• Title/Summary/Keyword: Energy injection

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An Improved Manufacturing Method of p-Dicyclopentadiene (DCPD) using Tungsten Type Catalyst in Air Condition (대기 조건에서 경화가 가능한 텅스텐계 p-DCPD의 개선된 성형 방법)

  • Kwon, Dong-Jun;Shin, Pyeong-Su;Kim, Jong-Hyun;Park, Joung-Man
    • Composites Research
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    • v.29 no.4
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    • pp.216-222
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    • 2016
  • Ring-opening metathesis polymerization of p-dicyclopentadiene (DCPD) can be performed using the tungsten type catalyst. This reaction usually progresses in nitrogen condition, because the catalysts are extremely sensitive in air condition. To solve this problem, DCPD resin with tungsten (W) was cured using hot press after stirring of DCPD A and B liquid in air condition. Mechanical properties of DCPD were improved by reducing microvoid occurrence successfully by using hot press method. It might be because hot press could provide sufficient press on DCPD specimen. Addition of catalyst was not effective for the curing of resin in a short time. During polymerization, pressure and temperature had a great influence on the mechanical properties of DCPD.

Optimum Remediation Conditions of Vertical Electrokinetic-Flushing Equipment to Decontaminate a Radioactive Soil (방사성토양 복원을 위한 수직형 동전기-세정장치의 최적제염조건 도출)

  • Kim, Gye-Nam;Yang, Byeong-Il;Moon, Jei-Kwon;Lee, Kune-Woo
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.7 no.3
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    • pp.153-160
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    • 2009
  • Vertical electrokintic-flushing remediation equipment was developed for the remediation of a radioactive soil near nuclear facilities. An optimum reagent was selected to decontaminate the radioactive soil near nuclear facilities with the developed vertical electrokintic-flushing remediation equipment, and the optimum remediation conditions were established to obtain a higher remediation efficiency. Namely, acetic acid was selected as an optimum reagent due to its higher remediation efficiency. When the electrokinetic remediation and the electrokinetic-flushing remediation results were compared, the removal efficiency of 4.6% and the soil waste solution volume of 1.5 times were increased in the electrokinetic remediation. When the potential gradient within an electrokinetic soil cell was increased by two times (4.0 V/cm), the removal efficiencies of $Co^{2+}$ and $Cs^+$ were increased by about 4.3%($Co^{2+}$ : 98.9%, $Cs^+$ : 96.7%). Also, when the reagent concentration was increased from 0.01M to 0.05M, the removal efficiency of $Co^{2+}$ was increased but that of $Cs^+$ was decreased. Therefore, the optimum remediation conditions were that the acetic concentration was $0.01M{\sim}0.05M$, the potential gredient was 4 V/cm, the injection of reagent 2.4ml/g, and the remediation period was 20days.

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Solid-liquid Separation Characteristics of Membrane Filter Press according to Coagulant Properties of Anaerobic Digestion Waste Water (혐기소화폐액의 응집제 특성에 따른 멤브레인 필터프레스의 고액분리 특성)

  • Han, Seong Kuk;Jung, Hee Suk;Song, Hyoung Woon;Kim, Ho;Ahn, Dae Hyun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.22 no.3
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    • pp.23-32
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    • 2014
  • Recently, it is increase in the processing of organic waste using anaerobic digestion. Therefore, the studies on the processing method for increasing the anaerobic digestion waste water. But it is very difficult to solid-liquid separation, because the characteristics of anaerobic digestion waste water. So this study evaluate solid-liquid separation efficiency of anaerobic digestion sludge using CST(Capillary Suction Time), TTF(Time to Filter). To address this problem, a membrane filter press of the lab scale was produced and the anaerobic digestion wastewater was applied to it. Polymer coagulants were found to be most suitable 7192PLUS and 1T60, It is necessary to minimum injection concentration is 7192PLUS (200 mg/L), 1T60 (100 mg/L). To evaluate dehydration efficiency, it was measured the moisture content of the dehydrated cake and suspended solids of decanted water. As a result, showed that a high removal efficiency of 97.4% when the solid-liquid separation using the membrane filter press. And the moisture content of the dehydrated cake was less than 65%.

