• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2004.09a
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• pp.191-194
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• 2004

The concentration of hydrogen peroxide in soil and effluent was measured to understand the relationship between the profile of hydrogen peroxide and the removal efficiency of phenanthrene in an Electrokinetic-Fenton process. Electrokinetic phenomena were observed in two different conditions for 1, 2, 4, and 7 days; 3.5% and 10% hydrogen peroxide. The concentration of hydrogen peroxide in soil was high near the anode and decreased towards the cathode due to the direction of electroosmosis. The hydrogen peroxide concentration in effluent increased with time, but the value was lower than the initial. The removal efficiency of phenanthrene at 10% hydrogen peroxide was higher than the case at 3.5%. The removal efficiency after 7 days was high(> 97%) in both cases.

• Proceedings of the KSME Conference
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• 2008.11b
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• pp.2544-2547
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• 2008

A micro channel heat sink has been studied and optimized for mixed pressure driven and electroosmotic flows through three-dimensional numerical analysis. The effects of ionic concentration represented by zeta potential and Debye thickness are studied with the various steps of externally applied electric potential. Optimization of the micro channel heat sink has been performed considering two design variables related to the micro channel width, depth and fin width. The surrogate-based optimization is performed using a search algorithm taking overall thermal resistance as objective function. The thermal resistance is found to be more sensitive to channel width-to-depth ratio than fin width-to-depth of channel ratio.

• Proceedings of the PSK Conference
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• 2003.04a
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• pp.293.1-293.1
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• 2003

Electroosmotic flux during iontophoresis originates due to the net negative charge of the current passing channels (pores) in skin at physiological pH (pH 7.4). Thus, the channels are permselective to cations, and this causes the convective solvent flow from anode to cathodal direction. This solvent flow facilitates the flux of cations (from anode), inhibits that of anions (from cathode), and enables theenhanced transport of neutral, polar solutes. (omitted)

• Proceedings of the PSK Conference
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• 2003.10b
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• pp.233.3-234
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• 2003

Electroosmotic flux during iontophoresis originates due to the net negative charge of the current passing channel (pores) in skin at physiological pH (pH 7.4). Thus, the channel is permselective to cations, and this causes the convective solvent flow, from anode to cathode direction. This solvent flow facilitates the flux of cations (from anode), inhibits that of anions (from cathode), and enables the enhanced transport of neutral, polar solutes. In this work, we have investigated the effect of a series of polyethylene glycols (PEGs) with different molecular weights on the electroosmtic flow to get more detail understanding of this phenomena. (omitted)

• Clean Technology
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• v.13 no.3
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• pp.195-200
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• 2007

This study investigated the flow rate changes of the heterogeneous rectangular microchannels which have different hydrophilic property on the bottom surface. The heterogeneous rectangular microchannel has three native PDMS (poly-dimethyl siloxane) surfaces which were patterned by the soft lithography. PDMS bottom surface was treated by the argon plasma and coated by the allyl alcohol (99%). The channel length was 10, 20 and 30 mm and the channel width was 100, 200 and $300\;{\mu}m$, respectively. Several external voltages were applied to make the fluid flow by the electroosmosis in the microchannel. For the same electric field strength and hydrophilicity of the bottom surface, the flow rate is almost same. This result is matched to the theoretical expectation and confirms that the experimental system is reliable. With increasing the channel width, the flow rate increased for the same hydrophilicity of the bottom surface. The flow rate of the microchannel of higher hydrophilicity was larger than that of the microchannel of lower hydrophilicity. This result implies that the hydrophilicity change of the bottom surface could be applied to control the flow rate in the microchannel.

• Journal of Pharmaceutical Investigation
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• v.38 no.6
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• pp.373-380
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• 2008

