• Title/Summary/Keyword: Electronic transition

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The Effect of Solution Agitation on the Electroless Cu Deposition Within Nano-patterns (용액 교반이 미세 패턴 내 무전해 구리 도금에 미치는 영향)

  • Lee, Joo-Yul;Kim, Man;Kim, Deok-Jin
    • Journal of the Korean institute of surface engineering
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    • v.41 no.1
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    • pp.23-27
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    • 2008
  • The effect of solution agitation on the copper electroless deposition process of ULSI (ultra large scale integration) interconnections was investigated by using physical, electrochemical and electrical techniques. It was found that proper solution agitation was effective to obtain superconformal copper configuration within the trenches of $130{\sim}80nm$ width. The transition of open potential during electroless deposition process showed that solution agitation induced compact structure of copper deposits by suppressing mass transfer of cuprous ions toward substrate. Also, the specific resistivity of copper layers was lowered by increasing agitation speed, which made the deposited copper particles smaller. Considering both copper deposit configuration and electric property, around 500 rpm of solution agitation was the most suitable for the homogeneous electroless copper filling within the ultra-fine patterns.

Interconversion of Electronic Spin State of p-Substituted Arylketocarbene Reactions

  • Sung, Dae-Dong;Jeong, Jin-Hee;Ryu, Zoon-Ha;Chin, Won-Bae;Lee, Ik-Choon
    • Bulletin of the Korean Chemical Society
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    • v.25 no.8
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    • pp.1231-1237
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    • 2004
  • Rate constants for photolytic reactions of p-substituted 2-diazopropiophenones were determined in acetonitrile. The reactions show a comparatively low value of activation energy and activation enthalpy to alkylcarbenes or other arylcarbenes. The transition state corresponds to the step of a new carbonyl bond formation. The high negative ρ -values are shown in Hammett plots. The kinetics results and EPR spectrum are in accord with a phenomenon that occurs in interconversion between singlet and triplet carbenes.

Design of Broadband Quasi-Yagi Antenna Using a Folded Dipole Driver

  • Ta, Son Xuat;Kim, Byoung-Chul;Choo, Ho-Sung;Park, Ik-Mo
    • Journal of electromagnetic engineering and science
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    • v.11 no.3
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    • pp.227-233
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    • 2011
  • This paper describes the development of a broadband quasi-Yagi antenna using a folded dipole driver. The antenna is designed on a low-permittivity substrate to reduce the surface wave effect, and hence the gain can be enhanced easily by adding directors. The folded dipole driver is connected to a 50-${\Omega}$ microstripline via a simple broadband microstrip-to-coplanar stripline transition with a quarter radial stub. The key motivation for the use of a folded dipole is to increase the input impedance at the driver, allowing a smaller mismatch loss between the antenna driver and the coplanar stripline feed. The proposed antenna has a measured bandwidth of 4.67~6.26 GHz for the -10 dB reflection coefficient, and a flat gain of 4.86~5.15 dB within the bandwidth.

Crystal growth and pinning enhancement of directionally melt-textured$(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$ oxides in air

  • Kim So-Jung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.15 no.5
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    • pp.188-192
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    • 2005
  • High $T_c(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y[(YNS)-123]$ superconductors with/without $CeO_2$ additive were systematically investigated by the zone melt growth process in air. Cylindrical green rods of (YNS)-123 oxides were fabricated by cold isostatic pressing (CIP) method using rubber mould. A sample prepared by this method showed well-textured microstructure, and $(Y_{0.5}Nd_{0.25}Sm_{0.25})_2BaCuO_5[(YNS)211]$ nonsuperconducting inclusions were uniformly dispersed in large $(Y_{0.5}Nd_{0.25}Sm_{0.25})Ba_2Cu_3O_y$[(YNS)123] superconducting matrix. In this study, optimum melting temperature and growth rate were $1100^{\circ}C$ and 3 mm/hr, respectively. The directionally melt-textured (YNS)-123 sample with $CeO_2$ additive showed an onset critical temperature $(T_c)\;T_c{\geq}93K$ and sharp superconducting transition.

Cardiac Disorder Classification Using Heart Sounds Acquired by a Wireless Electronic Stethoscope (무선 전자청진 심음을 이용한 심장질환 분류)

  • Kwak, Chul;Lee, Yun-Kyung;Kwon, Oh-Wook
    • Proceedings of the KIEE Conference
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    • 2007.10a
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    • pp.101-102
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    • 2007
  • Heart diseases are critical and should be detected as soon as possible. A stethoscope is a simple device to find cardiac disorder but requires keen experiences in heart sounds. We evaluate a cardiac disorder classifier by using heart sounds recorded by a digital wireless stethoscope developed in this work. The classifier uses hidden Markov models with circular state transition to model the heart sounds. We train the classifier using two kinds of data: One recorded by using our stethoscope and the other sampled from a clean heart sound database. In classification experiments using 165 sound clips, the classifier shows the classification accuracy of 82% in classifying 6 cardiac disorder categories.

