Kim, Jungchul;Shin, Jeong Heon;Kim, Dong Ho;Choi, Jun Seok;Yoon, Seok Ho
Transactions of the Korean Society of Mechanical Engineers B
/
v.41
no.11
/
pp.767-773
/
2017
Printed Circuit Heat Exchanger (PCHE) has an advantage for exchanging thermal energy between high-pressure and high-temperature fluids because its core is made by diffusion bonding method of accumulated metal thin-plates which are engraved of flow channel. Moreover, because it is possible that the flow channel can be micro-size hydraulic diameter, the heat transfer area per unit volume can be made larger than traditional heat exchanger. Therefore, PCHE can have higher efficiency of heat transfer. The smaller channel size can make the larger heat transfer area per unit volume. But if high pressure fluid flows inside the channel, the channel wall can be deformed, the structure and shape of flow channel and header have to be designed appropriately. In this study, the design methodology of PCHE channel in high pressure environment based on pressure vessel codes was investigated. And this methodology was validated by computational analysis.
A concrete silo plays an important role in subsurface low- and intermediate-level waste facilities (LILW) by limiting the release of radionuclides from the silo geosphere. However, due to several physical and chemical processes the performance of the concrete structure decreases over time and consequently the concrete loses its effectiveness as a barrier against groundwater inflow and the release of radionuclides. Although a number of processes are responsible for degradation of the silo concrete, it is determined that the main cause is corrosion of the reinforcing steel. Therefore, the time it takes for the silo concrete to fail is calculated based on two factors: the initiation time of corrosion, defined as the time it takes for chloride ions to penetrate through the concrete cover, and the propagation time of corrosion. This paper aims to estimate the time taken for concrete to fail in a LILW disposal facility. Based on the United States Department of Energy (DOE) approach, which indicates that concrete fails completely once 50% of the volume of the reinforcing steel corrodes, the corrosion propagation time is calculated to be 640 years, which is the time it takes for corrosion to penetrate 0.640 cm into the reinforcing steel. In addition to the corrosion propagation time, a diffusion equation is used to calculate the initiation time of corrosion, yielding a time of 1284 years, which post-dates the closure time of the LILW disposal facility if we also consider the 640 years of corrosion propagation. The electrochemical conditions of the passive rebar surface were modified using an acceleration method. This is a useful approach because it can reduce the test time significantly by accelerating the transport of chlorides. Using instrumental analysis, the physicochemical properties of corrosion products were determined, thereby confirming that corrosion occurred, although we did not observe significant cracks in, or expansion of, the concrete. These results are consistent with those of Smartet al., 2006 who reported that corrosion products are easily compressed, meaning that cracks cannot be discerned by eye. Therefore, it is worth noting that rebar corrosion does not strongly influence the hydraulic conductivity of the concrete.
Journal of the Korea Academia-Industrial cooperation Society
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v.10
no.12
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pp.3740-3747
/
2009
To protect the citizens' health of Gyeongju and to secure basic data for the assessment of health and environmental risk, distribution characteristics of meteorological elements were investigated and numerical simulation of wind field using RAMS model was carried out. In addition, measurement and analysis of air pollutants, forecasting the behavior air pollutants using ISC-AEROMOD view, and health and environmental risk-influenced zones were defined through managing air polluting materials to prevent health damage and property damage. According to the survey results of air pollution in Gyeongju and surroundings, average annual concentration of air pollutants in Gyeongju was slightly lower than that in Pohang and Ulsan areas, but concentration of particulate matters and nitrogen dioxide at Gyeongju Station Square and Yonggang Crossing were sometimes higher than that in Pohang and Ulsan areas. Results of the modeling of moving and diffusion of air pollutants that affect citizens' health showed that parts of the 1st through 4th industrial complexes together with POSCO were included in particulate matters and sulfur dioxide influenced areas in Pohang Steel Complex area, and that Haedo-dong, Sangdae-dong, Jecheol-dong and Jangheung-dong in Pohangnam-gu represented locally worsened air quality due to a quantity of air pollutant emission from dense steel industries and large scale industrial facilities.
