• Title/Summary/Keyword: Engineering polymer

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Deformation Behavior and Nucleation Activity of a Thermotropic Liquid­Crystalline Polymer in Poly(butylene terephthalate)-Based Composites

  • Kim Jun Young;Kang Seong Wook;Kim Seong Hun;Kim Byoung Chul;Shim Kwang Bo;Lee Jung Gyu
    • Macromolecular Research
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    • v.13 no.1
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    • pp.19-29
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    • 2005
  • Polymer composites based on a thermotropic liquid-crystalline polymer (TLCP) and poly(butylene terephthalate) (PBT) were prepared using a melt blending process. Polymer composites consisting of bulk cheap polyester with a small quantity of expensive TLCP are of interest from a commercial perspective. The interactions between the PBT chains and the flexible poly(ethylene terephthalate) (PET) units in the TLCP phase resulted in an improvement in the compatibility of PBT/TLCP composites. TLCP droplets deformed and fragmented into smaller droplets in the PBT/TLCP composites, which resulted in TLCP fibrillation through the effective deformation of the TLCP droplets. The nucleation activities of the PBT/TLCP composites increased by adding even a small amount of the TLCP component.

Preparation and Properties of Polyolefin Graft Polymer available as a Primer for Polyurethane Adhesive (I) Synthesis of polyolefins with cyclic acid anhydride by free radical graft polymerization

  • Ryu, Ki Jung;Kim, Min Jung;Min, Seong Kee;Lee, Won Kee;Park, Chan Young
    • Elastomers and Composites
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    • v.50 no.2
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    • pp.119-125
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    • 2015
  • Because of their low surface free energy and absence of polar groups at the surface, polyolefins are substrates whose wetting and adhesion are very difficult. Free radical grafting of monomers to backbone polymer is one of the most attractive ways for the chemical modification of polymers. Synthesis of graft copolymer through graft polymerizations of PE and/or PP with phthalic anhydride (PhAn) was made and FTIR spectra of the graft polymer were the examined. And also the effects of phthalic anhydride content on the grafting ratio, thermal properties and contact angle of the graft polymer were examined.

Fluorescence Spectroscopic and Atomic Force Microscopic Studies on the Microstructure of Polyimide/Silica-Titania Ternary Hybrid Composites

  • Park, Hae-Dong;Ahn, Ki-Youl;Mohammad A. Wahab;Jo, Nam-Ju;Kim, Il;Kim, Gyuhyun;Lee, Won-Ki;Ha, Chang-Sik
    • Macromolecular Research
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    • v.11 no.3
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    • pp.172-177
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    • 2003
  • Biphenyltetracarboximide-phenylene diamine polyimide/silica-titania ternary hybrid composites were Prepared by thermal imidization and sol-gel reaction. Fluorescence spectroscopic, scanning electron microscopy, and atomic force microscopy studies revealed that the addition of small amount of titania showed profound effects on the microstructure and photophysical behaviors of polyimide/silica hybrid composites, when the content of silica-titania mixture was small or when the ratio of silica to titania in the mixture was high.

Self-Healing Asphalt Prepared by using Ionic Epoxy Resin

  • Lee, Young-Jik;Seo, Jun-Young;Kim, Seo-Yeon;Lee, Seung-Hyun;Hong, Young-Keun
    • Elastomers and Composites
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    • v.50 no.3
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    • pp.167-174
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    • 2015
  • Anionic epoxy compound was synthesized and added to asphalt aiming to prepare self-healing asphalt. Epoxy-modified asphalt showed excellent modification effect and healing effect as well. The results revealed that with 5% addition of polymer the tensile strength, impact strength and complex shear modulus of the polymer-modified asphalt increased by 65%. 64% and 35%, respectively. It seems that high interaction occurs between polymer and asphalt matrix. Self-healing efficiency of the polymer-modified asphalt based on tensile strength showed 100%, comparing to 79% of straight asphalt. In impact experiment the polymer-modified asphalt showed 99% of healing efficiency, comparing to 77% of straight asphalt. In rheological experiment the polymer-modified asphalt showed 103% of healing efficiency, comparing to 72% of straight asphalt. It appears that the ionic bonding existing in epoxy polymers contributed to high values of self-healing efficiency. The polymer which has high intermolecular force fills the crack of the asphalt, pulling the opponent side each other, and so the original properties were restored.

