• 제목/요약/키워드: Electronic transition

검색결과 979건 처리시간 0.026초

BLN-PZT 세라믹의 상전이 특성 (Phase Transition Characteristics of the BLN - PZT Ceramics.)

  • 류기원;이영종;배선기;이영회
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 1994년도 춘계학술대회 논문집
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    • pp.25-33
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    • 1994
  • Temperature dependences of the remanent polarization $P_{\gamma}$/(T), effective birefringence ㅿn(T). dielectric constant K(T) and quadratic electro-optic coefficient R(T) of the two-stage sintered xBa(La$_{1/2}$Nb$_{1/2}$)O$_3$Pb$(Zr_{y}Ti_{1-y})O-{3}$(x=0.085, 0.09, 0.40$\leq$y$\leq$0.70)ceramics were investigated. Increasing the PbZrO$_3$ contents, the crystal structure of a specimen was varied from tetragonal and rhombohedral to cubic, and the phase transition was showed a diffuse phase transition(DPT) characteristics. Especially. in the compositions which located on the PE-FE phase boundary were showed a discrepancy between curie temperature and temperature range which a macroscopic polarization and a effective birefringence were disappeared.

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VDF/TrFE 공중합체의 히스테리시스 및 온도특성 (A study on hysteresis and temperature properties of VDF/TrFe copolymer)

  • 방태찬;김종경;강대하
    • E2M - 전기 전자와 첨단 소재
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    • 제10권2호
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    • pp.156-165
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    • 1997
  • D-E hysteresis loops have been measured for the 65/35 mole % copolymer of vinylidene fluoride and trifluoroethylene over wide temperature range. The remanent polarization and the coercive field at room temperature were estimated to be 75 mC/m$^{2}$ and 55 MV/m respectively. D-E hysteresis loops were observed even below the glass transition temperature(-20.deg. C) and the remanent polarization and the coercive field were larger, as the temperature lower. It seems that the remanent polarization and the coercive field depend on the amorphous region as well as crystalline region in this copolymer. And the ferroelectric-to-paraelectric phase transition was observed at 90.deg. C on heating and 80'C on cooling. Double hysteresis loops were observed at the temperature(85.deg. C) of paraelectric phase.

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선경사각에 따른 광학적 자기보상 스플레이 셀의 상전이와 응답속도 연구 (Study on Phase Transition and Response Time of Optically Compensated Splay Cell according to Pretilt Angle)

  • 황성한;정병선;황정연;서대식;이승희
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2006년도 하계학술대회 논문집 Vol.7
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    • pp.422-423
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    • 2006
  • We have studied phase transition time and response time of optically compensated splay(OCS) cell as a function of surface pretilt angle. With decreasing surface pretilt angle, phase transition time decreases and response time becomes faster in the OCS cell. Besides, the more surface pretilt angle decreases, the easier OCS structure is obtained.

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보조 회로를 활용한 ZCZVT 소프트 스위칭 플라이백 컨버터 (A Zero-Current-Zero-Voltage-Transition Flyback Converter using Auxiliary Circuit)

  • 주현승;최현칠
    • 전력전자학회논문지
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    • 제23권6호
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    • pp.397-402
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    • 2018
  • In this study, a high-efficiency flyback converter that uses a soft-switching auxiliary circuit is proposed. The structure of the proposed converter adds an inductor, switch, diode, and capacitor to the conventional flyback converter. The switch in the auxiliary circuit and the main switch are turned on and off under soft-switching conditions. Therefore, the switching losses of the proposed flyback converter are considerably smaller than those of conventional flyback converters. The performance of the proposed flyback converter is validated by experiments on a 100 W single-output flyback converter prototype, and design guidelines are presented.

리셋 권선을 사용하지 않는 새로운 형태의 영전류 천이형 포워드 컨버터 (A New Zero-Current-Transition Forward Converter without Reset Turn)

  • 백은성;최현칠
    • 전력전자학회논문지
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    • 제27권6호
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    • pp.464-470
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    • 2022
  • A new type of soft-switching forward converter is proposed in this study. By adding only a few components, the inductor, diode, switch, and capacitor exhibit higher efficiency than the conventional forward converter. Therefore, the switching losses of the proposed forward converter are considerably reduced compared with those of the conventional forward converter. In addition, the reset winding is not used because of the capacitor employed in the auxiliary circuit. The auxiliary capacitor is adopted for zero-current-transition operation and for dissipating magnetization energy. The performance of the proposed forward converter is validated using experimental results from a 60 W, single-output, forward converter prototype, and design guidelines are presented.