Yu, Hye-Weon;Song, Jun-Ho;Kim, Chang-Min;Yang, Euntae;Kim, In S.
Membrane Journal
/
v.28
no.1
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pp.75-82
/
2018
Forward osmosis (FO) desalination system has been highlighted to improve the energy efficiency and drive down the carbon footprint of current reverse osmosis (RO) desalination technology. To improve the trade-off between water flux and salt rejection of thin film composite (TFC) desalination membrane, thin film nanocomposite membranes (TFN), in which nanomaterials as a filler are embeded within a polymeric matrix, are being explored to tailor the separation performance and add new functionality to membranes for water purification applications. The objective of this article is to develop a graphene nanocomposite membrane with high performance of water selective permeability (high water flux, high salt rejection, and low reverse solute diffusion) as a next-generation FO desalination membrane. For advances in fabrication of graphene oxide (GO) membranes, layer-by-layer (LBL) technique was used to control the desirable structure, alignment, and chemical functionality that can lead to ultrahigh-permeability membranes due to highly selective transport of water molecules. In this study, the GO nanocomposite membrane fabricated by LBL dip coating method showed high water flux ($J_w/{\Delta}{\pi}=2.51LMH/bar$), water selectivity ($J_w/J_s=8.3L/g$), and salt rejection (99.5%) as well as high stability in aqueous solution and under FO operation condition.
Proceedings of the Materials Research Society of Korea Conference
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2011.10a
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pp.7-7
/
2011
Quantum beam technology has been expected to develop breakthroughs for nanotechnology during the third basic plan of science and technology (2006~2010). Recently, Green- or Life Innovations has taken over the national interests in the fourth basic science and technology plan (2011~2015). The NIMS (National Institute for Materials Science) has been conducting the corresponding mid-term research plans, as well as other national projects, such as nano-Green project (Global Research for Environment and Energy based on Nanomaterials science). In this lecture, the research trends in Japan and NIMS are firstly reviewed, and the typical achievements are highlighted over key nanotechnology fields. As one of the key nanotechnologies, the quantum beam research in NIMS focused on synchrotron radiation, neutron beams and ion/atom beams, having complementary attributes. The facilities used are SPring-8, nuclear reactor JRR-3, pulsed neutron source J-PARC and ion-laser-combined beams as well as excited atomic beams. Materials studied are typically fuel cell materials, superconducting/magnetic/multi-ferroic materials, quasicrystals, thermoelectric materials, precipitation-hardened steels, nanoparticle-dispersed materials. Here, we introduce a few topics of neutron scattering and ion beam nanofabrication. For neutron powder diffraction, the NIMS has developed multi-purpose pattern fitting software, post RIETAN2000. An ionic conductor, doped Pr2NiO4, which is a candidate for fuel-cell material, was analyzed by neutron powder diffraction with the software developed. The nuclear-density distribution derived revealed the two-dimensional network of the diffusion paths of oxygen ions at high temperatures. Using the high sensitivity of neutron beams for light elements, hydrogen states in a precipitation-strengthened steel were successfully evaluated. The small-angle neutron scattering (SANS) demonstrated the sensitive detection of hydrogen atoms trapped at the interfaces of nano-sized NbC. This result provides evidence for hydrogen embrittlement due to trapped hydrogen at precipitates. The ion beam technology can give novel functionality on a nano-scale and is targeting applications in plasmonics, ultra-fast optical communications, high-density recording and bio-patterning. The technologies developed are an ion-and-laser combined irradiation method for spatial control of nanoparticles, and a nano-masked ion irradiation method for patterning. Furthermore, we succeeded in implanting a wide-area nanopattern using nano-masks of anodic porous alumina. The patterning of ion implantation will be further applied for controlling protein adhesivity of biopolymers. It has thus been demonstrated that the quantum beam-based nanotechnology will lead the innovations both for nano-characterization and nano-fabrication.
