarding the traffic counts such as the amount and their location has to be carefully studied. The objective of this study is to select of the optimal location of traffic counting points for the OD matrix estimation. The model was tested in nationwide network. The network consists of 224 zones, 3,125 nodes and 6,725 links except to inner city road links. The OD matrix applied for selection of traffic counting points was estimated to 3-constrained entropy maximizing model. The results of this study follow that : the selected alternative to the best optimal counting points of six alternatives is the alternative using common links of OD matrix and vehicle-km and traffic density(13.0% of 6,725 links), however the worst alternative is alternative of all available traffic counting points(44.9% of 6,725 links) in the network. Finally, it should be concluded that the accuracy of reproduced OD matrix using traffic counts related much to the number of traffic counting points and locations.

Study on Adsorption Kinetic Characteristics of Propineb Pesticide on Activated Carbon (활성탄에 대한 프로피네브 농약의 흡착동력학적 특성 연구)

  • Lee, Jong-Jib;Cho, Jung-Ho;Kim, Heung-Tae
    • Clean Technology
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    • v.17 no.4
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    • pp.346-352
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    • 2011
  • The adsorption characteristics of propineb pesticide onto activated carbon has been investigated for the adsorption in aqueous solution with respect to initial concentration, contact time and temperature in batch experiment. The Langmuir and Freundlich adsorption models were applied to described the equilibrium isotherms and isotherm constants were also determined. The Freundlich model agrees with experimental data well. slope of isotherm line indicate that activated carbon could be employed as effective treatment for removal of propineb. The pseudo first order, pseudo second order kinetic models were use to describe the kinetic data and rate constants were evaluated. The adsorption process followed a pseudo second order model, and the adsorption rate constant($k_2$) decreased with increasing initial concentration of propineb. The activation energy, change of free energy, enthalpy, and entropy were also calculated to predict the nature adsorption. The estimated values for change of free energy were -7.28, -8.27 and -11.66 kJ/mol over activated carbon at 298, 308 and 318 K, respectively. The results indicated toward a spontaneous process. The positive value for change of enthalpy, 54.46 kJ/mol, found that the adsorption of propineb on activated carbon is an endothermic process.