• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.6 no.1
• /
• pp.12-16
• /
• 2005

We used electrostatic force microscopy to probe carbon nanotubes. There is a linear relationship between the phase shift (${\Delta}{\phi}^{-l/2}$) and the inverse tube length ($L^{-1}$) of carbon nanotubes. When the distance(h) between the tip and the carbon nanotubes increase, the phase shift on EFM image decrease by a factor of $1/h^2$

• Applied Microscopy
• /
• v.51
• /
• pp.7.1-7.9
• /
• 2021

Neuromorphic systems require integrated structures with high-density memory and selector devices to avoid interference and recognition errors between neighboring memory cells. To improve the performance of a selector device, it is important to understand the characteristics of the switching process. As changes by switching cycle occur at local nanoscale areas, a high-resolution analysis method is needed to investigate this phenomenon. Atomic force microscopy (AFM) is used to analyze the local changes because it offers nanoscale detection with high-resolution capabilities. This review introduces various types of AFM such as conductive AFM (C-AFM), electrostatic force microscopy (EFM), and Kelvin probe force microscopy (KPFM) to study switching behaviors.

• Proceedings of the KIEE Conference
• /
• 2004.11a
• /
• pp.95-97
• /
• 2004

본 연구에서는 Scanning Capacitance Microscopy (SCM)와 Electrostatic Force Microscopy (EFM)을 이용하여 국소영역에서 실리콘나노 크리스탈의 전기적 특성을 분석하였다. 실리콘 나노 크리스탈은 에어로솔 방식으로 P-type 실리콘웨이퍼 위에 $10{\sim}40\;nm$의 크기와 약 $10^{11}/cm^2$의 밀도를 갖도록 제작하였다. 실리콘 나노 크리스탈에서 전자와 정공의 trapping 현상은 EFM, SCM 이미지를 통하여 관찰하였고 이러한 나노 크리스탈의 국소영역 특성을 MOS 캐패시터 구조의 C-V 특성을 비교 분석하였다. 또한, 나노 크리스탈에 trapping된 전하의 detrapping 과정을 스트레스 조건에 따라 분석하였다.

• New Physics: Sae Mulli
• /
• v.68 no.11
• /
• pp.1173-1182
• /
• 2018

Mesoporous silica allows proper hydration of an ion exchange membrane under low relative humidity due to its strong hydrophilicity and structural characteristic. A mesoporous silica and Nafion composite membrane shows good proton conductivity under low relative humidity. An understanding of ion-channel formation and proton transfer through an ion-channel network in mesoporous silica and Nafion composite membranes is essential for the development and the optimization of ion exchange membranes. In this study, a mesoporous cellular foam $SiO_2/Nafion$ composite membrane is fabricated, and its proton conductivity and performance are measured. Also, the ion-channel distribution is analyzed by using electrostatic force microscopy to measure the surface charge density of the mesoporous cellular foam $SiO_2/Nafion$ composite membrane. The research reveals a few remarkable results. First, the composite membrane shows excellent proton conductivity and performance under low relative humidity. Second, the composite membrane is observed to form ion-channel-rich and ion-channel-poor region locally.

• Clean Technology
• /
• v.18 no.4
• /
• pp.355-359
• /
• 2012

For effectively photochemical hydrogen production, Ti ions (0.01, 0.10, 0.50 mol%) impregnated $WO_3$ ($Ti/WO_3$) nanometer sized particles were prepared using a impregnation method as a photocatalyst. The characteristics of the synthesized $Ti/WO_3$ photocatalysts were analyzed by X-ray diffraction (XRD), scanning electron microscopy (SEM), photoluminescence spectra (PL), atomic force microscope (AFM), and electrostatic force microscope (EFM). The evolution of $H_2$ from methanol/water (1/1) photo-splitting over $Ti/WO_3$ photocatalysts was enhanced compared to those over pure $TiO_2$ and $WO_3$ photocatalysts; 3.02 mL of $H_2$ gas was evolved after 8 h when 0.5 g of a 0.10 mol% $Ti/WO_3$ catalyst was used.

• Bulletin of the Korean Chemical Society
• /
• v.31 no.2
• /
• pp.344-350
• /
• 2010

The improved photocatalytic performance of a carbon/$TiO_2$ composite was studied for the Bisphenol A (BPA) decomposition. Titanium tetraisopropoxide (TTIP) and a rice husk from Korea were heterogeneously mixed as the titanium and carbon sources, respectively, for 3 h at room temperature, and then thermally treated at $600^{\circ}C$ for 1 h in $H_2$ gas. The transmission electron microscopy (TEM) images revealed that the bulk carbon partially covered the $TiO_2$ particles, and the amount that was covered increased with the addition of the rice husk. The acquired carbon/$TiO_2$ composite exhibited an anatase structure and a novel peak at $2{\theta}=32^{\circ}$, which was assigned to bulk carbon. The specific surface area was significantly enhanced to 123~164 $m^2/g$ in the carbon/$TiO_2$ composite, compared to $32.43m^2/g$ for the pure $TiO_2$. The X-ray photoelectron spectroscopy (XPS) results showed that the Ti-O bond was weaker in the carbon/$TiO_2$ composite than in the pure $TiO_2$, resulting in an easier electron transition from the Ti valence band to the conduction band. The carbon/$TiO_2$ composite absorbed over the whole UV-visible range, whereas the absorption band in the pure$TiO_2$ was only observed in the UV range. These results agreed well with an electrostatic force microscopy (EFM) study that showed that the electrons were rapidly transferred to the surface of the carbon/$TiO_2$ composite compared to the pure $TiO_2$. The photocatalytic performance of the BPA removal was optimized at a Ti:C ratio of 9.5:0.5, and this photocatalytic composite completely decomposed 10.0 ppm BPA after 210 min, whereas the pure $TiO_2$ achieved no more than 50% decomposition under any conditions.