• 제목/요약/키워드: Elementary reaction

검색결과 138건 처리시간 0.027초

초등 과학영재학생들의 '살아있는 것'에 대한 존재론적 이해 분석 (An Analysis of Science-gifted Elementary School Students' Ontological Understanding of 'Living Things')

  • 김동렬
    • 한국초등과학교육학회지:초등과학교육
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    • 제34권2호
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    • pp.164-182
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    • 2015
  • This study aims to analyze science-gifted elementary students' understanding of 'Living Things' with ontological domains. As research subjects, this study selected 80 science-gifted students who belonged to Education Institute for Science-gifted Elementary Students at University of Education, and this study came to the following conclusions. Firstly, the gifted students thought of animals as living things most, out of which humans accounted for the highest rate. They were also found to evaluate the importance of living things depending on benefits and harms to humans. Secondly, when judging 4 domains of living things, animals, plants, static inanimate objects and dynamic inanimate objects, the gifted students did not have difficulty judging animals, plants and static inanimate objects, but 4 of them judged the moon, a dynamic inanimate object, as a living thing. In the aspect of reaction time, they spent more time judging plants than animals. This study classified their standards of judgement on living things into ontological categories. As a result, it was found that 31 and 33 out of them had standards of judgement corresponding to the category of matter and the category of process respectively, and only 16 of them had standards of judgement corresponding to the category of mental states. Thirdly, how to make a waterwheel and images of euglena and paramecium were shown to 10 of the gifted students who suggested simple movements as characteristics of living things. As a result, 7 of them changed their standards of judgement from the category of matter to the category of process, while 3 of them changed from the category of matter to the category of mental states.

고온벽면에 의한 수소-공기 예혼합기체의 자연발화에 관한 수치적 해석 (Numerical Analysis on the Autoignition of Hydrogen/Air Mixture Near a Hot Surface)

  • 박은성;백승욱
    • 대한기계학회논문집
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    • 제16권1호
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    • pp.70-76
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    • 1992
  • 본 연구에서는 수소와 공기의 예혼합기체가 가열된 벽면에 노출되어 있는 경 우의 점화문제를 1차원 비정상상태로 예측하고자 하며 특히, 계산에서 가정하는 화학 반응기구가 갖는 정확성에 관하여 수치해석적으로 고찰하고자 한다.

메탄 화염에서 염화 탄화수소 화합물이 질소산화물 생성에 미치는 영향 조사 (The Investigation of Influence of Chlorinated Hydrocarbons on $NO_x$ Formation from Methane Flames)

  • 장경;장봉춘;이기용
    • 한국연소학회지
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    • 제13권1호
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    • pp.10-16
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    • 2008
  • Numerical simulations of freely propagating premixed flames burning mixtures of methane and chlorinated hydrocarbons in fuel are performed at atmospheric pressure in order to understand the effect of chlorinated hydrocarbons on the formation of nitrogen oxide. A detailed chemical reaction mechanism is used, the adopted scheme involving 89 gas-phase species and 1017 elementary forward reaction steps. Chlorine atoms available from chlorinated hydrocarbons inhibit the formation of nitrogen oxides by lowering the concentration of radical species. The reduction of NO emission index calculated with thermal or prompt NO mechanism is not linear and is probably related to the saturation effect as $CH_3Cl$ addition is increased, In the formation or consumption of nitrogen oxide, the $NO_2$ and NOCl reactions play an important role in lean flames while the HNO reactions do in rich flames. The molar ratio of Cl to H in fuel has an effect on the magnitude of NO emission index.

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Numerical Investigation for Combustion Characteristics of Vacuum Residue in a Test Furnace

  • Sreedhara, S.;Huh, Kang-Y.;Park, Ho-Young
    • 한국연소학회:학술대회논문집
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    • 한국연소학회 2006년도 제32회 KOSCO SYMPOSIUM 논문집
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    • pp.121-127
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    • 2006
  • It has become inevitable to search for alternative fuels due to severe energy crisis these days. Use of alternative fuels, which are typically of lower quality, tends to increase environmental pollution, including formation of nitrogen oxides (NOx). In this paper performance of vacuum residue has been investigated experimentally as well as numerically in typical operating conditions of a furnace. Heat release reaction is modeled as sequential steps of devolatilization, simplified gas phase reaction and char oxidation as that for pulverized coal. Thermal and fuel NOx are predicted by conditional estimation of elementary reaction rates and are compared against measured experimental data. On the overall reasonable agreement is achieved for spatial distributions of major species, temperature and NOx for all test cases.

