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Recent Progress in the Development of Organometallic Complexes, Inorganic Phosphors and Quantum Dots for White Light Emitting Devices

  • Raja, Inam ul Haq;Lee, So-Ha
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.2
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    • pp.175-195
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    • 2008
  • Recent years have brought remarkable developments in white light emitting devices (WLEDs) and white organic light-emitting devices (WOLEDs). However, their efficiency, CIE values, CRI and lifetime are still not ideal. This review covers detailed discussion about syntheses of organometallic complexes, inorganic phosphors and quantum dots used in WLEDs, WOLEDs and their electroluminescent properties until December 2007.

Attraction Effect of Blue Light Emitting Trap Combination of Sticky Trap for Trialeurodes vaporariorum (Hemiptera : Aleyrodidae) Capture in Tomato Greenhouse (토마토 온실에서 청색 발광 및 점착트랩을 이용한 온실가루이 유인 효과)

  • Lee, Jung Sup;Lee, Jae Han;Kwon, Joon Kook;Park, Kyoung Sub;Kim, Jin Hyun;Lee, Dong Soo
    • Journal of Bio-Environment Control
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    • v.27 no.3
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    • pp.239-244
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    • 2018
  • The effect of the trap equipped with diverse light-emitting lamp on the lure efficiency of whitefly (Trialeurodes vaporariorum) was investigated in the greenhouse cultivating tomato. The light-emitting lamp type equipped to trap was blue, yellow, and white light-emitting lamp. The experiment results showed that trap equipped with blue light-emitting lamp captured the most number of $110{\pm}3.2$ adult whitefly and the number of captured adult whitefly was $71{\pm}1.4$ at yellow light-emitting lamp trap and $45{\pm}1$ at white light-emitting lamp trap respectively. The wavelength distribution band of blue light-emitting lamp was between 330 nm and 430 nm. The wavelength band of yellow and white light-emitting lamp contain repellent wavelength band at the same time. These results show that the trap equipped with blue light-emitting lamp could be used effectively for whitefly control and prevention in the greenhouse cultivating tomato.

Enhanced Electrical Properties of Light-emitting Electrochemical Cells Based on PEDOT:PSS incorporated Ruthenium(II) Complex as a Light-emitting layer

  • Gang, Yong-Su;Park, Seong-Hui;Lee, Hye-Hyeon;Jo, Yeong-Ran;Hwang, Jong-Won;Choe, Yeong-Seon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.08a
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    • pp.139-139
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    • 2010
  • Ionic Transition Metal Complex based (iTMC) Light-emitting electrochemical cells (LEECs) have been drawn attention for cheap and easy-to-fabricate light-emitting device. LEEC is one of the promising candidate for next generation display and solid-state lighting applications which can cover the defects of current commercial OLEDs like complicated fabrication process and strong work-function dependent sturucture. We have investigated the performance characteristics of LEECs based on poly (3, 4-ethylenedioxythiophene):poly (styrene sulfonate) (PEDOT:PSS)-incorporated transition metal complex, which is tris(2, 2'-bipyridyl)ruthenium(II) hexafluorophosphate in this study. There are advantages using conductive polymer-incorporated luminous layer to prevent light disturbance and absorbance while light-emitting process between light-emitting layer and transparent electrode like ITO. The devices were fabricated as sandwiched structure and light-emitting layer was deposited approximately 40nm thickness by spin coating and aluminum electrode was deposited using thermal evaporation process under the vacuum condition (10-3Pa). Current density and light intensity were measured using optical spectrometer, and surface morphology changes of the luminous layer were observed using XRD and AFM varying contents of PEDOT:PSS in the Ruthenium(II) complex solution. To observe enhanced ionic conductivity of PEDOT:PSS and luminous layer, space-charge-limited-currents model was introduced and it showed that the performances and stability of LEECs were improved. Main discussions are the followings. First, relationship between film thickness and performance characteristics of device was considered. Secondly, light-emitting behavior when PEDOT:PSS layer on the ITO, as a buffer, was introduced to iTMC LEECs. Finally, electrical properties including carrier mobility, current density-voltage, light intensity-voltage, response time and turn-on voltages were investigated.

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A Study on Electric Characteristics of Multi-layer by Light Organic Emitting Diode (유기발광소자(Organic Light Emitting Diode)의 다층박막에 대한 전기적 특성 연구)

  • Lee Jung-Ho
    • Journal of Korea Society of Industrial Information Systems
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    • v.10 no.2
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    • pp.76-81
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    • 2005
  • This research approached electrical characteristics of organic light emitting diodes getting into the spotlight by next generation display device. Basic mechanism of OLED's emitting is known as that electron by cathode of lower work function and hole by anode of higher work function are driven and recombine exciton-state being flowed in emitting material layer passing carrier transport layer In order to make many electron-hole pairs, we must manufacture device in multi-layer structure. There are Carrier Injection Layer(CIL), Carrier Transport Layer(CTL) and Emitting Material Layer(EML) in multi-layer structure. It is important that regulate thickness of layer for high luminescence efficiency and set mobility of hole and electron.

