• Title/Summary/Keyword: Energy Equation

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Green synthesis of Lead-Nickel-Copper nanocomposite for radiation shielding

  • B.M. Chandrika;Holaly Chandrashekara Shastry Manjunatha;R. Munirathnam;K.N. Sridhar;L. Seenappa;S. Manjunatha;A.J. Clement Lourduraj
    • Nuclear Engineering and Technology
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    • v.55 no.12
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    • pp.4671-4677
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    • 2023
  • For the first time Pb, Ni, and Cu nanocomposites were synthesized by versatile solution combustion synthesis using Aloevera extract as a reducing agent, to study the potential applications in X-ray/gamma, neutron, and Bremsstrahlung shielding. The synthesized Lead-Nickel-Copper (LNC) nanocomposites were characterized by PXRD, SEM, UV-VIS, and FTIR for the confirmation of successful synthesis. PXRD analysis confirmed the formation of multiphase LNC NCs and the Scherrer equation and the W-H plot gave the average crystal sizes of 19 nm and 17 nm. Surface morphology using SEM and EDX confirmed the presence of LNC NCs. Strong absorption peaks were analyzed by UV visible spectroscopy and the direct energy gap is found to be 3.083 eV. Functional groups present in the LNC NCs were analyzed by FTIR spectroscopy. X-ray/gamma radiation shielding properties were measured using NaI(Tl) detector coupled with MCA. It is found to be very close to Pb. Neutron shielding parameters were compared with traditional shielding materials and found LNC NCs are better than lead and concrete. Secondary radiation shielding known as Bremsstrahlung shielding characteristics also studied and found that LNC NCs are best in secondary radiation shielding. Hence LNC NCs find shielding applications in ionizing radiation such as X-ray/gamma and neutron radiation.

Performance enhancement of base-isolated structures on soft foundation based on smart material-inerter synergism

  • Feng Wang;Liyuan Cao;Chunxiang Li
    • Earthquakes and Structures
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    • v.27 no.1
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    • pp.1-15
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    • 2024
  • In order to enhance the seismic performance of base-isolated structures on soft foundations, the hybrid system of base-isolated system (BIS) and shape memory alloy inerter (SMAI), referred to as BIS+SMAI, is for the first time here proposed. Considering the nonlinear hysteretic relationships of both the isolation layer and SMA, and soil-structure interaction (SSI), the equivalent linearized state space equation is established of the structure-BIS+SMAI system. The displacement variance based on the H2 norm is then formulated for the structure with BIS+SMAI. Employing the particle swarm optimization, the optimization design methodology of BIS+SMAI is presented in the frequency domain. The evolvement rules of BIS+SMAI in the effectiveness, robustness, SMA driving force, inertia force, stroke, and damping enhancement effect are revealed in the frequency domain through changing the inerter-mass ratio, structural height, aspect ratio, and relative stiffness ratio between the soil and structure. Meanwhile, the validation of BIS+SMAI is conducted using real earthquake records. Results demonstrate that BIS+SMAI can effectively reduce the isolation layer displacement. The inerter can significantly increase the hysteretic displacement of SMA and thus enhance its energy dissipation capacity, implying that BIS+SMAI has better effectiveness than BIS+SMA. Although BIS+SMAI and BIS+ tuned inerter damper (TID) have practically the same effectiveness, BIS+SMAI has the lower optimum damping, significantly smaller inertia force, and higher robustness to perturbations of the optimum parameters. Therefore, BIS+SMAI can be used as a more engineering realizable hybrid system for enhancing the performance of base-isolated structures in soft soil areas.

