• 제목/요약/키워드: Emission wavelength

검색결과 625건 처리시간 0.035초

Morphology-Controlled Fabrication of ZnS Nanostructures with Enhanced UV Emission

  • 김연호;장두전
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2013년도 제44회 동계 정기학술대회 초록집
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    • pp.587-587
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    • 2013
  • ZnS is well-known direct band gap II-VI semiconductor, and it attracts intense interest due to its excellent properties of luminescence which enable ZnS to have promising materials for optical, photonic and electronic devices. Especially, the emission wavelength of ZnS falls in the UV absorption band of most organic compoundsand biomolecules, thus it is envisaged that ZnS based devices may find applications in increasingly important fluorescence sensing. We have developed a facile and effective one-step process for the fabrication of single-crystalline and pure-wurtzite ZnS nanostructures possessing sharp band-edge emission at room-temperature having diverse length-to-width ratios. Each of nanostructures was composed of chemically pure, structurally uniform, single-crystalline, and defect-free ZnS. These features not only suppress trap or surface states emission centered at 420 nm, but also enhance UV band-edge emission centered at 327 nm, which give as-synthesized our ZnS nanostructures possible sharp UV emission at room temperature. The reaction medium consisting of mixed solvents such as hydrazine, ethylenediamine, and water as well as proper reaction time and temperature have played an important role in the crystallinity and optical properties of ZnS nanostructures. As-synthesized our ZnS nanostructures possessing sharp UV emission guarantee high potential for both fundamental research and technological applications.

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A New Iron Emission Template for Active Galactic Nuclei

  • Park, Daeseong;Barth, Aaron J.;Ho, Luis C.;Laor, Ari
    • 천문학회보
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    • 제44권2호
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    • pp.36.2-36.2
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    • 2019
  • Fe II emission is a prominent and ubiquitous feature in the spectra of broad-line Active Galactic Nuclei (AGN) by producing a pseudo-continuum from UV to optical with complex and strong blends of the numerous emission lines themselves, other emission lines, and continuum. Since theoretical modeling of such intricate Fe II emission is very difficult and still far from able to reproduce observed data in detail, an empirical iron emission template, derived from observations of a narrow-line Seyfert 1 galaxy, is an essential and practical tool to obtain accurate measurements of all the emission lines and continuum in AGN spectra. However, the existing iron templates, based on the single prototypical strong Fe II emitter I Zw 1, are suffering from inadequate S/N and non-simultaneous, inconsistent data with limited wavelength coverage, which consequently limit the accuracy of all the spectral measurements. To overcome the limitations and construct an improved iron template with wide spectral coverage, high-quality UV and optical spectra for the new and better identified template galaxy, Mrk 493, were successfully obtained from our HST STIS program (GO-14744). We will show the preliminary results for multicomponent spectral decomposition of the data and template construction with application tests to various AGN spectra and comparison with previous templates.

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Synthesis and Characterization of Phosphorescent Platinum and Iridium Complexes of 6-Chloro-3-phenylpyridazine

  • Lee, Sang-Jin;Seok, Kang;Lee, Jae-Sung;Lee, Seung-Hee;Hwang, Kwang-Jin;Kim, Young-Kwan;Kim, Young-Sik
    • Journal of Photoscience
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    • 제10권2호
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    • pp.185-187
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    • 2003
  • The preparation and the photophysics of organometallic Pt(II) and Ir(III) complexes with 6-ch1oro-3-phenylpyridazine (H6Clppdz) are reported. $K_2$PtCl$_4$ and IrCl$_3$ㆍn$H_{2}O$ cleanly cyclometalate with H6Clppdz, forming the corresponding chloro-bridged dimers, (6Clppdz)Pt($\mu$-Cl)$_2$Pt(6Clppdz) and (6Clppdz)$_2$Ir($\mu$-Cl)$_2$Ir(6Clppdz)$_2$ in good yield. These chloro-bridged dimers are cleaved with acetylacetone (Hacac) to give the corresponding monomer, (6Clppdz)Pt(acac) and (6Clppdz)$_2$ Ir(acac), respectively. Both complexes show bright orange luminescence at room temperature and the emission wavelengths are different depending on the metal and the structure of complexes. (6Clppdz)Pt(acac) shows two sharp emission bands in shorter wavelength ($\lambda$$_{em}$=541 and 580 nm), while (6Clppdz)$_2$ Ir(acac) shows a broad emission band in longer wavelength ($\lambda$$_{em}$=615 nm). Strong spinorbit coupling due to the heavy metal atom allows for the formally forbidden mixing of the $^1$MLCT with the $^3$MLCT and $^3$$\pi$-$\pi$$^{*}$ states.

