• Title/Summary/Keyword: Elemental carbon (EC)

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Thermal Distribution of Size-resolved Carbonaceous Aerosols and Water Soluble Organic Carbon in Emissions from Biomass Burning

  • Bae, Min-Suk;Park, Seung-Shik
    • Asian Journal of Atmospheric Environment
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    • v.7 no.2
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    • pp.95-104
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    • 2013
  • The study of carbonaceous aerosols in the atmosphere is critical to understand the role of aerosols in human health and climate. Using standardized thermal optical transmittance methods, organic carbon (OC), elemental carbon (EC), and water soluble organic carbon (WSOC) were determined using a combustion sampling system for four types of agricultural crop residues (rice straw, red pepper stems, soybean stems, and green perilla stems) and eight types of forest trees (pine stems, pine needles, ginkgo stems, ginkgo leaves, maple stems, maple leaves, cherry stems, and cherry leaves). The aerosol particles between 0.056 and $5.6{\mu}m$ in size were analyzed using a Micro-Orifice Uniform Deposit Impactor (MOUDI). In the current study, the Carbonaceous Thermal Distribution (CTD) by carbon analyzer was discussed in order to understand the carbon fractions from the twelve types of biomass burning. Also, the concentration of OC, EC, WSOC, and water insoluble organic carbon (WIOC) detected in the emissions were described.

The Study of PM2.5 and Exhaust Emission Characteristics in the Motorcycles according to Various Lubricants (윤활유 종류에 따른 이륜자동차 PM2.5 및 배출가스 특성 연구)

  • Lim, Yunsung;Lee, Jongtae;Park, Jangmin;Kim, Jeongsoo;Lee, Janghoon
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.4
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    • pp.70-76
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    • 2013
  • Because increased food delivery service and quick delivery service using motorcycle, registration numbers of motorcycles were sharply increased and it could contribute on worsening air quality. In this study, two models(50cc, 125cc) of motorcycle were tested by using three types of engine oil. Two motorcycles were tested with CVS-40 mode for emission characteristics such as CO, THC, NOx, Elemental Carbon(EC), Organic Carbon(OC), sulfate, soot and SOF(soluble organic fraction). Result of according to three types of lubricants which included phosphorus, sulfate ash impacted to particle matters so "C" lubricants is more higher PM than "A", "B" lubricants in this research.

Concentrations of Air Pollutants Measured at Kosan during ACE-Asia Intensive Observation Period (ACE-Asia 집중관측기간에 제주고산에서 측정한 대기오염물질의 농도 분포특성)

  • ;;;;Jianzhen Yu;Keith Bower
    • Journal of Korean Society for Atmospheric Environment
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    • v.18 no.6
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    • pp.487-501
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    • 2002
  • The concentrations of gaseous (NO$_{x}$, SO$_2$, and $O_3$) and particulate (Elemental Carbon, EC and Organic Carbon, OC) pollutants were measured to evaluate the air quality of Kosan. Samples were taken at Kosan during ACE-Asia (Asian Pacific Regional Aerosol Characterization Experiment) IOP (Intensive Observation Period) (2001. 3. 21~2001. 5. 5). The mean concentrations of $O_3$(46.3$\pm$10.4 ppb) is higher than those at urban area such as Seoul and Busan in Korea. On the other hand, the mean concentrations of other gaseous species, NO$_{x}$(4.73$\pm$3.42 ppb) and SO$_2$(0.62$\pm$0.63 ppb) are lower than those at great cities. So we concluded that there are a few primary sources emitting atmospheric pollutants. The concentration of EC is higher and the concentration of OC is similar with or higher than those at other background sites. The recent EC concentration is higher than those measured before at Kosan. We concluded that there are more primary sources than other background sites and the amount of primary source have increased recently in Jeju. Backward trajectory and co..elation analysis were used to study where the air masses originated and distinguish the source of pollutants. While NO$_{x}$ and $O_3$ were mainly emitted and formed from Jeju inland area, concentrations of SO$_2$, OC and EC were affected by Asian Dust from China. Using the mean relative standard deviation of ozone, cleanness coefficient was obtained. The cleanness coefficient value, is 1.6 times larger than the value in 1992. Recently, the air quality of Kosan has been contaminated because of the Asian Dust events since spring and the rapid industrialization development.pment.

Measurement of Carbonaceous Species in Fine Particles at the Background Sites in Korea During 1996 and 1997 (우리 나라 배경농도지역의 1996~1997년 미세입자상 탄소성분 측정 결과)

  • 김용표;이종훈
    • Journal of Korean Society for Atmospheric Environment
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    • v.14 no.6
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    • pp.621-630
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    • 1998
  • The concentrations of organic carbon (OC) and elemental carbon (EC) in fine aerosols were determined from the samples collected at the two background sites of Kosan in Cheju Island and Kangwha. Samplings were carried out during the spring and winter of 1996 and the fall and winter of 1997. PM25 particles were collected on the prefired quartz filters for 24 hours and analyzed by the selective thermal oxidation method. The concentrations of OC at the sites were higher than those commonly observed from clean areas around the world, but those of EC at both sites were lower than, or comparable to, other clean areas in the world. Both the OC and EC levels at Kangwha were higher than those at Kosan. According to backward trajectory analysis, most air pollutants collected at the two sites were from China. It was found that the OC and EC concentrations in air masses from southern China were higher than those from northern China.

