• Title/Summary/Keyword: Enhancement of conductivity

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Photonic Crystal Effect of Nano-Patterned PEDOT:PSS Layer and Its Application to Absorption Enhancement of ZnPc Thin Films

  • Han, Ji-Young;Ryu, Il-Whan;Park, Da-Som;Kwon, Hye-Min;Yim, Sang-Gyu
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.02a
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    • pp.252-252
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    • 2012
  • It is widely accepted that short exciton diffusion lengths of organic semiconductors with respect to the film thickness limit the charge (hole and electron) separation before excitons recombination in organic photovoltaic (OPV) cells. Therefore the efficient absorption of incident light within the thin active organic layer is of great importance to improve the power conversion efficiency (PCE) of the cells. In this work, we fabricated 2-dimensionally (2D) nano-patterned poly(3,4-ethylenedioxythiophene): poly(styrenesulfonate) (PEDOST:PSS) layers using capillary phenomenon and nano-imprinting technology at the scale of several hundred nanometers. This 2D nano-patterned PEDOT:PSS layer exerted photonic crystal effect such as redirection of light paths and variation of light intensity at specified wavelengths. It is also expected that the consequently alternated light pass lengths and intensities change the absorption properties of zinc phthalocyanine (ZnPc) thin films grown on top of the nano-patterned PEDOT:PSS layer. The influence of conductivity and thickness of the PEDOT:PSS layer on the absorption properties of ZnPc thin films were also investigated.

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Removal of Heavy Metal Contaminants from Cohesive Soil by Electrokinetics (Electrokinetic 기술에 의한 점성토의 중금속 오염물 제거)

  • 정하익;강병희
    • Geotechnical Engineering
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    • v.13 no.6
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    • pp.123-138
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    • 1997
  • Electroosmotic tests were performed on saturated marine clay specimens contaminated with lead to investigate the efficiency of the electrokinetic technique for removal of heavy metals from the cohesive soils. For this purpose, testing program included variable conditions such as the concentration of lead (500, 5, 000, 50, 000mg/kg), the level of electrical current (10, 50, 100 mA), operating duration (5, 15, 30days), and the application of three dirtferent chemicals for enhancement in efficiency. The pH of inflow and outflow, electroosmotic flow and electrical conductivity during the test, and the pH and the concentration of lead across the specimen after the test are presented. Test results came to the conclusion that the electrokinetic technique was very effective to remove heavy metals such as lead from the contaminated cohesive soil. Adding ecetic acid at the cathod to dissolve the procipitates of lead hydroxide as found to be effective for the enhancement of the efficiency in remediation.

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A Study on Unit Cell Design for the Performance Enhancement in PEMFC System (PEMFC 시스템의 성능향상을 위한 단위전지 설계에 관한 연구)

  • Kim Hong-Gun;Kim Yoo-Shin;Yang Sung-Mo;Nah Seok-Chan
    • Transactions of the Korean Society of Machine Tool Engineers
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    • v.14 no.4
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    • pp.104-109
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    • 2005
  • The catalyst layer design is one of the most important factors to enhance the performance of PEMFC(Proton Exchange Membrane Fuel Cell) system. The hydrophobic and ion conductive type is studied for the MEA(Membrane Electrolyte Assembly). It is found that those have some limitations for performance enhancement when they are used separately. Thus, the dual catalyst type, a mixed model, is developed for the better MEA performance. In the meantime, the design of flow field plate is subsequently carried out in order to give more enhanced output during its operation. The conductivity of flow field plate showed better performance in the case of manufactured by the more compressed process(20MPa) than by the less compressed process(10MPa). The micro-structure of the flow field plate is examined in details using SEM(Scanning Electron Microscope) to analyse the effects on the different compression processes.

Enhancement of Cycle Performance of Lithium Secondary Batteries Based on Nano-Composite Coated PVdF Membrane