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CRDS Study of Tropospheric Ozone Production Kinetics : Isoprene Oxidation by Hydroxyl Radical

  • Park, Ji-Ho
    • 한국환경보건학회지
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    • 제35권6호
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    • pp.532-537
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    • 2009
  • The tropospheric ozone production mechanism for the gas phase additive oxidation reaction of hydroxyl radical (OH) with isoprene (2-methyl-1,3-butadiene) has been studied using cavity ring-down spectroscopy (CRDS) at total pressure of 50 Torr and 298 K. The applicability of CRDS was confirmed by monitoring the shorter (~4%) ringdown time in the presence of hydroxyl radical than the ring-down time without the photolysis of hydrogen peroxide. The reaction rate constant, $(9.8{\pm}0.1){\times}10^{-11}molecule^{-1}cm^3s^{-1}$, for the addition of OH to isoprene is in good agreement with previous studies. In the presence of $O_2$ and NO, hydroxyl radical cycling has been monitored and the simulation using the recommended elementary reaction rate constants as the basis to OH cycling curve gives reasonable fit to the data.

유해 할로겐화 탄화수소 폐기물 처리를 위한 열분해 반응 (Pyrolysis Reaction for the Treatment of Hazardous Halogenated Hydrocarbon Waste)

  • 조완근
    • 한국환경과학회지
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    • 제6권4호
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    • pp.399-407
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    • 1997
  • The pyrolysis reactions of atomic hydrogen with chloroform were studied In a 4 cm 1.6. tubular flow reactor with low flow velocity 1518 cm/sec and a 2.6 cm 1.4. tubular flow reactor with high flow velocity (1227 cm/sec). The hydrogen atom concentration was measured by chemiluminescence titration with nitrogen dioxide, and the chloroform concentrations were determined using a gas chromatography. The chloroform conversion efficiency depended on both the chloroform flow rate and linear flow velocity, but 416 not depend on the flow rate of hydrogen atom. A computer model was employed to estimate a rate constant for the initial reaction of atomic hydrogen with chloroform. The model consisted of a scheme for chloroform-hydrogen atom reaction, Runge-Kutta 4th-order method for Integration of first-order differential equations describing the time dependence of the concentrations of various chemical species, and Rosenbrock method for optimization to match model and experimental results. The scheme for chloroform-hydrogen atom reaction Included 22 elementary reactions. The rate constant estimated using the data obtained from the 2.6 cm 1.4. reactor was to be 8.1 $\times$ $10^{-14}$ $cm^3$/molecule-sec and 3.8 $\times$ $10^{-15}$ cms/molecule-sec, and the deviations of computer model from experimental results were 9% and 12% , for the each reaction time of 0.028 sec and 0.072 sec, respectively.

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Ar+O2 혼합가스 취입에 의한 용철의 탈탄 반응속도 (Decarbonization Kinetics of Molten Iron by Ar+O2 Gas Bubbling)

  • 손호상;정광현
    • 대한금속재료학회지
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    • 제47권2호
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    • pp.107-113
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    • 2009
  • Molten iron with 2 mass % carbon content was decarbonized at 1823 K~1923 K by bubbling $Ar+O_2$ gas through a submerged nozzle. The reaction rate was significantly influenced by the oxygen partial pressure and the gas flow rate. Little evolution of CO gas was observed in the initial 5 seconds of the oxidation; however, this was followed by a period of high evolution rate of CO gas. The partial pressure of CO gas decreased with further progress of the decarbonization. The overall reaction is decomposed to two elementary reactions: the decarbonization and the dissolution rate of oxygen. The assumptions were made that these reactions are at equilibrium and that the reaction rates are controlled by mass transfer rates within and around the gas bubble. The time variations of carbon and oxygen contents in the melt and the CO partial pressure in the off-gas under various bubbling conditions were well explained by the mathematical model. Based on the present model, it was explained that the decarbonization rate of molten iron was controlled by gas-phase mass transfer at the first stage of reaction, but the rate controlling step was transferred to liquid-phase mass transfer from one third of reaction time.