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A Study of Carbonaceous Aerosols Measurement in Metropolitan Area Performed during KORUS-AQ 2016 Campaign (수도권 지역의 탄소 성분 에어로졸 측정 연구: KORUS-AQ 2016 캠페인 기간을 중심으로)

  • Jeong, Byeongju;Bae, Min-Suk;Ahn, Junyeong;Lee, Jeonghoon
    • Journal of Korean Society for Atmospheric Environment
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    • v.33 no.3
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    • pp.205-216
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    • 2017
  • Carbonaceous aerosols such as the equivalent black carbon (eBC), the elemental carbon (EC) and the organic carbon (OC) were monitored at the Seoul Olympic Park site ($37.521^{\circ}N$, $127.124^{\circ}E$) during the KORUS-AQ 2016 campaign using a Multi Angle Absorption Photometer (MAAP) and an OCEC Analyzer. Averaged mass concentrations of eBC, EC and OC were presented as $2.46{\pm}1.52{\mu}g/m^3$, $1.01{\pm}0.60{\mu}g/m^3$ and $4.85{\pm}2.60{\mu}g/m^3$, respectively. OC/EC ratio and mass absorption cross-section (MAC) of light absorbing aerosols were calculated as 2.32 and $14.8m^2/g$, respectively. Diesel OC concentrations were estimated from a source profile of diesel vehicles as well. eBC mass concentrations measured from May $26^{th}$ to May $27^{th}$, 2016 showed 40% higher than averaged eBC mass concentrations during campaign period. $PM_{2.5}$ concentrations measured in this period were also higher than average $PM_{2.5}$ concentrations. High eBC concentrations were observed from May $29^{th}$ to May $31^{st}$, 2016 and from June $9^{th}$ to June $11^{th}$, 2016, possibly due to morning rush hour and the effect of temperature inversion at night. Diurnal variations of eBC, EC and Diesel OC showed a typical pattern of metropolitan area. In the weekend, however, diurnal variations of eBC, EC and Diesel OC mass concentrations were different from those measured in the weekday. It is expected that this study can help to understand the relationship between carbonaceous aerosols in a metropolitan area.

Chemical Characteristics of Water Soluble Components in Fine Particulate Matter at a Gwangju area (광주지역 PM2.5 입자 수용성 성분의 화학적 특성조사)

  • Park, Seung Shik;Cho, Sung Yong;Kim, Seung Jai
    • Korean Chemical Engineering Research
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    • v.48 no.1
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    • pp.20-26
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    • 2010
  • Water soluble organic and inorganic species are important components in atmospheric aerosol particles and may act as cloud condensation nuclei to indirectly affect the climate. To characterize organic and elemental carbon(OC and EC), water-soluble organic carbon(WSOC) and inorganic ionic species contents, daily $PM_{2.5}$ measurements were made during the wintertime at an urban site of Gwangju. Average concentrations of WSOC, $NO_3^-$, $SO_4^{2-}$ and $NH_4^+$, which are major components in the water-soluble fraction in PM2.5, are 2.11, 5.73, 3.51 and $3.31{\mu}g/m^3$, respectively, representing 12.0(2.9~23.9%), 21.0(12.9~37.6%), 11.6(2.5~25.9%) and 11.7%(3.8~18.6%) of the $PM_{2.5}$, respectively. Abundance of water soluble organic compounds ranged from 5.4 to 35.9% of total water soluble organic and inorganic components with a mean of 17.6%. Even though the sampling was performed during the winter, the average contributions of secondary OC and WSOC, as deduced from primary OC/EC(or WSOC/EC) ratio, were relatively high, accounting for 17.9%(0~44.4%) of the total OC and 11.2%(0.0~51.4%) of the total WSOC, respectively. During the sampling period, low $SO_4^{2-}/(SO_4^{2-}+SO_2$) ratio of 0.14(0.03~0.32) and relative humidity condition in the winter time suggest an possibility of impact of long-range transport and/or aqueous transformation processes such as metal catalyzed oxidation of sulfur, in-cloud processes, etc.

Concentrations of Carbonaceous Compounds and Quantitation of Secondary Organic Carbon in PM2.5 at Taehwa Research Forest

  • Lee, Seung-Ha;Lee, Sang-Deok;Kim, Dan-Bi;Kim, Rhok-Ho;Lee, Sang-Bo
    • Journal of Forest and Environmental Science
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    • v.34 no.1
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    • pp.53-56
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    • 2018
  • Elemental carbon (EC) and organic carbon (OC) mass concentrations in PM2.5 were measured from March through October 2015 in Taehwa Research Forest (TRF). The concentration of carbon in the TRF was $3.4{\mu}g/m^3$ and the concentration of EC was $1.4{\mu}g/m^3$. Also the concentration of $OC_{sec}$ was the highest at $2.84{\mu}g/m^3$ in the summer and the lowest at 1.66 in the spring. The ratio of the secondary generation OC in the total OC was the highest at 62% in the summer. Monthly OC concentration was the lowest at $2.38{\mu}g/m^3$ in April and the highest at $6.60{\mu}g/m^3$ in July. In case of EC concentration was the lowest in April ($0.98{\mu}g/m^3$) and the highest in July ($3.41{\mu}g/m^3$). The OC/EC ratio showed the lowest ratio in March and the highest rate in September. It is suggested that the secondary generation reaction of OC component was active due to sufficient irradiation amount in summer.