  • Ryou, Myung-Hyun;Han, Young-Dal;Lee, Je-Nam;Lee, Dong-Jin;Park, Jung-Ki
    • Journal of the Korean Electrochemical Society
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    • v.11 no.3
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    • pp.190-196
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    • 2008
  • The multilayered membrane for lithium rechargeable batteries based on poly (vinylidene fluoride) (PVdF) is prepared with the coated layer containing nano-sized filler. The prepared membranes were subjected to studies of mechanical strength, morphology, interfacial stability, impedance spectroscopy, ionic conductivity, and cycle performance. The localized inorganic filler in the PVdF composite membrane rendered mechanical strength much reduced because of its low stretching ratio and it results in around half value of the mechanical strength of highly stretched PVdF membrane. In order to achieve high ionic conductivity and interfacial stability without sacrificing high mechanical strength, coating layer with nano-filler was newly introduced to PVdF membrane. The ionic conductivity of the coated membrane was 1.03 mS/cm, and the interface between the coating layer and PVdF membrane was stable when the membrane was immersed into liquid electrolyte. The discharge capacity of the cell based on nano-filler coated PVdF membrane was around 91% of the initial discharge capacity after 250 cycles, which is an improvement in cycle performance compared to the case for the non-coated PVdF membrane.

Enhancement of Thermoelectric Performance in Spark Plasma Sintered p-Type Bi0.5Sb1.5Te3.0 Compound via Hot Isostatic Pressing (HIP) Induced Reduction of Lattice Thermal Conductivity (열간등방가압 공정을 통한 P형 Bi0.5Sb1.5Te3.0 소결체의 격자 열전도도 감소 및 열전 특성 향상)

  • Soo-Ho Jung;Ye Jin Woo;Kyung Tae Kim;Seungki Jo
    • Journal of Powder Materials
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    • v.30 no.2
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    • pp.123-129
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    • 2023
  • High-temperature and high-pressure post-processing applied to sintered thermoelectric materials can create nanoscale defects, thereby enhancing their thermoelectric performance. Here, we investigate the effect of hot isostatic pressing (HIP) as a post-processing treatment on the thermoelectric properties of p-type Bi0.5Sb1.5Te3.0 compounds sintered via spark plasma sintering. The sample post-processed via HIP maintains its electronic transport properties despite the reduced microstructural texturing. Moreover, lattice thermal conductivity is significantly reduced owing to activated phonon scattering, which can be attributed to the nanoscale defects created during HIP, resulting in an ~18% increase in peak zT value, which reaches ~1.43 at 100℃. This study validates that HIP enhances the thermoelectric performance by controlling the thermal transport without having any detrimental effects on the electronic transport properties of thermoelectric materials.

CNT and CNF reinforced carbon fiber hybrid composites by electrophoresis deposition (전기영동법에 의한 탄소나노튜브 및 탄소나노섬유 강화 탄소섬유 하이브리드 복합재료)

  • Choi, O-Young;Lee, Won-Oh;Lee, Sang-Bok;Yi, Jin-Woo;Kim, Jin-Bong;Choe, Hyeon-Seong;Byun, Joon-Hyung
    • Composites Research
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    • v.23 no.3
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    • pp.7-12
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    • 2010
  • In order to increase the electrical conductivity and the mechanical properties of carbon fabric composites, multi-walled carbon nanotubes (MWCNTs) and carbon nanofibers (CNFs) were deposited on carbon fabrics by anodic and cathodic electrophoretic deposition (EPD) processes. In the cathodic EPD, carbon nano-particles and nano-sized Cu particles were simultaneously deposited on the carbon fabric, which gave a synergetic effect on the enhancement of properties as well as the degree of deposition. The hybridization of carbon nano-particles and micron-sized carbon fiber significantly improved the through-the-thickness electrical conductivity. In addition, both MWCNTs and CNFs were deposited onto the carbon fabric for multi-scale hybrid composites. Multi-scale deposition improved the through-the-thickness electrical conductivity, compared to the deposition of either MWCNTs or CNFs.

Direct Growth of CNT on Cu Foils for Conductivity Enhancement and Their Field Emission Property Characterization (전도성 향상을 위한 구리호일 위 CNT의 직접성장 및 전계방출 특성 평가)

  • Kim, J.J.;Lim, S.T.;Kim, G.H.;Jeong, G.H.
    • Journal of the Korean Vacuum Society
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    • v.20 no.2
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    • pp.155-163
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    • 2011
  • Carbon nanotubes (CNT) have been attracted much attention since they have been expected to be used in various areas by virtue of their outstanding physical, electrical, and chemical properties. In order to make full use of their prominent electric conductivity in some areas such as electron emission sources, device interconnects, and electrodes in energy storage devices, direct growth of CNT with vertical alignment is definitely beneficial issue because they can maintain mechanical stability and high conductivity at the interface between substrates. Here, we report direct growth of vertically aligned CNT (VCNT) on Cu foils using thermal chemical vapor deposition and characterize the field emission property of the VCNT. The VCNT's height was controlled by changing the growth temperature, growth time, and catalytic layer thickness. Optimum growth condition was found to be $800^{\circ}C$ for 20 min with acetylene and hydrogen mixtures on Fe catalytic layer of 1 nm thick. The diameter of VCNT grown was smaller than that of usual multi walled CNT. Based on the result of field emission characterization, we concluded that the VCNT on Cu foils can be useful in various potential applications where high conductivity through the interface between CNT and substrate is required.

