• Journal of Electrochemical Science and Technology
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• v.15 no.3
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• pp.353-364
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• 2024

Through component regulation and morphological construction, it is of considerable significance to develop high-activity and high-stability electrocatalyst for hydrogen evolution in electrolytic water. In the hydrothermal process, Mo-doped nickel-based sulfide catalysts (Mo-NiS-Fx) with a variety of morphologies (prisms, rods, flakes, and cones) were created by adding NH₄F with varying masses. Among these, the flaky Mo-NiS-F1.2 exhibited exceptional performance towards electrochemical hydrogen evolution reaction, surpassing most similar catalysts with an overpotential of 79 mV at 10 mA cm^-2 and a Tafel slope of 49.8 mV dec^-1. Significantly, Mo-NiS-F1.2 maintained its high activity for hydrogen evolution over 60 h at a current density of 10 mA cm^-2, making it suitable for widespread commercial application. According to the experimental findings, an electrocatalyst with a high surface area and a porous structure is better suited to exposing more gas transfer routes and active sites, which would encourage the hydrogen evolution reaction. This study presents a straightforward procedure for creating electrocatalysts with a range of morphologies, which can serve as a model for the creation of catalysts for use in industrial manufacturing.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.182-190
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• 2017

All liquids contain a small amount of gaseous components and the amount of gases dissolved in a liquid is in accordance with Henry's Law. In a multi-stage thermal-type seawater desalination plant, as the supplied seawater undergoes variations in temperature and pressure in each evaporator, the gases dissolved in the seawater are discharged from the liquid. The discharged gases are carbon dioxide, nitrogen, oxygen, and argon, and these emitted gases are non-condensable. From the viewpoint of convective heat transfer, the evaluation of non-condensable gas released during a vacuum evaporation process is a very important design factor because the non-condensable gases degrade the performance of the cooler. Furthermore, in a thermal-type seawater desalination plant, most evaporators operate under vacuum, which maintained through vacuum system such as a steam ejector or a vacuum pump. Therefore, for the proper design of a vacuum system, estimating the non-condensable gases released from seawater is highly crucial. In the study, non-condensable gases released in a thermal-type seawater desalination plant were calculated quantitatively. The calculation results showed that the NCG releasing rate decreased as the stage comes getting a downstream and it was proportional to the freshwater production rate.

• Applied Chemistry for Engineering
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• v.33 no.6
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• pp.636-645
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• 2022

In this study, we investigated the adsorption characteristics of methyl orange (MO), an anionic dye, on ginkgo shell-based activated carbon (AC). For this purpose, ACs (GS-1, GS-2, and GS-4) with different textural properties were prepared using ginkgo shells and potassium hydroxide (KOH), a representative chemical activating agent. The correlation between the textural characteristics of AC prepared and the mixing ratio of KOH was investigated using nitrogen adsorption/desorption isotherms. The MO adsorption equilibrium experiment on the prepared ACs was conducted under different pH (pH 3~11) and temperature (298~318 K) conditions, and the results were investigated by Langmuir, Freundlich, Sips and temperature-dependent Sips equations. The feasibility of the MO adsorption treatment process of the prepared AC was also investigated using the dimensionless Langmuir separation factor. The heterogeneous adsorption properties of MO for the prepared AC examined using the adsorption energy distribution function (AED) were closely related to the system temperature and textural characteristics of AC. The kinetic results of the batch adsorption performed at different temperatures can be satisfactorily explained by the homogeneous surface diffusion model (HSDM), which takes into account the external mass transfer, intraparticle diffusion, and active site adsorption. The relationship between the activation energy value obtained by the Arrhenius plot and the adsorption energy distribution function value was also investigated. In addition, the adsorption process mechanism of MO on the prepared AC was evaluated using Biot number.

• Atmosphere
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• v.27 no.4
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• pp.385-398
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• 2017

Numerical weather prediction experiments were carried out by applying topographic effects to reduce or enhance the solar radiation by terrain. In this study, x and ${\kappa}({\phi}_o,\;{\theta}_o)$ are precalculated for topographic effect on high resolution numerical weather prediction (NWP) with 1 km spatial resolution, and meteorological variables are analyzed through the numerical experiments. For the numerical simulations, cases were selected in winter (CASE 1) and summer (CASE 2). In the CASE 2, topographic effect was observed on the southward surface to enhance the solar energy reaching the surface, and enhance surface temperature and temperature at 2 m. Especially, the surface temperature is changed sensitively due to the change of the solar energy on the surface, but the change of the precipitation is difficult to match of topographic effect. As a result of the verification using Korea Meteorological Administration (KMA) Automated Weather System (AWS) data on Seoul metropolitan area, the topographic effect is very weak in the winter case. In the CASE 1, the improvement of accuracy was numerically confirmed by decreasing the bias and RMSE (Root mean square error) of temperature at 2 m, wind speed at 10 m and relative humidity. However, the accuracy of rainfall prediction (Threat score (TS), BIAS, equitable threat score (ETS)) with topographic effect is decreased compared to without topographic effect. It is analyzed that the topographic effect improves the solar radiation on surface and affect the enhancements of surface temperature, 2 meter temperature, wind speed, and PBL height.

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1703-1706
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• 1996

The purpose of this study is to research and develop polypyrrole(PPy) positive for thin film rechargeable lithium battery. We investigated cyclic voltammetry, AC impedance response and charge/discharge cycling of PPy/SPE/Li cells as a function of temperature. The redox capacity of $PPy/CF_{3}SO_{3}$ film was the most large. The discharge capacity of PPy/SPE/Li cell with $PPy/CF_{3}SO_{3}$ film was higher than those of $PPy/ClO_{4}$ and $PPy/AsF_6$ films at all cycles. The energy density of PPy/SPE/Li cells during 1st cycle was 73, 90 and 101Wh/kg at $25^{\circ}C$, $45^{\circ}C$ and $60^{\circ}C$, respectively. The improvement of energy density is due to reduction of charge-transfer resistance associated doping-undoping process in PPy film with Increasing temperature. $PPy/CF_{3}SO_{3}$ film shows a good property on charge/discharge cycling in PEO-$LiClO_4$-PC-EC electrolyte.

