• 한국군사과학기술학회지
• /
• 제18권2호
• /
• pp.131-138
• /
• 2015

Energetic monomers with new design concept were synthesized for energetic prepolymers. Novel energetic monomers consisted of ring-opening polymerizable oxirane and a molecular explosive moiety instead of small explosophores as energetic functional groups. According to the design concept, glycidyl dinitroazetidine (GDNAZ) and glycidyl nitroazetidinol(GNAZO) energetic monomers were synthesized, respectively, and characterized by NMR, EA and GC MS. Heat of formation and detonation performance were calculated by theoretical method to evaluate energy performance of these novel energetic monomers. The result revealed that GDANZ and GNAZO possessed high potential as new energetic monomers for synthesizing energetic prepolymers and binders in PBXs.

• Korean Chemical Engineering Research
• /
• 제60권2호
• /
• pp.267-276
• /
• 2022

Modelling the energy release performance of energetic material combustion in closed systems is of fundamental importance for aerospace and defense application. In particular, to compensate for the disadvantage of the combustion of single energetic material and maximize the benefits, a method of combusting the mixed energetic materials is used. However, since complicated heat transfer occurs when the energetic material is combusted, it is difficult to theoretically predict the combustion performance. Here, we suggest a theoretical model to estimate the energy release performance of mixed energetic material based on the model for the combustion performance of single energetic material. To confirm the effect of parameters on the model, and to gain insights into the combustion characteristics of the energetic material, we studied parameter analysis on the reaction temperature and the characteristic time scales of energy generation and loss. To validate the model, model predictions for mixed energetic materials are compared to experimental results depending on the amount and type of energetic material. The comparison showed little difference in maximum pressure and the reliability of the model was validated. Finally, we hope that the suggested model can predict the energy release performance of single or mixed energetic material for various types of materials, as well as the energetic materials used for validation.

• 한국진공학회지
• /
• 제7권s1호
• /
• pp.183-189
• /
• 1998

A new computer simulation method for film growth, the kinetic Monte Carlo simulation in combination with the results obtained from molecular dynamics simulation for the transient process induced by deposited atoms, was developed. The behavior of energetic atom in Au/Au(100) thin film deposition was investigated by the method. The atomistic mechanism of energetic atom deposition that led to the smoothness enhancement and the relationship between the role of transient process and film growth mechanism were discussed. We found that energetic atoms cannot affect the film growth mode in layer-by-layer at high temperature. However, at temperature of film growth in 3-dimensional mode and in quasi-two-dimensional mode, energetic atoms can enhance the smoothness of film surface. The enhancement of smoothness is caused by the transient mobility of energetic atoms and the suppression for the formation of 3-dimensional islands.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2015년도 제51회 KOSCO SYMPOSIUM 초록집
• /
• pp.219-222
• /
• 2015

The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The frequency factor and activation energy are extracted as a function of product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the response of energetic materials; instead, multiple set of Arrhenius factors are used in describing a single global step. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

• 한국연소학회:학술대회논문집
• /
• 한국연소학회 2012년도 제44회 KOSCO SYMPOSIUM 초록집
• /
• pp.283-286
• /
• 2012

The analytical model determining the unknown parameters of reaction rate equation which is necessary to simulate the combustion phenomena of energetic materials is proposed. The relationship between detonation velocity and size effect of energetic materials is derived from simplified JWL++ model. Theoretical model is used to investigate the combustion characteristics of certain energetic materials before running Hydrocode by pre-determination of unknown parameter, b. When b=0.8, the behavior of HANFO gunpowder is in the form of concave-up and ANFO explosives has the concave-down form in case of b=1.5. The analytical model provides efficient and highly accurate results rather than previous method which simulated the unconfined-rate-stick via the numerical means.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2011년도 제37회 추계학술대회논문집
• /
• pp.274-278
• /
• 2011

다양한 고에너지 물질이 포함된 폭발 장치를 정확하게 해석하기 위해서는 고에너지 물질의 다양한 연소 현상과 주변을 둘러싸고 있는 고체물질에 대한 대변형 현상을 정확하게 모사하는 것이 필수적이다. 이를 위하여 본 연구에서는 다중물질 각각의 경계면을 level set 함수를 이용하여 정확하게 표현하였으며, 경계면은 ghost fluid 기법을 사용하여 나타내었다. 각각의 물질에 대하여 대변형에 적합한 구성방정식을 사용하였으며, 지배방정식을 고차의 수치해석 기법을 사용하여 해석하였다. 다양한 폭발장치 중 실험적인 데이터를 이용하여 검증이 가능한 rate stick 문제를 해석하였으며, 실험과 유사한 결과를 획득하였다.