초등학교 고학년 아동의 성별 음란물 접촉실태와 성 갈등에 대한 연구 (Study of Contact with Pornographs and Feeling of Sexual Conflict in Upper Grade Elementary School Boys and Girls)

  • 차남현;왕명자;유경희;김정아
    • 동서간호학연구지
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    • 제13권2호
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    • pp.107-117
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    • 2007
  • Purpose: This study was to examine the possibility of the contact with pornographs of elementary school boys and girls and to confirm responses after that, and to compare the feeling of sexual conflict between the boys and girls. Methods: The subjects were 952 5th and 6th graders of elementary school in four city areas(456 boys, 496 girls). Data collection was via questionnaires Results: Except several pupils(34.4% of boys, 27.4% of girls), most of subjects of the study had no contact with pornographs. The response after the contact with pornographs was feeling of shame the most, which was a negative reaction. The sexual conflict appeared more in pupils who had contact with pornographs than in those who had not boys(t=3.84, p<.000), girls(t=3.96, p<.000), which showed a significant difference. However, the conflict between boys and girls was not significant statistically. Conclusion: We would like to suggest that a sound control system must be prepared and a development of programs related to sexual education and promotion of ability fighting against them that can release their impulse of sex.

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초등학교 학생들의 발달단계에 따른 던지기 동작의 운동역학적 분석 (The Biomechanical Analysis of Throwing Motion for the Elementary Students - Developmental Approach -)

  • 이동우
    • 한국운동역학회지
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    • 제17권1호
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    • pp.69-79
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    • 2007
  • The purpose of this study was to examine the characteristics of throwing motion in the elementary school students from the developmental point of view. For the purpose of this, total of nine subjects(each of three students in five, third, and first grades) were participated. They were asked to throw the ball as far as they can and the motions were videotaped with the 30frames/sec and 1/500 shutter speed. The successful motions for each subject were selected for three dimensional analysis. The collected data were analyzed using DV express 1.0 and Kwon3D 3.0 softwares. The results obtained from this study were as follows; 1. Total time for the throwing motion of the first grade was longer than that of the fifth and third grades. 2. The resultant displacement and velocity of COM for the fifth and third grades were greater than that of the frist grade. 3. The first grade tended to flex the trunk forward excessively during the throwing motion. 4. The fifth grade tended to place the upper arm close to the sagital plane and move the forearm and hand freely. 5. Looking at the greater variability of the angular velocity of the hand segment, the fifth grade seemed to have faster and more flexible movement of the wrist. 6. There were somewhat differences in the patterns and magnitudes of ground reaction forces among the different grades.

결손가정 아동의 정신건강 구조모형 (A Structural Model on the Mental Health in Children from Dysfunctional Families)

  • 이현주;김희경
    • 한국학교ㆍ지역보건교육학회지
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    • 제13권3호
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    • pp.13-31
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    • 2012
  • Purpose: This study was on the structural analysis of the covariant amount in order to evaluate the suitability of the structural models which can explain and predict the mental health of children on the basis of Bronfenbrenner's ecological theory. Methods: A questionnaire was used to survey 269 children from dysfunctional families out of 5th and 6th grade students from 30 elementary schools in one city and 6 counties, which was analyzed by using PASW Statistics 18.0 and LISREL 8.7 programs. Results: The variable which had influence on the self-esteem was the social support. The variable which had influence on the positive reaction under stress was the stress. The variables which had influence on the negative reaction under stress were stress, and self esteem. The variables which had influence on the mental health were the self-esteem and the negative reaction under stress. The main variables to influence the mental health of children from dysfunctional families turned out to be the self-esteem and the negative reaction under stress to the mental health. Conclusion: Evaluating the suitability of the models, I presented the bases on the practical nursing business. They showed the right directions to the mental health care of children from dysfunctional families.

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