• Journal of the Korean Society for Marine Environment & Energy
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• v.12 no.3
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• pp.209-216
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• 2009

IMO has established International Convention for the Control and Management of Ships' Ballast Water and Sediment 2004 in February 2004 in order to prevent transfer of aquatic organisms through ballast water. According to the Convention, Each countries are preparing ratification and legislation process and encouraging the development of treatment system to satisfy the performance standard in the Convention. This Electro-$Cleen^{TM}$ treatment system was granted IMO basic approval in March 2006, and final approval in October 2008. The Type Approval Certificate was issued in December 2008 by the Government of Republic of Korea. This paper considers the matter of principle mechanism, overview of the system, installation on shipboard and shipboard test results for the Electro-$Cleen^{TM}$. Shipboard tests with the 8300 GT M/V Yokohama and 27,000 DWT M/V Greenwing have already been conducted. These tests confirmed that the Electro-$Cleen^{TM}$ system satisfies all of the IMO standards and is suitable for installation in new and existing ships.

• Environmental Engineering Research
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• v.17 no.2
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• pp.83-88
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• 2012

Currently, the technology of $CO_2$ capture and storage (CCS) has become the main issue for climate change and global warming. Among CCS technologies, the prediction of $CO_2$ behavior underground is very critical for $CO_2$ storage design, especially for its safety. Hence, the purpose of this paper is to model and simulate $CO_2$ flow and its heat transfer characteristics in a storage site, for more accurate evaluation of the safety for $CO_2$ storage process. In the present study, as part of the storage design, a micro pore-scale model was developed to mimic real porous structure, and computational fluid dynamics was applied to calculate the $CO_2$ flow and thermal fields in the micro pore-scale porous structure. Three different configurations of 3-dimensional (3D) micro-pore structures were developed, and compared. In particular, the technique of assigning random pore size in 3D porous media was considered. For the computation, physical conditions such as temperature and pressure were set up, equivalent to the underground condition at which the $CO_2$ fluid was injected. From the results, the characteristics of the flow and thermal fields of $CO_2$ were scrutinized, and the influence of the configuration of the micro-pore structure on the flow and scalar transport was investigated.

• Journal of the Korean Society for Geothermal and Hydrothermal Energy
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• v.8 no.2
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• pp.1-8
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• 2012

The G-class cement is usually used for geothermal well grouting to protect a steel casing which is equipped in a geothermal well to transfer geothermal water from deep subsurface to ground surface. In geothermal grouting process, obtaining appropriate fluidity is extremely important in order to fill cement grout flawlessly. In this paper, a series of the V-funnel and Slump Flow test was performed on both of the Portland cement and the G-class cement in order to compare fluidity and filling ability of those kind of cements. In the result of V-funnel test, the fluidity of G-class cement was evaluated much better than the Portland cement at the water/cement ratio of 0.8. In the case of Slump Flow test, the fluidity of G- class cement was estimated slightly better than the Portland cement at both the water/cement ratio of 0.55 and 0.8. Even though the initial fluidity and filling ability of G-class cement were relatively higher than the Portland cement, the results could be considerably changed with time. The results show that the fluidity and filling ability for geothermal well cementation can be properly controlled with water content and additives for adverse geothermal well environment.

• Journal of Hydrogen and New Energy
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• v.24 no.1
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• pp.36-43
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• 2013

In this paper, a three-dimensional hydrogen desorption model is applied to a thin double-layered annulus ZrCo hydride bed and validated against the temperature evolution data measured by Kang et al. The present model reasonably captures the bed temperature evolution behavior and the 90% hydrogen discharging time. In addition, the performance of thin double-layered annulus bed is evaluated by comparing with a simple cylindrical bed using hydrogen desorption model. This study provides multi-dimensional contours such as temperature and H/M atomic ratio in the metal hydride region. This numerical study provides fundamental understanding during hydrogen desorption process and indicates that efficient design of the metal hydride bed is critical to achieve rapid hydrogen discharging performance. The present three-dimensional hydrogen desorption model is a useful tool for the optimization of bed design and operating conditions.

• Korean Journal of Materials Research
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• v.31 no.10
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• pp.552-561
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• 2021

For the purpose of manufacturing a high efficiency TiO₂ photocatalyst, B-doped TiO₂ photocatalysts are synthesized using a plasma electrolytic oxidation method in 0.5 M H₂SO₄ electrolyte with different concentrations of H₃BO₃ as additive. For the B doped TiO₂ layer fabricated from sulfuric electrolyte having a higher concentration of H₃BO₃ additive, the main XRD peaks of (101) and (200) anatase phase shift gradually toward the lower angle direction, indicating volume expansion of the TiO₂ anatase lattice by incorporation of boron, when compared with TiO₂ layers formed in sulfuric acid with lower concentration of additive. Moreover, XPS results indicate that the center of the binding energy peak of B1s increases from 191.45 eV to 191.98 eV, which suggests that most of boron atoms are doped interstitially in the TiO₂ layer rather than substitutionally. The B doped TiO₂ catalyst fabricated in sulfuric electrolyte with 1.0 M H₃BO₃ exhibits enhanced photocurrent response, and high efficiency and rate constant for dye degradation, which is ascribed to the synergistic effect of the new impurity energy band induced by introducing boron to the interstitial site and the improvement of charge transfer reaction.