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Dust-scattered FUV halo around Spica

  • 최연주;민경욱;박재우;임태호;선광일
    • 천문학회보
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    • 제37권1호
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    • pp.73.2-73.2
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    • 2012
  • The far ultraviolet (FUV) wavelength (900-1750A) range includes a wealth of important astrophysical information related to the cooling of hot gas, fluorescent emission from H2 molecules, and starlight scattered off dust particles. Among these, we would like to focus on the scattered emission of the central star by dust with the example of the FUV halo surrounding ${\alpha}$ Vir (Spica). While scattering properties of dust have been studied with the GALEX data, the improved dataset of STSAT-1 revealed many detailed structures of this interesting region. For example, the FUV continuum map obtained from the STSAT-1 observations shows enhanced emission in the southern part of the Spica halo region, where the dust level is also high. In fact, the FUV continuum intensity is seen to have a good correlation with the IRAS 100${\mu}m$ emission data. It is also seen that the scattered spectrum is softer than the original one emitted by the central star, which is attributed to the increase in the dust-scattering albedo with wavelength. We have developed a Monte Carlo code that simulates dust scattering of light including multiple encounters. The code is applied to the present Spica halo region to obtain the scattering properties such as the albedo and the phase function asymmetry factor.

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$Mg_xZn_{1-x}SiN_2$를 모체로 한 박막 전계발광소자용 형광체의 발광특성 (Luminescent Characteristics of $Mg_xZn_{1-x}SiN_2$ Based Phosphors for Thin Film Electroluminescent Device Applications)

  • 이순석;임성규
    • 전자공학회논문지D
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    • 제34D권2호
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    • pp.27-37
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    • 1997
  • Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and Photoluminescent and cathodoluminescent charcteristics of inorganic luminescent materials were investigated ot develop possible phosphors for thin film electroluminescent (TFEL) device applications. Mg, Zn, and $Si_3N_4$ powders were used to synthesize $(Mg_xZn_{1-x})SiN_2$ host materials. $Tb_4O_7$ and $Eu_2O_3$ powdrs were added as luminescent centers. Very sharp emission spectra of $Tb^{3+}$ ions were observed from $Mg._5Zn._5SiN_2:Tb$ sampels sintered at $1400^{\circ}C$ for an hour and the maximum intensity of emission spectra occured at wavelength of 550nm (green light). Synthetic conditions of $(Mg_xZn_{1-x})SiN_2:Eu$ phosphors were optimized for the hghest luminescence. The Eu concentrations were varied from 0.2% to 1.6%. Before firing, the powders were mixed using ballmills, methanol, acetone, or D.I. water. The Mg/Zn ratio also were varied from x=0.3 to x=0.7. The maximum PL intensity was obtained from a sample with 1.2% Eu concentration and the powder was mixed with methanol and dried before firing. The maximum intensity of the emission spectra occurred t the wavelength of 470nm(blue light). TFEL devices fabricated by using sputter deposition of $(Mg._3Zn._7)SiN_2:Eu$ phosphor layer showed yellowish white emission at the phosphor field of 2MV/cm.

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POLARIZATION OF THOMSON SCATTERED LINE RADIATION FROM BROAD ABSORPTION LINE OUTFLOWS IN QUASARS

