• Title/Summary/Keyword: Energy recycling

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Methane Fermentation of Pit in Pond System for Ecological Treatment and Recycling of Animal Excreta (생태적 축산폐수 처리 및 재활용 연못시스템의 Pit 메탄발효)

  • Yang, Hong-Mo
    • Korean Journal of Environmental Agriculture
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    • v.18 no.2
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    • pp.191-195
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    • 1999
  • An integrated wastewater treatment pond system is developed for treatment and recycling of excreta from dairy cattle. It is composed of three ponds in series. A pit with a capacity of $10m^3$, 2-day hydraulic residence time, and overflow velocity of $1.5m^3m^{-2}day^{-1}$ is located internally in primary pond. It is designed for efficient sludge sedimentation and effective methane fermentation. It receives $5m^3/day$ of diluted cattle excreta by the water used for clearing stalls. A submerged gays collector for the recovery of methane is installed on the top of the pit. The average BOD_5 concentration of influent is 398.7mg/l. That of the effluent from primary pond is 49.2mg/l. About 88% of BOD_5 are removed in primary pond. It is assumed that about 60% of the influent BOD_5 is removed in the pit and that almost all of the carbon of the removed BOD_5 in the pit is converted to methane and carbon dioxide. Methane fermentation of the pit is well established at $16^{\circ}C$. This phenomena results from temperature stability, complete anaerobic condition, and neutral pH of the pit. Gas from the collector is almost 90% methane, less than 9% nitrogen, and less than 1% carbon dioxide. Thus a purified methane is produced, which can be used as energy source.

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A Study on the Liberation Characteristics of Waste Concrete for Production of High Quality Recycled Aggregate (고품질(高品質) 순환골재(循環骨材) 생산(生産)을 위한 폐콘크리트의 단체분리(單體分離) 특성(特性) 연구(硏究))

  • Kim, Kwan-Ho;Mun, Myoung-Wook;Cho, Hee-Chan;Ahn, Ji-Whan
    • Resources Recycling
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    • v.19 no.3
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    • pp.52-61
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    • 2010
  • In general, the waste concrete is simply crushed and reused as a recycled aggregate at a low value application such as back filling material. It because that the quality of recycled aggregate is lower than one of natural aggregate due to the insufficient liberation of aggregate and cement mortar. So in this study, the liberation characteristics of liberation of aggregate and cement mortar is analyzed to investigate the limitation of conventional crushing stage at waste concrete processing circuit. In this process, thermal treatment method is evaluated for the enhancement of liberation. From test results, the preferential breakage along the grain boundary is not accomplished by the conventional crushers. It leads a low quality of recycled aggregate and a fracture of aggregate. To solve these problems, gentle breakage is used as a breakage mechanism to induce preferential breakage along the grain boundary. The recycled aggregate produced from the free fall test, which adopts a gentle breakage, shows a better liberation characteristics and a higher quality.

Compression Strength Behavior of Mixed Soil Recycling Bottom Ash for Surface Layer Hardening (매립석탄회를 재활용한 표층연약지반 개량용 혼합토의 압축강도 특성 연구)

  • Oh, Gi-dae;Kim, Kyoung Yul
    • KEPCO Journal on Electric Power and Energy
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    • v.5 no.4
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    • pp.287-293
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    • 2019
  • Domestic thermal power plant fly ash is at a situation which emissions are increasing every year. Comparing to Fly Ash, Bottom Ash is only 15 %, but it's recycling rate is low, so most of them is being buried in the ground. However, landfill site of every power plant is full, and the construction of a new landfill is difficult. To solve this problem, the best solution is to use Bottom Ash as a landfill of large-scale civil engineering projects. The purpose of this study was to investigate the compression strength behavior characteristics of weak clay and uniaxial compression test to examine the applicability of surface soil solidification method of mixed soils mixed with industrial waste coal ash and weak clay which is buried in bulk. As a result of the test, the fluidity of the Mixed soil with clay + bottom ash + cement was improved to 200 mm at the water content of 91-92 %. The uniaxial compressive strength was also good for the mixed soils (clay + bottom ash + cement) meeting the required strength of 159 kN/㎡ at 28 days. However, the other samples did not meet the required strength. In this study, the prediction equations for the compression strength behavior by cement and curing period were presented.

