• Title/Summary/Keyword: Elongation Structure

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A Study on Mechanical Properties Improvement of Halogen-free Flame Retardant Compounds by Nanoclay Addition (나노클레이 첨가에 따른 할로겐프리 난연컴파운드의 기계적 특성에 관한 연구)

  • Hwang, Chan-Yun;Yang, Jong-Seok;Sung, Baek-Yong;Kim, Ji-Yeon;Park, Dae-Hee
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.28 no.2
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    • pp.126-130
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    • 2015
  • In this study, some materials are organized and experimented with variables to obtain the optimum mix proportion for the mechanical property of halogen free flame resistance compound with varying addition of nano clay. Tensile strength, density and stiffness are tested in the room temperature. In this study, unlike existing layered structure, nano clay with tabular structure is used and sufficient stiffness, strength, thermal stability and gas block capability can be achieved with small amount of addition. Tensile strength and elongation test show high rupture strength only in specimens with compatibilizing agents while density test shows average measurement in all the specimens except T-9. It was confirmed that the measurement value according to the additives in compatibilizing agent or in nano clay of hardness test represents similarly.

1D-Coordination Polymer Formed by Structural Conversion of an Oxazolidine Ligand in Reaction with the Copper(II) Halides

  • Mardani, Zahra;Golsanamlou, Vali;Jabbarzadeh, Zahra;Moeini, Keyvan;Carpenter-Warren, Cameron;Slawin, Alexandra M.Z.;Woollins, J. Derek
    • Journal of the Korean Chemical Society
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    • v.62 no.5
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    • pp.372-376
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    • 2018
  • A 1D-coordination polymer of $1D-\{Cu({\mu}-picolinato)_2\}$ $\{Hakimi,\;2012\;\sharp73\}_n$ (1), was prepared by the reactions between 2-(2-(pyridin-2-yl)oxazolidin-3-yl)ethanol (AEPC) ligand and $CuCl_2$ or $CuBr_2$. The product was characterized by elemental analysis, UV-Vis, FT-IR spectroscopy and single-crystal X-ray diffraction. The X-ray analysis results revealed that the AEPC ligand, after reactions with the copper(II) chloride or bromide, gives the same product - $1D-\{Cu({\mu}-picolinato)_2\}_n$ (1). The coordination modes for various picolinate-based ligands were extracted from the Cambridge Structural Database (CSD). In the crystal structure of 1, the copper atom has a $CuN_2O_4$ environment and octahedral geometry, which is distorted by elongation of the axial bond lengths due to the Jahn-Teller effect.

A COMPARATIVE STUDY ON PHYSICAL PROPERTIES OF ORTHODONTIC STAINLESS STEEL WIRES (교정용 스테인리스강선재의 물리적 성질에 관한 비교연구)

  • Kwon, Oh-Won;Sohn, Byung-Hwn
    • The korean journal of orthodontics
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    • v.15 no.2
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    • pp.163-174
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    • 1985
  • The requirements of orthodontic wire should include chemical stability, non-discoloration and non-corrosion in oral environment. Ability to be soldered, ease of fabrication and elasticity should be also considered. The purpose of this study was to compare and analyze the physical properties of Tru-chrome wire and manufactured E.S.S. (Experimental Stainless Steel) wire similar to Tru-chrome. The results were as follows: 1. Tru-chrome wire and E.S.S. wire were SUS 304 which was 18 Cr-8Ni austenite stainless steel. There was not significant difference in each composition between two wires. 2. There were not significant differences in ultimate tensile strength, yield strength, elongation and modulus of elasticity between Tru-chrome and E.S.S. wires. 3. There was not significant difference between flexuree modulus of elasticity of Tru-chrome and E.S.S. wires. 4. Micro-hardness value of E.S.S. wire was more than that of Tru-chrome wire and they were softened significantly by solution heat reatment. 5. Micro-structure of Tru-chrome and E.S.S. wires showed fibrous interlocking grains, and an austenite structure after solution heat treatment. 6. There was significant difference between corrosion rate of Tru-chrome and E.S.S. wires.