A Basic Study on Separation of U and Nd From LiCl-KCl-UCl3-NdCl3 System (LiCl-KCl-UCl3-NdCl3 system에서 U 및 Nd 분리에 관한 기초연구)

  • Kim, Tack-Jin;Ahn, Do-Hee;Eun, Hee-Chul;Lee, Sung-Jai
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.1
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    • pp.59-64
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    • 2018
  • In case of high contents of rare earths in the LiCl-KCl salt, it is not easy to recover U and TRU metals as a usable resource form from LiCl-KCl eutectic salts generated from the pyroprocessing of spent nuclear fuel. In this study, a conversion of $UCl_3$ into an oxide form using $K_2CO_3$ and an electrodeposition of $NdCl_3$ into a metal form in $LiCl-KCl-UCl_3-NdCl_3$ system were conducted to resolve the problem. Before conducting the conversion, experimental conditions for the conversion were determined by performing a thermodynamic equilibrium calculation. In this study, almost all of $UCl_3$ disappeared in the LiCl-KCl salt when the injection of $K_2CO_3$ reached theoretical equivalent for the conversion, and then $NdCl_3$ was effectively electrodeposited as a metal form using liquid zinc cathode. After that, the LiCl-KCl salt became transparent, and uranium oxides were precipitated to the bottom of the LiCl-KCl salt. These results will be utilized in designing a process to separate U and rare earths in LiCl-KCl salt.

Introduction to Researches on the Characteristics of Gas Migration Behavior in Bentonite Buffer (벤토나이트 완충재 내 기체 이동의 거동 특성 관련 연구 동향 소개)

  • Kang, Sinhang;Kim, Jung-Tae;Lee, Changsoo;Kim, Jin-Seoup
    • Tunnel and Underground Space
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    • v.31 no.5
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    • pp.333-359
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    • 2021
  • Gases such as hydrogen and radon can be generated around the canister in high-level radioactive waste disposal systems due to several reasons including the corrosion of metal materials. When the gas generation rate exceeds the gas diffusion rate in the low-permeability bentonite buffer, the gas phase will form and accumulate in the engineered barrier system. If the gas pressure exceeds the gas entry pressure, gas can migrate into the bentonite buffer, resulting in pathway dilation flow and advective flow. Because a sudden occurrence of dilation flow can cause radionuclide leakage out of the engineered barrier of the radioactive waste disposal system, it is necessary to understand the gas migration behavior in the bentonite buffer to quantitatively evaluate the long-term safety of the engineered barrier. Experimental research investigating the characteristics of gas migration in saturated bentonite and research developing numerical models capable of simulating such behaviors are being actively conducted worldwide. In this technical note, previous gas injection experiments and the numerical models proposed to verify such behaviors are introduced, and the future challenges necessary for the investigation of gas migration are summarized.

Experimental Study on Fracture Pressure, Permeability Enhancement and Fracture Propagation using Different Fracture Fluids (다양한 파쇄 유체별 파쇄압력, 투과도 증진 및 균열전파에 관한 실험적 연구)

  • Choi, JunHyung;Lee, Hyun Suk;Kim, Do Young;Nam, Jung Hun;Lee, Dae Sung
    • Tunnel and Underground Space
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    • v.31 no.1
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    • pp.41-51
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    • 2021
  • The hydraulic fracturing developed to improve permeability of tight reservoir is one of key stimulation technologies for developing unconventional resources such as shale gas and deep geothermal energy. The experimental study was conducted to improve disadvantage of hydraulic fracturing which has simple fracture pattern and poor fracturing efficiency. The fracturing experiments was conducted for tight rock using various fracturing fluids, water, N2, and CO2 and the created fracture pattern and fracturing efficiency was analyzed depending on fracturing fluids. The borehole pressure increased rapidly and then made fractures for hydraulic fracturing with constant injection rate, however, gas fracturing shows slowly increased pressure and less fracture pressure. The 3D tomography technic was used to generate images of induced fracture using hydraulic and gas fracturing. The stimulated reservoir volume (SRV) was estimated increment of 5.71% (water), 12.72% (N2), and 43.82% (CO2) respectively compared to initial pore volume. In addition, permeability measurement was carried out before and after fracturing experiments and the enhanced permeability by gas fracturing showed higher than hydraulic fracturing. The fracture conductivity was measured by increasing confining stress to consider newly creating fracture and closing induced fracture right after fracturing. When the confining stress was increased from 2MPa to 10MPa, the initial permeability was decreased by 89% (N2) and 50% (CO2) respectively. This study shows that the gas fracturing makes more permeability enhancement and less reduction of induced fracture conductivity than hydraulic fracturing.