  • Baek, Kyoung-Min;Bang, Jeong-Hoon;Jeon, Yeon-Kyeong;Kang, Suna;Lee, Hee-Won
    • 천문학회지
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    • 제40권1호
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    • pp.1-7
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    • 2007
  • About 10 percent of quasars are known to exhibit deep broad absorption troughs blueward of prominent permitted emission lines, which are usually attributed to the existence of outflows slightly above he accretion disk around the supermassive black hole. Typical widths up to 0.2c of these absorption roughs indicate the velocity scales in which special relativistic effects may not be negligible. Under he assumption of the ubiquity of the broad absorption line region in quasars, the broad emission line flux will exhibit Thomson scattered components from these fast outflows. In this paper, we provide our Monte Carlo calculation of linear polarization of singly Thomson scattered line radiation with the careful considerations of special relativistic effects. The scattering region is approximated by a collection of rings that are moving outward with speeds ${\upsilon}=c{\beta}<0.2c$ near the equatorial plane, and the scattered line photons are collected according to its direction and wavelength in the observer's rest frame. We find that the significantly extended red tail appears in the scattered radiation. We also find that the linear degree of polarization of singly Thomson scattered line radiation is wavelength-dependent and hat there are significant differences in the linear degree of polarization from that computed from classical physics in the far red tail. We propose that the semi-forbidden broad emission line C III]1909 may be significantly contributed from Thomson scattering because this line has small resonance scattering optical depth in the broad absorption line region, which leads to distinct and significant polarized flux in this broad emission line.

Multispectral viewing angle characterization of LCDs and their components

  • Boher, P.;Leroux, T.;Bignon, T.;Glinel, D.
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2008년도 International Meeting on Information Display
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    • pp.1366-1369
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    • 2008
  • We introduce new instrument that provides the spectral radiance at any incidence and azimuth angle in all the visible range. LCD emission and transmittance properties of display components can be measured precisely at each incidence and azimuth angle and wavelength. Full polarization spectral analysis can be also made.

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Far-infrared Study of Supernova Remnants in the Large Megellanic Cloud

  • 김예솔;구본철;석지연
    • 천문학회보
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    • 제38권1호
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    • pp.53-53
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    • 2013
  • We present preliminary results of far-infrared(FIR) study of the supernova remnant(SNR)s in the Large Magellanic Cloud using the Herschel HERITAGE (HERschel Inventory of The Agents of Galaxy Evolution) data set. HERITAGE provides FIR data covering the entire LMC at 100,160, 250, 350, and 500 um. In order to confirm FIR emission associated with SNRs, we refer to Magellanic Cloud Emission-Line Survey (MCELS) H-alpha & SII data, Spitzer surveying the Agents of a Galaxy's Evolution (SAGE) Multiband Imaging Photometer (MIPS) 24um & 70um data, Chandra Supernova Remnants Catalog, and ATCA 4.8GHz continuum images of Dickel et al. (2005). Among 47 SNRs in the LMC, 7 SNRs show associated FIR emission. We present multi-wavelength view of 5 SNRs; DEM L249, N49, N63A, N132D, and the SNR in N4. N49 and N132D show morphological correlation in FIR and X-ray, suggesting that the FIR emission is from dust grains collisionally heated by X-ray emitting plasma. The FIR emission of N63A resembles H-alpha emission, which implies that the FIR line radiation could be dominant. The FIR images of the rest two objects, DEM L249 and SNR in N4, show no correlation to the other-waveband images.

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Low Temperature Annealing Effect of PFO-Poss Emission Layer on the Properties of Polymer Light Emitting Diodes

  • Gong, Su-Cheol;Chang, Ho-Jung
    • 한국재료학회지
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    • 제19권6호
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    • pp.313-318
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    • 2009
  • Polymer Light Emitting Diodes (PLEDs) with an ITO/PEDOT:PSS/PVK/PFO-poss/LiF/Al structure were prepared on plasma-treated ITO/glass substrates using spin-coating and thermal evaporation methods. The annealing effects of the PFO-poss film when it acts as the emission layer were investigated by using electrical and optical property measurements. The annealing conditions of the PFO-poss emission film were 100 and $200^{\circ}C$ for 1, 2 and 3 hours, respectively. The luminance increased and the turn-on voltage decreased when the annealing temperature and treatment time increased. After examining the Luminance-Voltage (L-V) properties of the PLED, the maximum luminance was found to be 1497 cd/$m^2$ at 11 V for the device when it was annealed at $200^{\circ}C$ for 3 hours. The peak intensity of the PLED emission spectra at approximately 525 nm in wavelength increased when the annealing temperature and time of the PFO-poss film increased. These results suggest that the light emission color shifted from blue to green.