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Physical Properties of Polyester, Tencel and Cotton MVS Blended Yarns with Yarn counts and Blend Ratio (PET, Tencel, Cotton MVS 혼방사의 섬도와 혼용률에 따른 물성 특성)

  • Sa, A-Na;Lee, Jung Soon
    • Fashion & Textile Research Journal
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    • v.17 no.2
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    • pp.287-294
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    • 2015
  • This study investigates the physical properties of Murata Vortex Spinning (MVS) blended yarn with yarn count(20's, 30's, 40's) and blend ratio(Polyester 100, Polyester70:Cotton30, Polyester50:Cotton50, Polyester30:Cotton70, and Polyester50:Tencel40:Cotton10). This study evaluated tenacity, elongation, bending rigidity, bending hysteresis, hairiness coefficient, irregularity and twist number. The structure of MVS blended yarn influenced stress, strain, bending rigidity, bending hysteresis and the hairiness coefficient of MVS blended yarn decreased as the yarn count increased. MVS blended yarn consists of core and sheath. The core of MVS blended yarn is composed of a parallel fiber with a wrapping fiber that covers thecore fiber. This special structure of the MVS blended yarn effects the physical properties of the yarn; in addition, the mechanical properties of the component fibers influenced the stress, strain, bending rigidity, bending hysteresis and hairiness coefficient of MVS blended yarn with the blend ratio. Polyester decreases and cotton increases resulted in decreased physical properties. A similar polyester content increased the tencel and physical properties. Appropriate physical properties and a variety of touch expression can be realized through a correct blend ratio.

Development of Control Technology of Austempered Ductile Iron with High Strength and High Toughness for Gear Parts. (고강도 ADI의 기어부품 개발에 관한 연구)

  • Kim, Won-Yong;Kim, Kwang-Bae;Kang, In-Chan;An, Sang-Uk
    • Journal of Korea Foundry Society
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    • v.13 no.2
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    • pp.187-193
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    • 1993
  • In this study, it was examined the relationship between the microstructure, fatigue properties, mechanical properties and retained austenite volume of Mo-Ni ADI corresponding to various austempering temperatures. When the austempering temperature is increased to $370^{\circ}C$, acicular bainite structure was found to be transformed to feathery bainite structure. But at the austempering temperature of $420^{\circ}C$, the dissolved bainite lath was showned. Up to the austempering temperature of $370^{\circ}C$, the volume of retained austenite was increased. However at the austempering temperature of $420^{\circ}C$ a large amount of retained austenite was decreased. In this study, the retained austenite volume was determined by XRD(X-ray diffraction). It was observed that the optimum fatigue properties can be obtained at the condition of austempering temperature $370^{\circ}C$. Under the such conditions, fatigue limit determined as the value of 290 MPa, tensile strength 877MPa elongation 6%, hardness 285(BHN), impact values(CVN) 9.2J and retained austenite volume 30.3%, respectively.

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A study on the characteristics of Pb free Sn-2%Ag-x%Bi solder alloys (Pb Free Sn-2%Ag-x%Bi계 Solder의 특성에 관한 연구)

  • 흥순국;박일경;강정윤
    • Journal of Welding and Joining
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    • v.16 no.3
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    • pp.148-156
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    • 1998
  • The purpose of this study is to investigate the characteristics of Pb-Free Sn-2%Ag-Bi solder alloys. The solder alloys used in this study is Sn-2%Ag-(3,5,7,9%) Bi It is examined that their properties such as melting range, wettability, microstructure, microhardness, and tensile property. The addition of Bi(3,5,7,9%) lowered the melting point of the solder and the melting range was 196~203$^{\circ}C$. The wettability of the solder as equal to that of Sn-37% Pb solder. The morphology of structure did not change largely by addition of Bi. But the structure of cellular dendrite of linear type displayed. The tensile strength of the solder was superior to that of Sn-37%Pb solder. But the elongation was inferior to that of Sn-37%Pb solder. The hardness of Sn-2%Ag solder was tow times and that of Sn-2%Ag-Bi solder was three times of that in Sn-37%Pb solder. But the effect of increment of Bi content did not change largely.

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A Study of Hull Stress Monitoring System considering Thermal Effect

  • Shim, Chun-Sik;Kang, Joong-Kyoo;Heo, Joo-Ho
    • Journal of Navigation and Port Research
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    • v.32 no.2
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    • pp.121-126
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    • 2008
  • This paper presents hull stress monitoring system installed in LNGC damaged by a Typhoon Elongation/contraction of removed areas has been assessed in terms of possible residual stress that will take place in replaced blocks when the applied load is removed. The bending moment of a vessel changes actually in terms of loss of longitudinal members and the change of weight distribution in repair procedure. The change of bending moment affects mainly in hull stress of longitudinal members. Hull stress monitoring system was installed on upper deck to prove LNGC stable in the criteria to be less than 40MPa during the period of repair procedure. A temperature measuring system was also installed to exclude the additional stress due to thermal effect from the measured hull stress. As a result, the hull stress was modified with the data measured by the temperature measuring system. This hull stress considering thermal effect was used as a guide stress to check the safety of LNGC during the period of repair procedure.