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First-principles Study on Magnetism of Cu in GaN

  • Kang, Byung-Sub;Heo, Chul-Min;Lyu, Kwang-Kwyun;Yu, Seong-Cho
    • Journal of Magnetics
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    • v.14 no.3
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    • pp.114-116
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    • 2009
  • The electronic properties of Cu or Pd-doped GaN at several concentrations are examined using the full-potential linear muffin-tin orbital method. For ($Cu_{0.055}Ga_{0.945}$)N, the model reveals a magnetic moment of $1.47{\mu}B$ per supercell. The range of concentrations that are spin-polarized should be restricted within narrow limits. A paramagnetic to ferromagnetic phase transition is found to occur at a Cu concentration of 5.55%.

Cathodoluminescence Enhancement of CaTiO3:Pr3+ by Ga Addition

  • Kang, Seung-Youl;Byun, Jung-Woo;Kim, Jin-Young;Suh, Kyung-Soo;Kang, Seong-Gu
    • Bulletin of the Korean Chemical Society
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    • v.24 no.5
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    • pp.566-568
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    • 2003
  • The phosphor $CaTiO_3:Pr^{3+}$ attracts much attention as a low-voltage red phosphor because of its good chromaticity and intrinsic conductivity. The addition of Ga into this CaTiO₃:Pr led the luminance intensity to greatly enhance without the change of the wavelength for the electronic transition and the peak shape of it. The increase of the recombination rate of electron-hole pairs through the Ga ion doping, which was expected to play a role of a hole-trap center, is proposed to be one of the reasons for the enhancement of the cathodoluminescence intensity.

Characteristics of Hydrogenation and Electronic Properties of Thin Film Y-Hx

  • Cho, Young-Sin;Jee, Chan-Soo;Kim, Sun-Hee;Yoon, Jong-Hwan
    • Transactions of the Korean hydrogen and new energy society
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    • v.3 no.2
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    • pp.35-43
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    • 1992
  • Thin Film yttrium, 500 nm thick, was prepared by electron beam evaportion on sapphire substrate. Film was hydrogenated at room temperature upto 1 bar hydorgen pressure without any activation process. Electrical resistivity was measured by four-point DC method in the temperature range between room temperature and 30 K for various hydorgen concentration x = 0 to 2.924 of $YH_x$ sample. Temperature dependent resistance of $YH_{2\;924}$ shows low temperature minmum at 105K ($36{\mu}{\Omega}cm$ deep), the metal-semiconductor transition at 260K, and a hysteresis, which are similar behavior to bulk $YH_x$(x>2) experimental results.

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Highly Donor-doped $Ba_{1-x}La_{x}TiO_{3}$ Semiconductive Ceramics

  • Soh, Dea-Wha;Korobova N.
    • Journal of information and communication convergence engineering
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    • v.1 no.1
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    • pp.31-34
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    • 2003
  • Sol-gel processing of $BaTiO_{3}$ ceramics doped with La (0.01∼1.00 at.%) were prepared from metal barium, titanium n-butoxide and lanthanum isopropoxide. Characterization of the sol-gel-derived powder using XRD, SEM is also reported. The obtained results suggested that insulator to semiconductor transition for highly donor-doped barium titanate was closely related to the incorporation of donor into the grains and to the resultant grain size, which were significantly affected by the sinterability of $BaTiO_{3}$ powders and sintering conditions used.

A Study on Thermal, Mechanical and Electrical Properties as Silane Treated Epoxy/MICA Composites (실란처리된 Epoxy/MICA 콤포지트의 열적, 기계적 전기적 특성연구)

  • Park, Jae-Jun
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.62 no.2
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    • pp.213-218
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    • 2013
  • In this study, epoxy/mica composite was prepared by mixing with mechanical stirrer together with homogenizer, and the effect of amino-type silane coupling agent was also studied. To reduce the viscosity without any decrement of other properties, 1,4-Butanediol diglycidyl ether (1,4-BDGE) as an aliphatic epoxy reactive diluent was introduced to the epoxy/mica composite in order to use as vanish for high voltage motor and generator stator winding. It was confirmed by scanning electron microscopy (SEM) observation that interfacial characteristics between organic epoxy and inorganic mica was modified by coupling agent treatment so that glass transition temperature increased, and tensile strength and electrical breakdown strength increased. The properties were estimated by Weibull statistical analysis and the ac electrical breakdown strength was 20.2% modified by treating silane coupling agent.