• Title/Summary/Keyword: Enhanced layer

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Synthesis of Conjugated Copolymers with phenothiazine and Azomethine Units and their Electro-Optic Properties

  • Seo, Hyeon-Jin;Jang, Byeung-Jo;Chang, Jin-Gyu;Park, Lee-Soon
    • Journal of Information Display
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    • v.2 no.4
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    • pp.8-14
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    • 2001
  • Three types of conjugated polymers, poly(PZ-Pi), poly(PZ-BPI) and poly(PZ-NPI) were synthesized by Schiff-base reaction. These new conjugated polymers exhibited improved solubility in common organic solvents due to the presence of alkyl side chains as well as azomethine groups, Double layer LEDs made with the synthesized polymers as emitting layer and $Alq_3$, as electron transporting layer exhibited enhanced EL emission and efficiency compared to those of single layer LEDs. Double layer LEDs exhibited gradual shift in the emission peak th the single layer LED, made of only $Alq_3$ as the emitting layer as the thickness of $Alq_3$ layer increased.

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Diamond thin film deposition on Ni in microwave plasma CVD (Microwave plasma CVD에서 Ni 기판에 다이아몬드 박막 증착)

  • Kim, Jin-Kon;Ryu, Su-Chak;Cho, Hyun
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.12 no.6
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    • pp.311-316
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    • 2002
  • Two different approaches, namely two-step deposition process and Bias-Enhanced Nucleation (BEN) technique have been examined for deposition of high quality diamond thin film on polycrystalline Ni which has low chemical activity with the carbon neutrals provided from the $CH_4/H_2$mixtures. A two-step deposition process, consisted of pre-deposition of soot layer at lower temperatures and subsequent deposition at higher temperature condition, has been developed to deposit diamond layer directly on Ni substrate. Diamond particles were observed after deposition step at $925^{\circ}C$ for 5 hours and those particles seem to be nucleated from the soot layer pre-deposited at lower temperatures ($810^{\circ}C$). Diamond particles of a substantial size were found on Ni substrate after biasing -220 V for 10 minutes and subsequent deposition for 2 hours while no diamond particles were observed under the conditions without applied bias.

Construction of a PEALD System and Fabrication of Cobalt Thin Films (PEALD 장치 제작 및 Co박막 증착)

  • Lee, D.H.;Noh, S.J.
    • Journal of the Korean Vacuum Society
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    • v.16 no.2
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    • pp.110-115
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    • 2007
  • A plasma enhanced atomic layer deposition(PEALD) system has been constructed adopting an inductively coupled plasma(ICP) source with an ALD system, and its plasma generation was carried out. Cobalt thin films were deposited on a p-type Si(100) wafer at $230^{\circ}C$. $Co_{2}(CO)_{6}$ was used as a cobalt precursor, $NH_{3}$ as a reactant, and Ar as a carrier and purge gas. The properties of the thin films were investigated using field emission scanning electron microscopy(FESEM) and auger electron spectroscopy(AES). Large amounts of impurities were found in both the ALD film and the PEALD film, however, the amount of impurities in the PEALD film was reduced to about 50 % compared to that in the ALD film. It was found that $NH_{3}$ plasma, very effectively, induces the reaction with carbon in a cobalt precursor.

A study on reactive chlorine species generation enhanced by heterojunction structures on surface of IrO2-based anodes for water treatment (IrO2 기반 수처리용 산화 전극의 표면 이종 접합 구성에 따른 활성 염소종 발생 증진 특성 연구)

  • Hong, Sukhwa;Cho, Kangwoo
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.349-355
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    • 2018
  • This study interrogated multi-layer heterojunction anodes were interrogated for potential applications to water treatment. The multi-layer anodes with outer layers of $SnO_2/Bi_2O_3$ and/or $TiO_2/Bi_2O_3$ onto $IrO_2/Ta_2O_5$ electrodes were prepared by thermal decomposition and characterized in terms of reactive chlorine species (RCS) generation in 50 mM NaCl solutions. The $IrO_2/Ta_2O_5$ layer on Ti substrate (Anode 1) primarily served as an electron shuttle. The current efficiency (CE) and energy efficiency (EE) for RCS generation were significantly enhanced by the further coating of $SnO_2/Bi_2O_3$ (Anode 2) and $TiO_2/Bi_2O_3$ (Anode 3) layers onto the Anode 1, despite moderate losses in electrical conductivity and active surface area. The CE of the Anode 3 was found to show the highest RCS generation rate, whereas the multi-junction architecture (Anode 4, sequential coating of $IrO_2/Ta_2O_5$, $SnO_2/Bi_2O_3$, and $TiO_2/Bi_2O_3$) showed marginal improvement. The microscopic observations indicated that the outer $TiO_2/Bi_2O_3$ could form a crack-free layer by an incorporation of anatase $TiO_2$ particles, potentially increasing the service life of the anode. The results of this study are expected to broaden the usage of dimensionally stable anodes in water treatment with an enhanced RCS generation and lifetime.