Journal of the Korean Society of Food Science and Nutrition
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v.25
no.4
/
pp.643-648
/
1996
The changes in hydration of brown rice, Chu-chung byeo(Japonica type) were determined during storage at different storage temperatures($4^{\circ}C$, 2$0^{\circ}C$, 3$0^{\circ}C$ and 4$0^{\circ}C$) in a 4-layered laminated film pouch(PET 12${\mu}{\textrm}{m}$/AI-foil 7${\mu}{\textrm}{m}$/o-Nylon 15${\mu}{\textrm}{m}$/L-Mix100${\mu}{\textrm}{m}$). At the beginning of storage, the hydration rate of brown rice increased with higher soaking temperature, and the activation energy of hydration was 10.3kcal/mole. Water diffusion coefficient of brown rice due to storage temperature during storage at 3$0^{\circ}C$ of soaking temperature was decreased by the elapse of storage periods and increment of storage temperature(below 3$0^{\circ}C$). ).
A traveltime tomography has been carried out by transforming electromagnetic data in frequency domain to wave-like domain. The transform uniquely relates a field satisfying a diffusion equation to an integral of the corresponding wavefield. But direct transform of frequency domain magnetic fields to wave-field domain is ill-posed problem because the kernel of the integral transform is highly damped. In this study, instead of solving such an unstable problem, it is assumed that wave-fields in transformed domain can be approximated by sum of ray series. And for further simplicity, reflection and refraction energy compared to that of direct wave is weak enough to be neglected. Then first arrival can be approximated by calculating the traveltime of direct wave only. But these assumptions are valid when the conductivity contrast between background medium and the target anomalous body is low enough. So this approach can only be applied to the models with low conductivity contrast. To verify the algorithm, traveltime calculated by this approach was compared to that of direct transform method and exact traveltime, calculated analytically, for homogeneous whole space. The error in first arrival picked by this study was less than that of direct transformation method, especially when the number of frequency samples is less than 10, or when the data are noisy. Layered earth model with varying conductivity contrasts and inclined dyke model have been successfully imaged by applying nonlinear traveltime tomography in 30 iterations within three CPU minutes on a IBM Pentium Pro 200 MHz.
Transactions of the Korean Society of Mechanical Engineers B
/
v.37
no.5
/
pp.481-488
/
2013
Nitric oxide ($NO_x$) formation characteristics in non-premixed diffusion flames of methane fuels have been investigated experimentally and numerically by adding 10% ammonia to the fuel stream, according to the variation of the oxygen ratio in the oxidizer with oxygen/carbon dioxide and oxygen/nitrogen mixtures. In an experiment of coflow jet flames, in the case of an oxidizer with oxygen/carbon dioxide, the $NO_x$ emission increased slightly as the oxygen ratio increased. On the other hand, in case of an oxygen/nitrogen oxidizer, the $NO_x$ emission was the maximum at an oxygen ratio of 0.7, and it exhibited non-monotonic behavior according to the oxygen ratio. Consequently, the $NO_x$ emission in the condition of oxyfuel combustion was overestimated as compared to that in the condition of conventional air combustion. To elucidate the characteristics of $NO_x$ formation for various oxidizer compositions, 1D and 2D numerical simulations have been conducted by adopting one kinetic mechanism. The result of 2D simulation for an oxidizer with oxygen/nitrogen well predicted the trend of experimentally measured $NO_x$ emissions.