Characteristics of Carbidization for Iron Ore Fines with a Wide Size Range (입도분포가 넓은 분철광석의 탄화특성)

  • Hwang Ho-Sun;Chung Uoo-Chang;Chung Won-Sub;Chung Won-Bae
    • Resources Recycling
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    • v.12 no.5
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    • pp.42-49
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    • 2003
  • Characteristics of reduction and carbidization for hematite ore with a wide size range have been investigated at high temperature(590∼64$0^{\circ}C$) under $H_2$ and $H_2$-CO gas mixtures. The apparent activation energy for reduction of hematite ore with H2 gas was found to be 20 kJ/mol. The weight loss by reduction was about 28% md the weight gain by carbidization was about 5%. The measured values of weight change were compared with those calculated from equation (3) & (5) and fairly good agreement was obtained. The rate of carbidization was increased with an decrease in temperature, particle diameter and gas ratio($H_2$/ CO). The free carbon was increased with decrease in gas ratio($H_2$/ CO). The rate of carbidization was increased with mixing of $H_2$ gas but this effect was not proportional to fraction of $H_2$ gas. It was also found that the rate of carbidization was the maximum in the $H_2$ gas fraction of 0.5. It is considered that $H_2$ plays a part as a catalyst for formation of iron carbide($Fe_3$C).

The Extraction of Ca in Electric arc Furnace Slag for CO2 Sequestration (CO2고정화(固定化)를 위한 전기로제강(電氣爐製鋼)슬래그의 칼슘성분(成分) 침출(浸出))

  • Youn, Ki-Byoung
    • Resources Recycling
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    • v.22 no.1
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    • pp.64-71
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    • 2013
  • Mineral carbonation has been proposed as a possible way for $CO_2$ sequestration. The electric arc furnace slags consist of calcium, magnesium and aluminum silicates in various combinations. If they could be used instead of natural mineral silicates for carbonation, considerable energy savings and $CO_2$ emissions reductions could be achieved. Indirect aqueous carbonation of the slags consists of two steps, extraction of calcium and carbonation. Acetic acid leaching of electric arc furnace slags had been already studied to extract Ca in them, but it was reported that the carbonation of the extracted $Ca^{2+}$ in the leached solution would suffer from too slow kinetics, even at high pressure of $CO_2$. In this work, to develop more efficient extraction of the electric arc furnace slags, hydrochloric acid leaching to separate calcium from them was studied, and the results were compared with the acetic acid ones. The phase boundary between $Ca^{2+}$ and $CaCO_3$ in the solution with pH was determined by thermodynamic calculations. Hydrochloric acid was more effective than acetic acid for the extraction of Ca in electric arc furnace slag, and there is a possibility to recycle an unreacted hydrochloric acid in the leached solution by electrolysis or evaporation.

Adsorption/Desorption Characteristics of Vanadium from Ammonium Metavanadate using Anion Exchange Resin (음(陰)이온교환수지(交換樹脂)를 이용한 Ammonium Metavanadate로부터 바나듐 흡탈착(吸脫着) 특성(特性))

  • Jeon, Jong Hyuk;Kim, Young Hun;Hwang, In Sung;Lee, Jin Young;Kim, Joon Soo;Han, Choon
    • Resources Recycling
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    • v.22 no.1
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    • pp.55-63
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    • 2013
  • Considering considerable contents of vanadium and tungsten in spent SCR DeNOx catalysts, separation and recovery of those metals are required. In this respect, commercial anion exchange resin (MP600) was employed to recover vanadium from the synthetic solution of ammonium metavanadate. Experimental results indicated that vanadium exist as anion under the acidic condition (pH 2 ~ 6) and adsorbed on the resin. Although the adsorption rate was increased with temperature, the maximum amount of adsorption was not affected by temperature. Desorption took place under either strong acidic (less than pH 1) or strong caustic (higher than pH 13) condition. However, desorption seldom took place under moderate conditions (pH 3~11). Furthermore, adsorption equilibrium results agreed well with Freundlich isotherm and pseudo-second-order reactions. And, adsorption energy was evaluated using Dubinin-Radushkevich and Temkin isotherm.

Application of Phytoremediation for Total Nitrogen and Total Phosphorus Removal from Treated Swine Wastewater and Bio-methane Potential of the Biomass (돈분뇨 처리수 유래 질소와 인 제거를 위한 식물정화법 활용과 바이오매스의 바이오메탄 잠재성 연구)

  • Sudiarto, Sartika Indah Amalia;Choi, Hong Lim;Renggaman, Anriansyah
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.21-31
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    • 2015
  • The aim of this study is to determine the removal efficiency of total nitrogen and phosphorus from treated swine wastewater by Phragmites australis and Miscanthus sacchariflorus var Geode Uksae-1, and to determine its biomass total energy value and biomethane potential. Plants were grown with a bedding mixture either soil and sand or soil, sand, and bioceramic. Treeated swine wastewater with Total nitrogen (TN) and Total phosphorus (TP) of 222.78 mg/L and 66.11 mg/L, respectively, was utilized. The TN and TP removal is higher in the bio-ceramic-soil-sand bedding media treatment. The highest TN removal of 96.14% was performed by Miscanthus sacchariflorus var Geode Uksae-1, but the elemental analysis shows that Phragmites australis contains more nitrogen than Miscanthus sacchariflorus var Geode Uksae-1, indicating higher nitrogen uptake. The highest TP removal of 98.12% was performed by Phragmites australis. The cellulose content of the plant grown with the bioceramic-soil-sand bedding was approximately 3-6% higher than that of the plant grown in the soil-sand bedding. Different growing substrates may have an effect on the fiber content of plants. The biomethane potential of the produced biomass of the plants was between 57.01 and $99.25L-CH_4/kg$ VS. The lignin content is believed to inhibit the breakdown of plant biomass, resulting in the lowest methane production in the Phragmites australis grown in the soil-sand bedding media.