ESTIMATION OF IONOSPHERIC CONDUCTIVITY BASED ON THE MEASUREMENTS BY SUPERDARN HF RADARS AND GREENLAND MAGNETOMETERS (SUPERDARN과 GREENLAND 자력계를 이용한 전리층 전기전도도의 추정)

  • Lee, Eun-Ah;Ahn, Byung-Ho;Yi, Yu
    • Journal of Astronomy and Space Sciences
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    • v.19 no.2
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    • pp.141-150
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    • 2002
  • The ionosphere plays an important role in the electrodynamics of space environment. In particular, the information on the ionospheric conductivity distribution is indispensable in understanding the electrodynamics of the magnetosphere and ionosphere coupling study. To meet such a requirement, several attempts have been made to estimate the conductivity distribution over the polar ionosphere. As one of such attempts we compare the ionospheric plasma convection patterns obtained from the Super Dual Auroral Radar Network (SuperDARN), from which the electric field distribution is estimated, and the simultaneously measured ground magnetic disturbance. Specifically, the electric field measured from the Goose Bay and Stokkseyri radars and magnetic disturbance data obtained from the west coast chain of Greenland are compared. In order to estimate ionospheric conductivity distribution with these information, the overhead infinite sheet current approximation is employed. As expected, the Hall conductance, height-integrated conductivity, shows a wide enhancement along the center of the auroral electrojet. However, Pedersen conductance shows negative values over a wide portion of the auroral oval region, a physically unacceptable situation. To alleviate this problem, the effect of the field-aligned current is taken into account. As a result, the region with negative Pedersen conductance disappears significantly, suggesting that the effect of the field-aligned current should be taken into account, when one wants to estimate ionospheric conductance based on ground magnetic disturbance and electric field measurements by radars.

Numerical Investigation of CuO-Water Nanofluid Flow and Heat Transfer across a Heated Square Cylinder

  • Bouazizi, Lotfi;Turki, Said
    • International Journal of Fluid Machinery and Systems
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    • v.9 no.4
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    • pp.382-393
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    • 2016
  • Flow over a bluff body is an attractive research field in thermal engineering. In the present study, laminar flow over a confined heated square cylinder using CuO-Water nanofluid is considered. Unsteady two-dimensional Navier-Stokes and energy equations are solved numerically using finite volume method (FVM). Recent correlations for the thermal conductivity and viscosity of nanofluids, which are function of nanoparticle volume fraction, temperature and nanoparticle diameter, have been employed. The results of numerical solution are obtained for Richardson number, nanoparticle volume fractions and nanoparticle diameters ranges of 0-1, 1-5% and 30-100 nm respectively for a fixed Reynolds number of Re = 150. At a given volume concentration, the investigations reveal that the decreasing in size of nanoparticles produces an increase in heat transfer rates from the square cylinder and a decrease in amplitude of the lift coefficient. Also, the increment of Nusselt number is more pronounced at higher concentrations and higher Richardson numbers.

Effect of nanoparticle material for heat transfer enhancement (열전달 향상을 위한 나노물질 코팅재료의 영향에 대한 연구)

  • Jeon, Yong-Han;Kim, Nam-Jin
    • Design & Manufacturing
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    • v.13 no.1
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    • pp.42-47
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    • 2019
  • Nucleate boiling heat transfer is one of the most important phenomenon in the various industries. Especially, critical heat flux (CHF) refers to the upper limit of the pool boiling heat transfer region. Therefore, many researchers have found that CHF can be significantly increased by adding very small amounts of nanoparticles. In this study, the CHF and heat transfer coefficient were tested under the pool boiling state using copper and multi wall carbon nanotube nanoparticles. The results showed that two different types of nanoparticles deposited on the surface of two specimens made of the same material increased the heat flux in the nanoparticles with high conductivity, and there was no difference in the critical heat flux when the same material nanoparticles were deposited on the two different specimen surfaces.