Temperature dependent electro-optical studies of liquid crystal in Fringe Field Switching (FFS), In-plane switching (IPS), and Patterned Vertical Alignment (PVA) modes

  • Jo, Eun-Mi;Srivastava, Anoop Kumar;Kim, Mi-Young;Kim, Sung-Min;Lee, Seung-Hee;Ji, Seung-Hoon;Lee, Gi-Dong
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.320-323
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    • 2008
  • In this paper, electro-optical characteristic of Nematic Liquid crystal (LC) with varying temperature in different LCD modes, namely Fringe Field Switching (FFS), In-plane switching (IPS), and Patterned Vertical Alignment (PVA) modes are investigated and compared. Electro optic me asurements suggest that rate of change of transmission with temperature in FFS mode was lowest and much more thermally stable as compared to IPS and PVA m odes. However the electro-optical characteristic of patterned vertical alignment (PVA) mode was most affected by changing temperature. The measured threshold voltage was found to be much more thermally stable in FFS and IPS modes than that of PVA mode.

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Temperature Dependence of the Electro-optic Characteristics in the Liquid Crystal Display Switching Modes

  • Jeon, Eun-Jeong;Srivastava, Anoop Kumar;Kim, Mi-Young;Jeong, Kwang-Un;Choi, Jeong-Min;Lee, Gi-Dong;Lee, Seung-Hee
    • Journal of Information Display
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    • v.10 no.4
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    • pp.175-179
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    • 2009
  • As the physical properties of nematic liquid crystals vary with respect to temperature, the performances of liquid crystal displays (LCDs) are highly dependent on temperature. Additionally, it is well known that the electro-optic characteristics of LCDs, such as transmittance and threshold voltage, also rely on the LCD switching modes. The temperature dependence of the electro-optic characteristics of the wide-viewing-angle LCD modes, such as in-plane switching (IPS), multidomain vertical alignment by patterned electrode (PVA), and fringe-field switching (FFS), have been studied, and the results showed that the FFS mode has lower temperature dependence compared to the IPS and PVA modes. Since the liquid crystal (LC) reorients in different ways in each mode, this result is associated with the temperature dependence of LC's bend and twist elastic constants, and also with the position of the main reorientation, either in the middle or on the surface of the LC layer.

Sensing and Interfacial Evaluation of Ni Nanowire Strands/Polymer Composites using Electro-micromechanical Technique (Electro-Micromechanical 시험법을 이용한 Ni Nanowire Strands 강화 고분자 복합재료의 Sensing과 계면 물성 평가)

  • Kim, Sung-Ju;Jung, Jin-Gyu;Park, Joung-Man
    • Proceedings of the Korean Society For Composite Materials Conference
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    • 2005.11a
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    • pp.141-144
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    • 2005
  • Sensing and interfacial evaluation of Ni nanowire strands/polymer composites were investigated using Electro-micromechanical technique. Electro-micromechanical techniques can be used as sensing method for micro damage, loading, temperature of interfacial properties. Using Ni nanowire strands/silicone composites with different content, load sensing response of electrical contact resistivity was investigated under tensile and compression condition. The mechanical properties of Ni nanowire strands with different type/epoxy composites were measured using uniformed cyclic loading and tensile test. Ni nanowire strands/epoxy composites showed humidity and temperature sensing within limited ranges, 20 vol% reinforcement. Some new information on temperature and humidity sensing plus loading sensing of Ni nanowire strands/polymer composites could be obtained from the electrical resistance measurement as a new concept of the nondestructive interfacial evaluation.

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Molecular Dynamics Simulation Study on the Carbon NanotubeInteracting with a Polymer

  • Saha, Leton C.;Mian, Shabeer A.;Jang, Joon-Kyung
    • Bulletin of the Korean Chemical Society
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    • v.33 no.3
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    • pp.893-896
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    • 2012
  • Using molecular dynamics simulation method, we studied the carbon nanotube (CNT) non-covalently interacting with a polymer. As the polymer coiled around the CNT, the diameter of CNT deformed by more than 40% of its original value within 50 ps. By considering three different polymers, we conclude that the interaction between the CNT and polymer is governed by the number of repeating units in the polymer, not by the molecular weight of polymer.