• Bulletin of the Korean Chemical Society
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• v.35 no.8
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• pp.2573-2576
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• 2014

• Bulletin of the Korean Chemical Society
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• v.35 no.6
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• pp.1692-1696
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• 2014

A practical and efficient one-pot synthesis of 1,3,5-trisubstituted pyrazoles from ${\alpha},{\beta}$-enones and arylhydrazine hydrochlorides has been developed. The pyrazoles were formed via a tandem formation of the corresponding pyrazolines and an acid-catalyzed aerobic oxidation process.

• Bulletin of the Korean Chemical Society
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• v.32 no.1
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• pp.291-295
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• 2011

The catalytic enantioselective conjugate addition reaction of $\alpha$-nitroacetate to $\alpha,\beta$-unsaturated enones promoted by chiral bifunctional organocatalysts is described. The treatment of $\alpha$-nitroacetate to $\alpha,\beta$-unsaturated enones afforded the corresponding Michael adducts with high enantioselectivity. The conjugate addition adducts are easily converted to chiral $\gamma$-nitro ketones and $\delta$-keto esters.

• Bulletin of the Korean Chemical Society
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• v.8 no.3
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• pp.202-205
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• 1987

The reduction of some cyclic conjugated enones with electron-donating substituent on C-3 by sodium borohydride was accelerated on irradiation. The photo-enhanced reduction seems to undergo through zwitterionic species formed from the (n, ${\pi}^{\ast}$) triplet state of conjugated enones, followed by hydride attack to yield unsaturated or saturated alcohols.

• Bulletin of the Korean Chemical Society
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• v.33 no.6
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• pp.1825-1826
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• 2012

• Bulletin of the Korean Chemical Society
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• v.31 no.11
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• pp.3431-3433
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• 2010

• Bulletin of the Korean Chemical Society
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• v.29 no.11
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• pp.2089-2090
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• 2008

• Bulletin of the Korean Chemical Society
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• v.27 no.12
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• pp.1961-1962
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• 2006

• Bulletin of the Korean Chemical Society
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• v.3 no.2
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• pp.81-82
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• 1982

Lithium n-butylborohydride generated from n-butyllithium and borane-dimethyl sulfide complex in equimolar ratio in toluene-n-hexane is exceedingly effective for selective 1,2 reductions of enones.

• Bulletin of the Korean Chemical Society
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• v.34 no.10
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• pp.2915-2920
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• 2013

Convenient synthetic method for 4-arylethylpyrazoles and 4-styrylpyrazoles was developed using ${\alpha}$-alkenyl-${\alpha},{\beta}$-enones readily accessed from the Morita-Baylis-Hillman reaction. For the synthesis of 4-arylethylpyrazole, the reactions with arylhydrazines needed to be carried out in o-dichlorobenzene under $N_2$ balloon atmosphere. On the other hand, 4-styrylpyrazoles required the reactions in ethanol under $O_2$ balloon atmosphere.