Information Management System of Solid Waste Landfill based on 3 Dimensional Method (3차원기법을 이용한 폐기물매립지 정보관리시스템 구축 연구)

  • Park, Jin-Kyu;Cho, Sung-Youn;Kim, Byung-Tae;Lee, Nam-Hoon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.24 no.4
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    • pp.39-48
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    • 2016
  • An information management system for a solid waste landfill site was developed, in this study, to optimize the operation and management of solid waste landfill in real time in addition to provide the information of landfill status to the landfill operator, public official concerned and local residents. The landfill information management system is composed of two systems (Solid waste landfill history management system and landfill operation and performance management system). The solid waste landfill history management system based on automated RFID/LPR system allows landfill operators to provide information of waste collection vehicles and received waste. In addition, the system aids in the identification of 3-dimensional (3D) position for landfilled solid wastes. Using the landfill operation and performance management system based on 3D laser scanner delivers information about landfill volume, settlement, landfill density, and current landfill capacity to landfill operators in real time, resulting in optimum space utilization. Ultimately, this system would dramatically reduce exposure of landfill operators to hazardous materials and improve the productivity of landfill operations.

Environmental impact evaluation and improvement measure of incineration plant by life cycle assessment (전과정평가를 이용한 소각시설의 환경영향평가 및 개선방안)

  • Kim, Hyeong-Woo;Kim, Kyeong-Ho;Park, Hung-Suck
    • Journal of the Korea Organic Resources Recycling Association
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    • v.21 no.4
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    • pp.88-100
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    • 2013
  • This study evaluated the direct and indirect environmental impacts of various unit operations of a industrial waste incineration plant by using the life cycle assessment tool and reviewed the improvement plan. During the incineration process, the direct environmental impact was decreased with decrease in emission of various air pollutants by incorporating an air pollution prevention facilities. However, an increase in indirect environmental impacts was observed as a consequence of resources and energy of consumption at the various operational facilities. Consequently, quantitative direct and indirect impact were 89.1%, 10.9%, respectively. The environmental impact analysis of system revealed the highest impact of incineration followed by the impacts of other unit processes such as semidry reactor, and bag-filter. The various air pollutants and ashes generated during the incineration process caused the most significant environmental impact. Among the various categories of environmental impact, global warming accounted the highest impact(more than 85%) followed by eutrophication, and abiotic depletion. As a result of the avoided impact by the utilization of heat generated during the waste incineration process, using an incineration heat for steam and electricity obtained the impact reduction of 45.5%, 19.8%. So, during siting of new incineration plant, the utilization of steam generated from the waste combustion is highly considered to reduce the environmental impact.

SRF Conversion Potential of Biomass and Mixed Plastic Waste Generated in D City (D시 내에서 발생하는 바이오매스 및 폐플라스틱 혼합 폐기물의 SRF 전환 포텐셜 분석)

  • Yang, Han-Sol;Kim, Ki-Kwang;Lim, Chae-Wook;Hyun, Jae-Hyuk
    • Journal of the Korea Organic Resources Recycling Association
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    • v.26 no.3
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    • pp.55-61
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    • 2018
  • This study evaluated if the selected samples meets the Solid Refuse Fuel quality criteria in Korea. Biomass and plastic wastes generated in D City were mixed in diverse ratio. When the biomass content was about 40%, the moisture content was close to the SRF criteria and was measured to be 9.8%. The ash contents were analyzed up to 4.19%, and the lower calorific values based on Steuer, Dulong Equation and Bomb Calorimeter were at least 4,851, 4,181 and 3,847 kcal/kg, respectively. As a result of the elemental analysis, sulfur and chloride content were measured up to 0.05%. Those values satisfied the SRF criteria. Also, heavy metals(Hg, Cd, Pb, As) were analyzed to be below the SRF criteria. This makes it possible to use efficiently the wood byproducts abandoned in the woods, and the physical properties of wood being weak to moisture can be supplemented with plastics. Consequently, if plastic and biomass were well mixed and made into SRF, it would overcome the problem of shortening the life span of incineration facilities due to the high temperature of plastic wastes in the incinerator.