• Title/Summary/Keyword: Electrophoretic deposition

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Preparation and Characterization of a Layered Organic-inorganic Composite by the Electrophoretic Deposition of Plate-shaped Al2O3 Particles and Electrophoretic Resin (전기영동적층법을 통한 판상 알루미나 입자와 전기영동 수지의 배향 유무기 복합체 제조 및 물성평가)

  • Park, Hee Jeong;Lim, Hyung Mi;Choi, Sung-Churl;Kim, Younghee
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.460-465
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    • 2013
  • Plate-shaped inorganic particles are coated onto a stainless steel substrate by the electrophoretic deposition of a precursor slurry which includes the inorganic particles of $Al_2O_3$ and polymer resin in mixed solvents to mimic the abalone shell structure, which is a composite of plate-shaped inorganic particles and organic interlayer binding materials with a layered orientation. The process parameters of the electrophoretic deposition include the voltage, coating time, and conductivity of the substrate. In addition, the suspension parameters are the particle size, concentration, viscosity, conductivity, and stability. We prepared an organic-inorganic composite coating with a high inorganic solid content by arraying the plate-shaped $Al_2O_3$ particles and electrophoretic resin via an electrophoretic deposition method. We analyzed the effect of the slurry composition and the electrophoretic deposition process parameters on the physical, mechanical and thermal properties of the coating layer, i.e., the thickness, density, particle orientation, Young's modulus and thermogravimetric analysis results.

Electrophoretic Deposition of Ni Nano-particles for Self-repairing of Heat Exchanger Tubes

  • Lee, Gyoung-Ja;Pyun, Su-Il;Rhee, Chang-Kyu
    • Proceedings of the Korean Powder Metallurgy Institute Conference
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    • 2006.09b
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    • pp.1211-1212
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    • 2006
  • The electrophoretic deposition process of Ni nano-particles was employed for self-repairing of heat exchanger tubes. For electrophoretic deposition of Ni nano-particles on pitted Ni alloy specimen, a constant electric field of 100 V $cm^{-1}$ was applied to the specimen for 180 s in Ni-dispersed solution. It was found that as electrophoretic deposition proceeded, the size of the pit remarkably decreased due to the agglomeration of Ni nano-particles at the pit. This strongly suggests that the electrophoretic mobility of the charged particles is larger for the pit with a higher current value rather than outer surfaces with a lower current value.

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Electrophoretic Superconducting Film Applications

  • Fenghua, Li;Jue, Wang;Soh, Dea-Wha;Zhanguo, Fan
    • Journal of the Speleological Society of Korea
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    • no.76
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    • pp.15-17
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    • 2006
  • [ $YBa_2Cu_3O_{7-{\delta}}$ ] superconductor films have been prepared on silver substrates by electrophoretic deposition. As silver does not react with $YBa_2Cu_3O_{7-{\delta}}$ compound and has little influence on its superconductivity, it is usually doped in $YBa_2Cu_3O_7$ to improve the strength of the material and eliminate micro cracks. It has been proved that Ag additive can lower the melting temperature of $YBa_2Cu_3O_{7-{\delta}}$ and act as linking bridge among $YBa_2Cu_3O_{7-{\delta}}$ particles, thus in this paper Ag doped $YBa_2Cu_3O_{7-{\delta}}$ thick films are prepared by electrophoretic co deposition. As there are only some referenced experience formula and models for co electrophoretic deposition and does not exist unified explanation, the behavior of Ag particles during co electrophoretic deposition is also studied.

Electrophoretic Deposition for the Growth of Carbon nanofibers on Ni-Cu/C-fiber Textiles

  • Nam, Ki-Mok;Mees, Karina;Park, Ho-Seon;Willert-Porada, Monika;Lee, Chang-Seop
    • Bulletin of the Korean Chemical Society
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    • v.35 no.8
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    • pp.2431-2437
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    • 2014
  • In this study, Ni, Ni-Cu and Ni/Cu catalysts were deposited onto C-fiber textiles via the electrophoretic deposition method, and the growth characteristics of carbon nanofibers on the deposited catalyst/C-fiber textiles were investigated. The catalyst deposition onto C-fiber textiles was accomplished by immersing the C-fiber textiles into Ni or Ni-Cu mixed solutions, producing the substrate by post-deposition of Ni onto C-fiber textiles with pre-deposited Cu, and passing it through a gas mixture of $N_2$, $H_2$ and $C_2H_4$ at $700^{\circ}C$ to synthesize carbon nanofibers. For analysis of the characteristics of the synthesized carbon nanofibers and the deposition pattern of catalysts, SEM, EDS, BET, XRD, Raman and XPS analysis were conducted. It was found that the amount of catalyst deposited and the ratio of Ni deposition in the Ni-Cu mixed solution increased with an increasing voltage for electrophoretic deposition. In the case of post-deposition of Ni catalyst onto substrates with pre-deposited Cu, both bimetallic catalyst and carbon nanofibers with a high level of crystallizability were produced. Carbon nanofibers yielded with the catalyst prepared in Ni and Ni-Cu mixed solutions showed a Y-shaped morphology.