Experimental damage evaluation of prototype infill wall based on forced vibration test

  • Onat, Onur
    • Advances in concrete construction
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    • v.8 no.2
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    • pp.77-90
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    • 2019
  • This paper aims to investigate vibration frequency decrease (vibration period elongation) of reinforced concrete (RC) structure with unreinforced infill wall and reinforced infill wall exposed to progressively increased artificial earthquake load on shaking table. For this purpose, two shaking table experiments were selected as a case study. Shaking table experiments were carried on 1:1 scaled prototype one bay one storey RC structure with infill walls. The purpose of this shaking table experiment sequence is to assess local behavior and progressive collapse mechanism. Frequency decrease and eigen-vector evolution are directly related to in-plane and out-of-plane bearing capacities of infill wall enclosure with reinforced concrete frame. Firstly, frequency decrease-damage relationship was evaluated on the base of experiment results. Then, frequency decrease and stiffness degradation were evaluated with applied Peak Ground Acceleration (PGA) by considering strength deterioration. Lastly, eigenvector evolution-local damage and eigenvector evolution-frequency decrease relationship was investigated. Five modes were considered while evaluating damage and frequency decrease of the tested specimens. The relationship between frequency decrease, stiffness degradation and damage level were presented while comparing with Unreinforced Brick Infill (URB) and Reinforced Infill wall with Bed Joint Reinforcement (BJR) on the base of natural vibration frequency.

Synthesis and Properties of Bio-Thermoplastic Polyurethanes with Different Isocyanate Contents

  • Li, Xiang Xu;Sohn, Mi Hyun;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.54 no.3
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    • pp.225-231
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    • 2019
  • Bio-based polyester polyol was synthesized via esterification between azelaic acid and isosorbide. After esterification, bio-based polyurethanes were synthesized using polyester polyol, 1,3-propanediol as the chain extender, and 4,4'-diphenylmethane diisocyanate, in mixing ratios of 1:1:1.5, 1:1:1.8, 1:1:2, and 1:1:2.3. The bio TPU (Thermoplastic Polyurethane) samples were characterized by using FT-IR (Fourier Transform Infrared Spectroscopy), TGA (Thermal Gravimetric Analysis), DSC (Differential Scanning Calorimetry), and GPC (Gel Permeation Chromatography). The mechanical properties (tensile stress and hardness) were obtained by using UTM, a Shore A tester, and a Taber abrasion tester. The viscoelastic properties were tested by an Rubber Processing Analyzer in dynamic strain sweep and dynamic frequency test modes. The chemical resistance was tested with methanol by using the swelling test method. Based on these results, the bio TPU synthesized with the ratio of 1:1:2.3, referred to as TPU 4, showed the highest thermal decomposition temperature, the largest molecular weight, and most compact matrix structure due to the highest ratio of the hard segment in the molecular structure. It also presented the highest tensile strength, the largest elongation, and the best viscoelastic properties among the different bio TPUs synthesized herein.

Effect of NCO/OH Ratio and Chain Extender Content on Properties of Polycarbonate Diol-based Waterborne Polyurethane

  • Kim, Eun-jin;Kwon, Yong Rok;Chang, Young-Wook;Kim, Dong Hyun
    • Elastomers and Composites
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    • v.57 no.1
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    • pp.13-19
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    • 2022
  • Polycarbonate diol-based waterborne polyurethane (WPU) was prepared by prepolymer mixing process. The prepolymer mixture contained the polycarbonate diol, isophorone diisocyanate (IPDI), dimethylol propionic acid, triethylamine, and ethylenediamine (EDA). The NCO/OH ratio in the prepolymer was adjusted by controlling the molar ratio of IPDI, and its effects on the properties of WPU were studied. The structure of WPU was characterized by fourier transform infrared spectroscopy. The average particle size increased and viscosity decreased with increasing NCO/OH ratio and EDA content in WPU. The reduced phase separation between soft and hard segments increased glass transition temperature. The reduction in the thermal decomposition temperature could be attributed to the low bond energy of urethane and urea groups, which constituted the hard segment. Additionally, the polyurethane chain mobility was restricted, elongation decreased, and tensile strength increased. The hydrogen bond between the hard segments formed a dense structure that hindered water absorption.