The Change in Geotechnical Properties of Clay Liner and the Contamination Behavior of Groundwater Due to Contaminant (오염물질에 의한 점토 차수재의 역학적 특성변화 및 지하수 오염거동)

  • Ha, Kwang-Hyun;Lee, Sang-Eun;Chung, Sung-Rae;Chun, Byung-Sik
    • Journal of Soil and Groundwater Environment
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    • v.13 no.1
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    • pp.13-23
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    • 2008
  • The triaxial compression tests and consolidation tests using NaCl solution and leachates as substitute pore (or saturated) water in samples were carried out to find out the behavior characteristics of strength, deformation and permeability coefficient of contaminated clay. Also, the chemical property analysis on the clay samples using scanning electron microscope and energy dispersive x-ray spectrometer were involved. The magnitudes of composition ratio were shown in the order of O, C, Si, Al, and Fe as a result of chemical composition analysis for clay samples. Besides, as the results of triaxial compression tests and consolidation tests, the shear strength, compression and permeability properties were increased with increasing in the concentration of contaminant (NaCl). It may be considered that these circumstances be caused by the changes of soil structure to flocculent structure due to the decrease in the thickness of diffuse double layer with increasing in the concentration of electrolyte. MT3D model was also using to grasp the procedures that the groundwater may be contaminated by the leachates permeated through the clay liner. The results of contaminant transport analysis showed a tendency that the predicted concentration of groundwater was higher with increasing in the initial concentration of $Cl^-$ ion and increased as a nonlinear curves with time. The transportation distance calculated by the use of regression equation between the distance from contaminant source and the concentration of $Cl^-$ ion was increased with increasing the initial concentration.

Estimation of Potential Evapotranspiration using LAI (LAI를 고려한 잠재증발산량 추정)

  • Kim, Joo-Hun;Kim, Kyung-Tak
    • Journal of the Korean Association of Geographic Information Studies
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    • v.8 no.4
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    • pp.1-13
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    • 2005
  • In the process of a hydrology circulation, evapotranspiration is considered a very important factor to build a plan for the development of water resources and to operate water resources system. This study purposes to estimate daily potential evapotranspiration quantity in consideration of energy factors of the surface by using spatial information such as Landsat TM (ETM+) data, DEM and Landcover. Kyounan-cheon, Han River is selected as a target area, and landcover is divided by vegetation and non-vegetation covered area. Penman-Monteith equation which considers leaf-area index is used to estimate potential evapotranspiration quantity of vegetation covered area. The combination method (energy burget and aerodynamic method) is used in non-vegetation covered area. Among the input data for estimating potential evapotranspiration, NDVI, SR and Albedo is formed by Landsat, TM and ETM+ from 1986 through 2002. ground heat flux is estimated by using NDVI distribution map, LAI distribution map is drawn by using SR distribution map. The result of estimation shows that the average potential evapotranspiration in the whole basin is about 1.8-3.2mm/day per each cell. THe results of estimating potential evapotranspiration quantity by each landcover are as follows; water surface 3.6-4.9mm/day, city 1.4-3.1mm/day, bareland 1.4-3.5mm/day, grassland 1.7-3.7mm/day, forest 1.7-3.0mm/day and farmland 1.8-3.6mm/day. The potential evapotranspiration quantity is underestimated in comparison with observed evaporation data by evaporation pan, but it is considered that it has physical propriety.

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Adsorption Characteristics and Parameters of Acid Black and Quinoline Yellow by Activated Carbon (활성탄에 의한 Acid Black과 Quinoline Yellow의 흡착특성 및 파라미터)

  • Yi, Kyung Ho;Hwang, Eun Jin;Baek, Woo Seung;Lee, Jong-Jib;Dong, Jong-In
    • Clean Technology
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    • v.26 no.3
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    • pp.186-195
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    • 2020
  • The isothermal adsorption, dynamic, and thermodynamic parameters of Acid black (AB) and Quinoline yellow (QY) adsorption by activated carbon were investigated using the initial concentration, contact time, temperature, and pH of the dyes as adsorption parameters. The adsorption equilibrium data fits the Freundlich isothermal adsorption model, and the calculated Freundlich separation factor values found that activated carbon can effectively remove AB and QY. Comparing the kinetic data showed that the pseudo second order model was within 10% error in the adsorption process. The intraparticle diffusion equation results were divided into two straight lines. Since the slope of the intraparticle diffusion line was smaller than the slope of the boundary layer diffusion line, it was confirmed that intraparticle diffusion was the rate-controlling step. The thermodynamic experiments indicated that the activation energies of AB and QY were 19.87 kJ mol-1 and 14.17 kJ mol-1, which corresponded with the physical adsorption process (5 ~ 40 kJ mol-1). The adsorption reaction was spontaneous because the free energy change in the adsorption of AB and QY by activated carbon was negative from 298 to 318 K. As the temperature increased, the free energy value decreased resulting in higher spontaneity. Adsorption of AB and QY by activated carbon showed the highest adsorption removal rate at pH 3 due to the effect of anions generated by dissociation. The adsorption mechanism was electrostatic attraction.