In order to develop optimal formulation and iontophoresis condition for the transdermal delivery of levodopa, we have evaluated the effect of two permeation enhancers, ethanol and oleic acid in microemulsion, on transdermal delivery of levodopa. In vitro flux studies were performed at $33^{\circ}C$, using side-by-side diffusion cell and full thickness hairless mouse skin. Current density applied was $0.4\;mA/cm^2$ and current was off after 6 hours application. Levodopa was analysed by HPLC at 280 nm. The o/w microemulsions of oleic acid in buffer solution (pH 2.5 & 4.5) were prepared using oleic acid, Tween 80 and ethanol. The existence of microemulsion regions were investigated in pseudo-ternary phase diagrams. Contrary to our expectation, cumulative amount of levodopa transported from microemulsion (pH 2.5) for 10 hours was similar to that from aqueous solution in all delivery methods (passive, anodal and cathodal). When pH of the micro-emulsion was pH 4.5, cumulative amount of levodopa transported for 10 hours increased about 40% (anodal) to 50% (cathodal), when compared to that from aqueous solution. Flux from pH 4.5 microemulsion showed higher value than that from pH 2.5 in all delivery methods. These results seem to indicate that electroosmosis plays more dominant role than electrorepulsion in the flux of levodopa at pH 2.5. The effect of ethanol on iontophoretic flux was studied using pH 2.5 phosphate buffer solution containing 3% or 5% (v/v) ethanol. Flux enhancement was observed in passive and anodal delivery as the concentration of the ethanol increased. Without ethanol, cathodal delivery showed higher flux than anodal delivery. Anodal delivery increased the cumulative amount of levodopa transported 1.6 fold by 5% ethanol after 10 hours. However, in cathodal delivery, no flux enhancement of levodopa was observed during current application and only marginal increase in cumulative amount transported after 10 hours was observed by 5% ethanol. These results seem to be related to the decrease in dielectric constant of the medium and the lipid extraction of the ethanol, which decrease the electroosmotic flow, and thus decrease the flux. Overall, the results provide important insights into the role of electroosmosis and electrorepulsion in the transport of levodopa through skin, and provide some useful informations for optimal formulation for levodopa.

• Geotechnical Engineering
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• v.13 no.6
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• pp.123-138
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• 1997

Electroosmotic tests were performed on saturated marine clay specimens contaminated with lead to investigate the efficiency of the electrokinetic technique for removal of heavy metals from the cohesive soils. For this purpose, testing program included variable conditions such as the concentration of lead (500, 5, 000, 50, 000mg/kg), the level of electrical current (10, 50, 100 mA), operating duration (5, 15, 30days), and the application of three dirtferent chemicals for enhancement in efficiency. The pH of inflow and outflow, electroosmotic flow and electrical conductivity during the test, and the pH and the concentration of lead across the specimen after the test are presented. Test results came to the conclusion that the electrokinetic technique was very effective to remove heavy metals such as lead from the contaminated cohesive soil. Adding ecetic acid at the cathod to dissolve the procipitates of lead hydroxide as found to be effective for the enhancement of the efficiency in remediation.

• Journal of the Korean Geosynthetics Society
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• v.6 no.3
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• pp.25-30
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• 2007

The major reason to employ electrokinetic geosynthetics is to take advantage of its ability to densify very low permeability materials in shorter time periods than ordinary seepage consolidation. A number of laboratory scale experiments was carried out with acrylic column using natural clayey soil. The testing results indicate that (1) the electrically induced settlement was faster than the gravitational one, (2) the higher the voltage, the faster the dewatering but the less final settlement, and (3) the pH extended as low as 3 in the anode section and as high as 11 near the cathode.

• Membrane and Water Treatment
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• v.11 no.3
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• pp.201-206
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• 2020

Electrodialysis (ED) is used in wastewater treatment, during the processing and recovery of beneficial materials, to produce usable water. In this study, sulfate and chlorine ions, which are the anions majorly used for electroplating, were studied as factors affecting the recovery of copper, nickel and water from wastewater by electrodialysis. Although the removal rates of copper and nickel ions were slightly higher with the use of chlorine ions than of sulfate ions, the removal efficiencies were above 99.9% under all experimental conditions. The metal ions of the plating wastewater flowed through the ion exchange membrane of the diluate tank and the concentrate tank while all the water moved together due to electro-osmosis. The migration of water from the diluate tank to the concentrate tank was higher in the presence of a monovalent chloride ion compared to that of a divalent sulfate ion. When sulfate was the anion used, the recoveries of copper and nickel increased by about 25% and 30%, respectively, as compared to the chloride ion. Therefore, when divalent ions such as sulfate are present in the electrodialysis, it is possible to reduce the movement amount of water and highly concentrate the copper and nickel in the plating wastewater.

• Journal of Soil and Groundwater Environment
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• v.6 no.4
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• pp.13-23
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• 2001

In this study, the characteristics of pH variations and contaminant distribution in soil are investigated during electrokinetic treatment for the purpose of restoring contaminated soil with heavy metal. For these objects, laboratory test for the kaolin contaminated by lead was performed. During electrokinetic treatment, lead was transported from anode to cathode. And 75% of lead removed within 80% region of the specimen. Most lead, however, that transported from anode to cathode precipitated in the vicinity of cathode compartment, thus the amount of lead removed by electroosmosis was little. Electrokinetic treatment satisfied regulation criteria of Korean Soil Environment Conservation Law within almost region of the specimen. But enhancement methods can be regarded as inevitable requisite for the cathode region.