In this paper, the unipolar corona-needle charger was developed and its capabilities were both numerically and experimentally investigated. The experimental corona discharges and particle losses in the charger were obtained at different corona voltage, aerosol flow rate and particle diameter for positive and negative coronas. Inside the charger, the electric field and charge distribution and the transport behavior of the charged particle were predicted by a numerical simulation. The experimental results yielded the highest ion number concentrations of about $1.087{\times}10^{15}ions/m^3$ for a positive corona voltage of about 3.2 kV, and $1.247{\times}10^{16}ions/m^3$ for a negative corona voltage of about 2.9 kV, and the highest $N_it$ product for positive and negative coronas was found to about $7.53{\times}10^{13}$ and $8.65{\times}10^{14}ions/m^3$ s was occurred at the positive and negative corona voltages of about 3.2 and 2.9 kV, respectively, and the flow rate of 0.3 L/min. The highest diffusion loss was found to occur at particles with diameter of 30 nm to be about 62.50 and 19.33 % for the aerosol flow rate of 0.3 and 1.5 L/min, respectively, and the highest electrostatic loss was found to occur at particles with diameters of 75 and 50 nm to be about 86.29 and 72.92 % for positive and negative corona voltages of about 2.9 and 2.5 kV, respectively. The numerical results for the electric field distribution and the charged particles migration inside the charger were used to guide the description of the electric field and the behavior of charged particle trajectories to improve the design and refinement of a unipolar corona-needle charger that otherwise could not be seen from the experimental data.
A highly purified $(Na^+,\;K^+)-ATPase$ from the rectal gland of Squalus acanthias and from the electric organ of Electrophorus electricus has been used to raise antibodies in rabbits. The 97,000 dalton catalytic subunit and glycoprotein derived from the rectal gland of spiny shark were also used as antigens. The two $(Na^+,\;K^+)-ATPase$ holoenzymes and the two shark subunits were antigenic. In Ouchterlony double diffusion experiments, these antibodies formed precipitation bands with their antigens. Antibodies prepared against the two subunits of shark holoenzyme also formed precipitation bands with their antigens and shark holoenzyme, but not with eel holoenzyme. These observations are in good agreement with inhibitory effect of these antibodies on the catalytic activity of $(Na^+,\;K^+)-ATPase$ both from the shark and the eel, since there is very little cross-reaction between the shark anticatalytic subunit antibodies and the eel holoenzyme. The maximum antibodies titer of the anticatalytic subunit antibodies is found to be 6 weeks after the initial single exposure to this antigen. Multiple injections of the antigen increased the antibody titer. However, the time required to produce the maximum antibody titer was approximately the same. These antibodies also inhibit catalytic activity of $(Na^+,\;K^+)-ATPase$ vesicles reconstituted by a slow dialysis of cholate after solubilization of the enzyme in a presonicated mixture of cholate and phospholipid. In these reconstituted $(Na^+,\;K^+)-ATPase$ vesicles, effects of these antibodies on the fluxes of $Na^+$, $Rb^+$, and $K^+$ were investigated. Control or preimmune serum had no effect on the influx of $^{22}Na^+$ or the efflux of $^{86}Rb^+$. Immunized sera against the shark $(Na^+,\;K^+)-ATPase$ holoenzyme, its glycoprotein or catalytic subunit did inhibit the influx of $^{22}Na^+$ and the efflux of $^{86}Rb^+$. It was also demonstrated that these antibodies inhibit the coupled counter-transport of $Na^+$ and $K^+$ as studied by means of dual labeling experiments. However, this inhibitory effect of the antibodies on transport of ions in the $(Na^+,\;K^+)-ATPase$ vesicles is manifested only on the portion of energy and temperature dependent alkali metal fluxes, not on the portion of ATP and ouabain insensitive ion movement. Simultaneous determination of effects of the antibodies on ion fluxes and vesicular catalytic activity indicates that an inhibition of active ion transport in reconstituted $(Na^+,\;K^+)-ATPase$ vesicles appears to be due to the inhibitory action of the antibodies on the enzymatic activity of $(Na^+,\;K^+)-ATPase$ molecules incorporated in the vesicles. These findings that the inhibitory effects of the antibodies specific to $(Na^+,\;K^+)-ATPase$ or to its subunits on ATP and temperature sensitive monovalent cation transport in parallel with the inhibitory effect of vesicular catalytic activity by these antibodies provide direct evidence that $(Na^+,\;K^+)-ATPase$ is the molecular machinery of active cation transport in this reconstituted $(Na^+,\;K^+)-ATPase$ vesicular system.
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