Assessment of Vibration Produced by the Grinder Used in the Shipbuilding Industry and Development of Prospective Prevalence Model of Hand-arm Vibration Syndrome (선박건조업에서 사용되는 그라인더의 진동평가와 수지진동증후군 예측 모델 개발)

  • Yim, Sanghyuk;Lee, Yunkeun;Park, Hee-Sok
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.16 no.4
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    • pp.398-412
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    • 2006
  • The purpose of this study is to investigate the relationship between the acceleration of vibration by the powered hand tools used in the shipbuilding industry, and to develop the prospective prevalence model for the hand-arm vibration syndrome among the shipbuilding workers.The acceleration levels and frequencies of six types of grinder were measured using the ISO5349 method along with the time of exposure to the vibration from the powered hand tools. Medical examination for 114 workers were performed using the cold provocation test. Comparisons were made between the estimated prevalence of hand-arm vibration syndrome from ISO5349 and the observed values from the medical examinations. By multiple regression, we developed the prospective prevalence model of hand-arm vibration syndrome produced by the hand tools used in the shipbuilding industry. 4 hour-energy-equivalent frequency-weighted accelerations were $6.23m/s^2$ in the grinding job done after welding, and $13.39m/s^2$ in the grinding job done before painting. The mean exposure time while holding powered hand tools was 4.64 hours. Prevalence rates of Raynaud's Phenomenon were 12.04% in the grinding after soldering, and 42.9% in the grinding before painting measured using the ISO5349 method. After exposure to vibration for 10.79 years, about a half of the workers in the grinding after welding could developed Raynaud's Phenomenon. For the workers in the grinding before painting, the latency was 5.02 years. The ISO equation for dose response relationship was not significantly correlated with observed recovery rates of finger skin temperatures, blood flows and amplitudes of nerve conduction velocities. A multiple regression model for dose-response relationship was proposed from the results. Recovery rate of the skin temperatures = -0.668+ 0.337 ${\times}$ 4 hour energy equivalent frequency-weighted accelerations + 0.767 ${\times}$ duration of vibration exposure(years) The validity was proved by multiple regression analysis after correlation transformation and regression results based on model-building data and validation data.

Comparison and Evaluation of Dynamic Modulus of Hot Mix Asphalt with Different Shift Factors (전이함수 결정법에 따른 아스팔트 혼합물의 동탄성계수 비교평가)

  • Kim, Hyun-Oh;Lee, Kwan-Ho
    • International Journal of Highway Engineering
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    • v.7 no.1 s.23
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    • pp.49-61
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    • 2005
  • The dynamic modulus of hot mix asphalt can be determined according to the different combinations of testing temperature and loading frequency. The superposition rule is adapted to get the master curve of dynamic modulus for each hot mix asphalt. There are couple of different methods to get the shift factor which is a key for making the master curve. In this paper, Arrehnius, 2002 AASHTO, and experimental method was employed to get the master curve. Evaluation of dynamic modulus for 25mm base course of hot mix asphalt with granite aggregate and two asphalt binders(AP-3 and AP-5) was carried out. Superpave Level 1 Mix Design with gyratory compactor was adopted to determine the optimum asphalt binder content(OAC) and the measured ranges of OAC were between 4.1% and 4.4%. UTM was used for laboratory test. The dynamic modulus and phase angle were determined by testing on UTM, with 5 different testing temperature(-10, 5, 20, 40, & $55^{\circ}C$) and 5 different loading frequencies(0.05, 0.1, 1, 10, 25 Hz). Using the measured dynamic modulus and phase angle, the input parameters of Sigmoidal function equation to represent the master curve were determined and these will be adopted in FEM analysis for asphalt pavements. The shift factor and activation energy for determination of master curve were calculated.