Electrophoretic Deposition of Superconducting $YBa_2Cu_3O_{7-\delta}$ Films Added with Silver Addition

  • Li, Fenghua;Wang, Jue;Soh, Dea-Wha;Fan, Zhanguo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2005.07a
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    • pp.260-261
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    • 2005
  • $YBa_2Cu_3O_{7-\delta}$ superconductor films have been prepared on silver substrates by electrophoretic deposition. As silver does not react with $YBa_2Cu_3O_{7-\delta}$ compound and has little influence on its superconductivity, it is usually doped in $YBa_2Cu_3O_7$ to improve the strength of the material and eliminate micro-cracks. It has been proved that Ag additive can lower the melting temperature of $YBa_2Cu_3O_{7-\delta}$ and act as linking bridge among $YBa_2Cu_3O_{7-\delta}$ particles, thus in this paper Ag doped $YBa_2Cu_3O_{7-\delta}$ thick films are prepared by electrophoretic co-deposition. As there are only some referenced experience formula and models for co-electrophoretic deposition and does not exist unified explanation, the behavior of Ag particles during co-electrophoretic deposition is also studied.

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Self-repairing Technology by Electrophoresis of Ni Nano-Particles for Heat Exchanger Tubes (Ni 나노입자의 전기영동 코팅에 의한 전열관 자가보수 기술 개발)

  • Lee, Gyoung-Ja;Lee, Min-Ku;Rhee, Chang-Kyu
    • Journal of Powder Materials
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    • v.14 no.4
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    • pp.238-244
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    • 2007
  • The electrophoretic deposition process of Ni nano-particles in organic suspension was employed for self-repairing of heat exchanger tubes. For this purpose, Ni nano-particles prepared by levitational gas condensation method were dispersed into the solution of ethanol with the addition of dispersant Hypermer KD2. For electrophoretic deposition of Ni nano-particles on the Ni alloy specimen, constant electric fields of 20 and 100 V $cm^{-1}$ were applied to the specimen in Ni-dispersed solution. It was found that as electrophoretic deposition proceeds, the size of the pit or crack remarkably decreased due to the agglomeration of Ni nano-particles at the pit or crack. This strongly suggests that the electrophoretic mobility of the charged particles is larger for the damaged part with a higher current value rather than outer surfaces with a lower current value.

Electrophoretic Deposition of YBCO powder in mixed suspension solution of iso-prophanol and iso-buthanol (이소프로판올과 이소부탄올 용매에서의 YBCO 분말 영동전착)

  • Soh, Dae-Wha;Li, Ying-Mei;Park, Jung-Cheul;N., Korobova
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11b
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    • pp.288-291
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    • 2001
  • It is very important to select suspension solution for forming electrophoretic deposited YBCO thick mm, because it is heavily affected to its superconducting properties. In this paper, high-temperature superconductor films of $YBa_{2}Cu_{3}O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension such as iso-propanol, iso-butanol, and their mixture. For the formation of YBCO dense and adherent coating on a silver wire by EPD, 1 % PEG(1000) 2 ml, as a additive for making their surface crack-free, was used for electrophoresis. As a results, the cracks were considerably decreased and the superconducting critical current density $(J_e)$ without/with PEG was $1200A/cm^2$ and $2020A/cm^2$, which films deposited in mix iso-propanol and iso-butanol suspension.

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Electrophoretic Deposition of YBCO powder in mixed suspension solution of iso-prophanol and iso-buthanol (이소프로판올과 이소부탄을 용매에서의 YBCO 분말 영동전착)

  • ;;;Korobova N.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.11a
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    • pp.288-291
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    • 2001
  • It is very important to select suspension solution for forming electrophoretic deposited YBCO thick film, because it is heavily affected to its superconducting properties. In this paper, high-temperature superconductor films of YBa$_2$Cu$_3$$O_{7-x}$ were fabricated by electrophoretic deposition (EPD) from alcohol-based suspension such as iso-propanol, iso-butanol, and their mixture. For the formation of YBCO dense and adherent coating on a silver wire by EPD, 1% PEG(1000) 2 $m\ell$, as a additive for making their surface crack-free, was used for electrophoresis. As a results, the cracks were considerably decreased and the superconducting critical current density (J$_{c}$) without/with PEG was 1200 A/$\textrm{cm}^2$ and 2020 A/$\textrm{cm}^2$, which films deposited in mix ism-propanol and iso-butanol suspension.ion.

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Barium titanate doping on superconducting perovskite YBCO

  • Soh, Deawha;Korobova, N.;Li, Ying-Mei;Cho, Yong-Joon;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2000.11a
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    • pp.120-123
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    • 2000
  • This paper reports a newly developed sol-gel process to synthesize dense YBCO thick films with BaTiO$_3$additives using electrophoretic deposition and metal alkoxide sol/particle suspension, which we successfully produce dense $YBCO+BaTiO_3$ ceramics at a rather low temperature, compared with the sintering temperature used in conventional methods. The thick films of HTS were prepared by electrophoretic deposition, using pre-sintered powder with barium titanate addition in the form of $BaTi(OR)_6$ solution in suspension for electrophoresis. The conditions for applied voltage and deposition times for electrophoretic deposition of HTS thick films were studied in detail.

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