Fabrication of TiO2 Thin Films Using UV-enhanced Atomic Layer Deposition at Room Temperature (자외선 활성화 원자층 성장 기술을 이용한 상온에서 TiO2 박막의 제조)

  • Lee, Byoung-H.;Sung, Myung-M.
    • Journal of the Korean Vacuum Society
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    • v.19 no.2
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    • pp.91-95
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    • 2010
  • A UV-enhanced atomic layer deposition (UV-ALD) process was developed to deposit $TiO_2$ thin films on Si substrates using titanium isopropoxide(TIP) and $H_2O$ as precursors with UV light. In the UV-ALD process, the surface reactions were found to be self-limiting and complementary enough to yield a uniform, conformal, pure $TiO_2$ thin film on Si substrates at room temperature. The UV light was very effective to obtain the high-quality $TiO_2$ thin films with good adhesive strength on Si substrates. The UV-ALD process was applied to produce uniform and conformal $TiO_2$ coats into deep trenches with high aspect ratio.

Chemically enhanced steam cleaning for the control of ceramic membrane fouling caused by manganese and humic acid (망간과 휴믹산에 의한 세라믹 막 오염의 제어를 위한 약품 스팀세정의 적용)

  • An, Sun-A;Park, Cheol-Gyu;Lee, Jin-San;Kim, Han-Seung
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.6
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    • pp.425-436
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    • 2021
  • In this study, chemically enhanced steam cleaning(CESC) was applied as a novel and efficient method for the control of organic and inorganic fouling in ceramic membrane filtration. The constant filtration regression model and the resistance in series model(RISM) were used to investigate the membrane fouling mechanisms. For total filtration, the coefficient of determination(R2) with an approximate value of 1 was obtained in the intermediate blocking model which is considered as the dominant contamination mechanism. In addition, most of the coefficient values showed similar values and this means that the complex fouling was formed during the filtration period. In the RISM, R c/R f increased about 4.37 times in chemically enhanced steam cleaning compared to physical backwashing, which implies that the internal fouling resistance was converted to cake layer resistance, so that the membrane fouling hardly to be removed by physical backwashing could be efficiently removed by chemically enhanced steam cleaning. The results of flux recovery rate showed that high-temperature steam may loosen the structure of the membrane cake layer due to the increase in diffusivity and solubility of chemicals and finally enhance the cleaning effect. As a consequence, it is expected that chemically enhanced steam cleaning can drastically improve the efficiency of membrane filtration process when the characteristics of the foulant are identified.

Molecular Aligning Properties of a Dielectric Layer of Polymer-Ceramic Nanocomposite for Organic Thin-Film Transistors

  • Kim, Chi-Hwan;Kim, Sung-Jin;Yu, Chang-Jae;Lee, Sin-Doo
    • 한국정보디스플레이학회:학술대회논문집
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    • 2004.08a
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    • pp.1200-1203
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    • 2004
  • We investigated the molecular aligning capability of a polymer layer containing ceramic nanoparticles which can be used as a gate insulator of organic thin-film transistors (OTFTs). Because of the enhanced dielectric properties arising from the nanoparticles and molecular aligning properties of the polymer, the composite layer provides excellent mobility characteristics of the OTFTs.

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Bistable Switching Behaviors of One-dimensional Nonlinear Photonic Crystal with Ken Medium (일차원 Ken 비선형 광결정의 쌍안정 스위칭 특성)

  • Kim, Dalwllo;Lixue Chen
    • Proceedings of the Optical Society of Korea Conference
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    • 2002.07a
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    • pp.94-95
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    • 2002
  • Photonic crystal (PC) has special interests for their promising applications in three-dimensional photon control and integrated devices. In a nonlinear photonic crystal (NPC), optical intensity in a defect layer is greatly increased due to the location function of NPC and nonlinearity. The nonliearity of the defect layer is very much enhanced because the group velocity is reduced and the interaction time between light and nonlinear medium in the defect layer is enlarged. (omitted)

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Electroluminescence characteristics of organic light-emitting diodes with TPD doped PVK as the hole transport layer

  • Shin, Y.C.;Song, J.H.;Lee, C.H.
    • 한국정보디스플레이학회:학술대회논문집
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    • 2005.07b
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    • pp.1404-1407
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    • 2005
  • We have fabricated organic light-emitting diodes using poly(N-vinylcarbazole)(PVK) doped with N,N'- diphenyl-N,N'-bis(3-methylphenyl)-[l,l'-biphenyl]- 4,4/-diamine (TPD) as the hole transport layer. TPD molecules act as the trapping sites in PVK and reduce the hole mobility, which can enhance the electronhole balance in the emitting layer, resulting in the enhanced device performance. We have found the optimum ratio of TPD to PVK for the EL efficiency.

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Enhanced Fuzzy Multi-Layer Perceptron

  • Kim, Kwang-Baek;Park, Choong-Sik;Abhjit Pandya
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2004.05a
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    • pp.1-5
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    • 2004
  • In this paper, we propose a novel approach for evolving the architecture of a multi-layer neural network. Our method uses combined ART1 algorithm and Max-Min neural network to self-generate nodes in the hidden layer. We have applied the. proposed method to the problem of recognizing ID number in student identity cards. Experimental results with a real database show that the proposed method has better performance than a conventional neural network.

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