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Interfacial Engineering of Polymer Light Emitting Diode

  • Chen, Show-An
    • 한국정보디스플레이학회:학술대회논문집
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    • 2007.08a
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    • pp.165-167
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    • 2007
  • The performance of polymer light emitting diode can be improved significantly by interfacial engineering on anode and/or cathode through adjusting the charge injection barriers for holes and electrons. Studies involve CFx and SAM modifications on ITO, thickness and delay time to baking of PEDOT:PSS, and electron injection/hole blocking layer.

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Cultivation of Chlorella sp. under Different Aeration Conditions Illuminated by Light Emitting Diode (LED 조명을 이용한 광생물 반응기에서 공기 주입량에 따른 클로렐라 성장 연구)

  • Choi, Bo-Ram;Lee, Tae-Yoon
    • KSBB Journal
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    • v.27 no.4
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    • pp.263-267
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    • 2012
  • The purpose of this study was to determine optimum value of aeration rate for the cultivation of Chlorella sp. under illumination of red light emitting diode. The aeration rates varied from 0 to 2.4 vvm under the illumination of 4,400 lux of red light emitting diode. The highest specific growth rate of $1.51\;day^{-1}$ was obtained at the aeration of 0.7 vvm and lower specific growth rates were obtained for other aeration tests. Furthermore, the highest biomass concentration (1.02 g/L) was also obtained at the aeration of 0.7 vvm. Therefore, aeration of 0.7 vvm was determined to be the optimum aeration rate for the cultivation of Chlorella sp. under red light emitting diode.

Interlayer Engineering with Different Host Material Properties in Blue Phosphorescent Organic Light-Emitting Diodes

  • Lee, Jong-Hee;Lee, Jeong-Ik;Lee, Joo-Won;Chu, Hye-Yong
    • ETRI Journal
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    • v.33 no.1
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    • pp.32-38
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    • 2011
  • We investigated the light-emitting performances of blue phosphorescent organic light-emitting diodes, known as PHOLEDs, by incorporating an N,N'-dicarbazolyl-3,5-benzen interlayer between the hole transporting layer and emitting layer (EML). We found that the effects of the introduced interlayer for triplet exciton confinement and hole/electron balance in the EML were exceptionally dependent on the host materials: 9-(4-tert-butylphenyl)-3,6-bis(triphenylsilyl)-9H-carbazole, 9-(4-tert-butylphenyl)-3,6-ditrityl-9H-carbazole, and 4,4'-bis-triphenylsilanyl-biphenyl. When an appropriate interlayer and host material were combined, the peak external quantum efficiency was greatly enhanced by over 21 times from 0.79% to 17.1%. Studies on the recombination zone using a series of host materials were also conducted.

The Microscopic Surface Properties of Rhodamine Derivatives in EL System (EL시스템의 Rhodamine 유도체화합물의 표면특성)

  • 박수길;조성렬;손원근;조병호;임기조;이주성
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1997.04a
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    • pp.265-268
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    • 1997
  • Electroluminescent(EL) devices are constructed using multilayer organic thin film. A cell structure of glass substrate/Indium-Tinoxide/TPD as a hole transporting layer/Alq3+Rhodamine 101 perchrolate(Red3) as an emitting layer/Alq3 as an electrron transporting layer/Al as an electrode was employed. Optimal thickness of emitting layer in EL cell was performed from the viewpoint of the electronics properties of emitting layers. The general vapor-deposition method was used to control the thickness of omitting layer in EL devices and electro-optical characteristics were measured. It is clarified that controlling thickness of emitting layer in vapor-deposition film had an effect on the change of carrier injection and EL spectrum. The intensity of red omission with luminance of 81cd/$m^2$ was achived at 11V driving voltage. The surface morphology of emitting layer in EL devices was investigated.

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Nanocrystalline $Y_3Al_5O_{12}$:Ce Phosphor-Based White Light-Emitting Diodes Embedded with CdS:Mn/ZnS Core/Shell Quantum Dots

  • Kim, Jong-Uk;Lee, Dong-Kyoon;Lee, Jong-Jin;Yang, Hee-Sun
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.588-590
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    • 2008
  • Yellow-emitting $Y_3Al_5O_{12}$:Ce nanocrystalline phosphor and orange-emitting CdS:Mn/ZnS core/shell quantum dots were prepared by a modified polyol and a reverse micelle chemistry, respectively. To compensate a poor color rendering index of YAG:Ce nanocrystalline phosphor due to the lack of red spectral component, CdS:Mn/ZnS quantum dots were blended into YAG:Ce. Based on spectral evolutions in the blended systems, hybrid white light emitting diodes are fabricated and characterized.

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Correlation between host materials and device performances of phosphorescent white organic light-emitting diodes with blue/orange/blue stacked emitting structure

  • Joo, Chul-Woong;Kim, Sung-Hyun;Yook, Kyoung-Soo;Jeon, Soon-Ok;Lee, Jun-Yeob
    • 한국정보디스플레이학회:학술대회논문집
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    • 2008.10a
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    • pp.439-442
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    • 2008
  • A mixed host structure of TCTA and TPBI was used in orange emitting layer and host composition was critical to device performances of PHWOLEDs. PHWOLEDs with TPBI host in orange emitting layer showed high quantum efficiency of 10.3 % at $1000\;cd/m^2$ with little change of CIE coordinates of (0.32, 0.34) from $100\;cd/m^2$ to $10,000\;cd/m^2$.

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