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Estimation of Surface Fluxes Using Noah LSM and Assessment of the Applicability in Korean Peninsula (Noah LSM을 이용한 지표 플럭스 산정 및 한반도에서의 적용성 검토)

  • Jang, Ehsun;Moon, Heewon;Hwang, Seok Hwan;Choi, Minha
    • Journal of Wetlands Research
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    • v.15 no.4
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    • pp.509-518
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    • 2013
  • Understanding of the exchange between the water and energy which is happening between the surface and atmosphere is the basic of studying water resources. To study these, lots of researches using Noah Land Surface Model(LSM) are in progress. Noah LSM is based on energy and water balance equation and simulates various hydrological factors. There are diverse researches with Noah LSM are ongoing in overseas, on the other hand not enough study has been done. Especially there is almost no study using uncoupled Noah LSM in Korea. In this study we used data from Korea Flux Tower in Haenam(HFK) and Gwangneung(GDK) as forcing data to simulate the model and compared its result of net radiation, sensible heat flux and latent heat flux with the observation data to assess the applicability of Noah LSM in Korea. Regression coefficients of the comparison results of Noah LSM and observation show good agreement with the value of 0.83~0.99 at Haenam and 0.64~0.99 at Gwangneung which means Noah LSM can be trusted.

Effect of the Inner Pressure on a Hybrid Composite Flywheel Retor (하이브리드 복합재 플라이휠 로터에 작용하는 내압의 효과)

  • Oh Je-Hoon;Han Sang-Chul;Kim Myung-Hoon;Ha Sung Kyu
    • Composites Research
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    • v.18 no.1
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    • pp.45-54
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    • 2005
  • The delamination in the filament-wound composite flywheel rotor often lowers the performance of the flywheel energy storage system. A conventional ring type hub usually causes tensile stresses on the inner surface of the composite rotor, resulting in lowering the maximum rotational speed of the rotor. In this work, the stress and strain distributions within a hybrid composite rotor were derived from the two-dimensional governing equation with the specified boundary conditions, and an optimum pressure at the inner surface of the rotor was proposed to minimize the strength ratio and maximize the storage energy. A split type hub was introduced to apply the calculated optimum pressure at the inner surface, and a spin test was performed up to 40,000 rpm to demonstrate the performance of the split type hub with radial and circumferential strains measured using a wireless telemetry system. From the analysis and the test, it was found that the split type hub successfully generates a compressive pressure on the inner surface of the rotor, which can enhance the performance of the composite rotor by lowering the strength ratio within the rotor.

Internal Confining Stress of Internally Confined Hollow Columns under Compressive Load (압축을 받는 내부 구속 중공 RC 기둥의 내부 구속력)

  • Won, Deok Hee;Han, Taek Hee;Kim, Seungjun;Kang, Young Jong
    • Journal of Korean Society of Steel Construction
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    • v.25 no.3
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    • pp.243-254
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    • 2013
  • Internally Confined Hollow RC(ICH RC) column consisted of concrete, transverse reinforcement, longitudinal reinforcement, and inner tube. It had good strength and ductility by core concrete was become triaxial confining state with transverse reinforcement and inner tube. There were two confining stress as external confining stress and internal confining stress in an ICH RC column. While external confining stress was researched by former researchers, internal confining stress has not researched. In this paper, confining stress of both Hollow RC column and ICH RC column was investigated using FEA program. Relation between theoretical confining stress and internal confining stress was drawn by analysis results. Modified failure condition equations of inner tube were suggested to base on failure condition equations of inner tube by former researcher. When thickness of inner tube was calculated by modified equations, it could be economic because thickness of inner tube was reduced 50% compared with former researcher equations in order to same confining stress.