• Nuclear Engineering and Technology
• /
• 제51권7호
• /
• pp.1860-1865
• /
• 2019

The confinement degradation of the energetic particles during RMP would be a key issue in success of realizing the successful energy production using fusion plasma, because a 3.5 MeV energetic alpha particle should be able to sustain the burning plasma after the ignition. As KSTAR recent results indicate the generation of high-performance plasma(${\beta}_p{\sim}3$), the confinement of the energetic particles is also an important key aspect in neutral beam driven plasma. In general, the measured absolute value of the neutron intensity is generally used for to estimating the confinement time of energetic particles by comparing it with the theoretical value based on transport calculations. However, the availability of, but for its calculation process, many accurate diagnostic data of plasma parameters such as thermal and incident fast ion density, are essential to the calculation process. In this paper, the time evolution of the neutron signal from an He3 counter during the beam blank has permitted to facilitate the estimation of the slowing down time of energetic particles and the method is applied to investigate the fast ion effect on ELM suppressed KSTAR plasma which is heated by high energy deuterium neutral beams.

• 한국추진공학회:학술대회논문집
• /
• 한국추진공학회 2017년도 제48회 춘계학술대회논문집
• /
• pp.547-553
• /
• 2017

Differential Scanning Calorimetry(DSC)를 이용하여 파이로점화장치에 사용되는 세 가지 고에너지 물질의 열분석 실험을 수행하였다. DSC 실험 데이터를 이용하여 고에너지 물질의 반응속도식을 추출해내는 이론적 방법을 제안하고 반응속도식 추출을 수행하였다. DSC 실험 결과는 Friedman 등전환법으로 분석되었다. 질량분율에 따른 활성화에너지와 빈도인자를 추출해 내어 반응속도식을 완성하였다. 추출된 반응속도식은 고에너지 물질의 화학반응과정을 몇 단계의 주요단계로 가정하는 형태가 아닌 전체 화학 반응 과정을 나타내는 형태를 갖는다. 이는 기존의 열분석 실험을 통해 추출되는 화학반응속도식 형태에 비해 이론적 측면과 정확성 측면에서 상당한 장점을 갖는다. 도출된 반응속도식을 이용하여 실제 추진기관에 운용되는 세 가지 고에너지 물질의 성능변화를 20년에 대하여 예측하였다.

• 한국입자에어로졸학회지
• /
• 제10권4호
• /
• pp.177-182
• /
• 2014

In this study, nickel-coated aluminum (Ni/Al) powders were synthesized for the utilization of energetic applications. Oxide materials present at the surface of Al powders of $45{\mu}m$ in averaged size were removed by using sodium hydroxide(NaOH) solution which is used for controlling pH. Nickel material is coated into the surface of oxide-removed Al powders by electroless-plating process. The microstructure of fabricated Ni/Al powders shows that nickel layers with a few hundreds nm were very homogeneously formed onto the surface of Al powders. The oxidation behavior of Ni/Al exihibit somewhat faster oxidation rate than that of pure Al with surface oxidation. Also, the higher exothermic reaction was observed from the Ni/Al powders. From the result of this, nickel coating is very promising method to obtain highly reactive and safe Al powders for energetic applications.

• 드라이브 ㆍ 컨트롤
• /
• 제16권2호
• /
• pp.80-90
• /
• 2019

Fuel cell hybrid electric vehicle is an attractive solution to reduce pollutants, such as noise and carbon dioxide emission. This study presents an approach for energy management and control algorithm based on energetic macroscopic representation for a fuel cell hybrid electric vehicle that is powered by proton exchange membrane fuel cell, battery and supercapacitor. First, the detailed model of the fuel cell hybrid electric vehicle, including fuel cell, battery, supercapacitor, DC-DC converters and powertrain system, are built on the energetic macroscopic representation. Next, the power management strategy was applied to manage the energy among the three power sources. Moreover, the control scheme that was based on back-stepping sliding mode control and inversed-model control techniques were deduced. Simulation tests that used a worldwide harmonized light vehicle test procedure standard driving cycle showed the effectiveness of the proposed control method.