Photovoltaic Properties of Organic Solar Cell using Zinc phthalocyanine(ZnPc)/$C_{60}$ devices (Zinc phthalocyanine(ZnPc)/$C_(60)$ 소자를 이용한 유기 광소자의 광기전특성)

  • Lee, Ho-Sik;Hur, Sung-Woo;Lee, Won-Jae;Shin, Hoon-Kyu;Kim, Tae-Wan;Kwon, Young-Soo
    • Proceedings of the KIEE Conference
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    • 2004.07c
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    • pp.1712-1714
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    • 2004
  • During the last 20 years organic semiconductors have attracted considerable attention due to their interesting physical properties followed by various technological applications in the area of electronics and opto-electronics. It has been a long time since organic solar cells were expected as a low-cost energy-conversion device. Although practical use of them has not been achieved, technological progress continues. Morphology of the materials, organic/inorganic interface, metal cathodes, molecular packing and structural properties of the donor and acceptor layers are essential for photovoltaic response. We have fabricated solar cell devices based on zinc-phthalocyanine(ZnPc) as donor(D) and fullerine($C_{60}$) as electron acceptor(A) with doped charge transport layers, $Alq_3$ as an electron transport or injection layer. We observed the photovoltaic characteristics of the solar cell devices using the Xe lamp as a light source.

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Effects of Flos Sophora japonica Extract on the Changes of Cerebral Hemodynamics

  • Rha, Young-Ah;Lee, Woo-Sik;Park, Sung-Jin
    • Culinary science and hospitality research
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    • v.20 no.5
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    • pp.67-70
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    • 2014
  • The purpose of this study was to measure the changes of regional cerebral blood flow(rCBF) and blood pressure(BP) in rats, following the intravenous injection of Flos Sophora japonica L.(FSJ) water extract. The measurement was continually monitored by Laser-Doppler Flowmeter and pressure transducer in anaesthetized adult Sprague-Dawley rats for 2 hours to 2 hours and a half through the data acquisition system. FSJ increased the changes of rCBF in rat significantly. The rCBF of FSJ did not change by pretreated propranolol, atropine, L-NNA($N^G$-nitro-L-argininine) and indomethacin. But the rCBF of Flos Sophora japonica L. was increased by pretreated methylene blue. FSJ decreased the changes of BP, significantly. The BP of FSJ did not change by pretreated propranolol, atropine, L-NNA and indomethacin. But the BP FSJ was decreased by pretreated methylene blue. There results indicated that FSJ can increase the rCBF and decrease the BP, that is related to guanylyl cyclase activity.

A Novel Flyback-type Utility Interactive Inverter for AC Module Systems

  • Shimizu Toshihisa;Nakamura Naoki;Wada Keiji
    • Proceedings of the KIPE Conference
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    • 2001.10a
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    • pp.518-522
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    • 2001
  • In recent years, natural energy has attracted growing interest because of environmental concerns. Many studies have been focused on photovoltaic power generation systems because of the ease of use in urban areas. On the conventional system, many photovoltaic modules (PV modules) are connected in series in order to obtain the sufficient DC-bus voltage for generating AC output voltage at the inverter circuit. However, the total generation power on the PV modules sometimes decreases remarkably because of the shadows that partially cover the PV modules. In order to overcome this drawback, an AC module strategy is proposed. On this system, a small power DC-AC utility interactive inverter is mounted on each PV module individually and the inverter operates so as to generate the maximum power from the corresponding PV module. This paper presents a novel flyback-type utility interactive inverter circuit suitable for AC module systems. The feature of the proposed system are, (1) small in volume and light in weight, (2) stable AC current injection, (3) enabling a small DC capacitor. The effectiveness of the proposed system is clarified through the simulation and the experiments.

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A Study on The Reduction of Fuel Oil Consumption for Fishing Boat Engine (어선기관의 연료유 절감에 관한 연구)

  • 이창호
    • Journal of Advanced Marine Engineering and Technology
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    • v.5 no.1
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    • pp.12-19
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    • 1981
  • As the fuel oil cost covers from 45% to 60% of the total expenditure for fishing boat operation, the energy saving is now an urgent problem to be taken a countermeasure for engineers, manufacturers or specialists engaging in this field. Undertaking a second-hand engine of the trainging ship, the author made several reconstructions to restore its performances. By inserting foot linears of connecting rods the compression ratio was increased and by adjusting both the fuel injection timing and the cooling water outlet temperature, its thermal efficiency was improved. The results of the experimental operation were summarized as follows. 1. By raising the piston top position 0.75mm more than the value of the operating manual, the compression pressure increased 1.3 kg/$cm^2$ and the maximum pressure did 3.4 kg/$cm^2$ at 75% load. 2. At 75% load, the difference of the maximum pressure between each cylinder was decreased from 2.4 kg/$cm^2$ to 1.8 kg/$cm^2$. 3. The fuel consumption was decreased about 8 g/ps.h at 75% load, and about 5.3 g/ps.h at 85% load. 4. The brake thermal efficiency was improved about 1.5% at 75% load and 0.9% at 85% load.

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