The Study on the Phase Transition and Piezoelectric Properties of Bi0.5(Na0.78K0.22)0.5TiO3-LaMnO3 Lead-free Piezoelectric Ceramics

  • Lee, Ku Tak;Park, Jung Soo;Cho, Jeong Ho;Jeong, Young Hun;Paik, Jong Hoo;Yun, Ji Sun
    • 한국세라믹학회지
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    • 제52권4호
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    • pp.237-242
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    • 2015
  • $Bi_{0.5}(Na_{0.78}K_{0.22})_{0.5}TiO_3$ (BNKT) lead-free piezoelectric ceramics modified by $LaMnO_3$ (LM) were fabricated by conventional solid-state method. The crystal structure and the morphology of the lead free ceramics were analyzed by XRD (X-ray diffraction) and FE-SEM (Field Emission Scanning Electron Microscopy). The LM modified BNKT ceramics have a phase transition from ferroelectric tetragonal to non-polar pseudo-cubic. Despite decreases in the remnant polarization ($P_r$) and coercive field ($E_c$) in the P-E hysteresis loops, the electric-field induced strain properties were significantly enhanced by the LM modification. The highest value of $S_{max}/E_{max}=412pm/V$ at an applied electric field of 5 kV/mm was found in BNKT-0.01LM ceramic.

Factors Affecting the Magnitude of the Metal-Insulator Transition Temperature in AMo4O6 (A=K, Sn)

  • Jung, Dong-Woon;Choi, Kwang-Sik;Kim, Sung-Jin
    • Bulletin of the Korean Chemical Society
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    • 제25권7호
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    • pp.959-964
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    • 2004
  • A low-dimensional metal frequently exhibits a metal-insulator transition through a charge-density-wave (CDW) or a spin-density-wave (SDW) which accompany it's structural changes. The transition temperature is thought to be determined by the amount of energy produced during the transition process and the softness of the original structure. $AMo_4O_6$ (A=K, Sn) are known to be quasi-one dimensional metals which exhibit metalinsulator transitions. The difference of the transition temperatures between $KMo_4O_6$ and $SnMo_4O_6$ (A=K, Sn) is examined by investigating their electronic and structural properties. Fermi surface nesting area and the lattice softness are the governing factors to determine the metal-insulator transition temperature in $AMo_4O_6$ compounds.

균질기를 이용한 에폭시-층상 실리케이트 나노콤포지트 분산 특성 (Dispersion Properties of Epoxy-layered Silicate Nanocomposites Using Homogenizer)

  • 이상극;박재준
    • 한국전기전자재료학회논문지
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    • 제26권2호
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    • pp.126-133
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    • 2013
  • This paper presents a study on the dispersion effect of the X-Ray diffraction, glass transition and DMA properties of organic modifier clay/epoxy nanocomposites produced in a homogenizer. Several experiments were conducted including different types of dispersion condition with varying processing conditions such as homogenizer rotor speed and applied time of homogenizer. The effects of these variables on the dispersion properties of nanocomposites were then studied. In order to fully understand the experimental results, a X-ray diffraction, DSC and DMA were used to investigate the effect of above mentioned variables on microstructure and intercalation/exfoliation of organic modifier clay/epoxy nanocomposites. The results from this work could be used to determine the best processing condition to obtain appropriate levels of d-spacing, glasss transition temperature and storage modulus in organic modifier clay/epoxy nanocomposites.

Solvent Effects on the Solvatochromism of 7-Aminocoumarin Derivatives in Neat and Binary Solvent Mixtures: Correlation of the Electronic Transition Energies with the Solvent Polarity Parameters

  • Choi, Jin-Yeong;Park, Eun-Ju;Chang, Seung-Hyun;Kang, Tai-Jong
    • Bulletin of the Korean Chemical Society
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    • 제30권7호
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    • pp.1452-1458
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    • 2009
  • The change in the electronic absorption and emission energy of 7-aminocoumarin derivatives in binary solvent mixtures has been studied. The electronic transition energy along with the Stokes' shift is correlated with the orientation polarizability of the solvent as well as the empirical solvent polarity parameters $E_T$ (30). It is observed that the emission peak shift traces the change of $E_T$ (30) value very closely in binary solvent mixtures. The emission transition more strongly depends on the solvent polarity than the absorption, which indicates the dipole moment gets larger on excitation. From the dependence of the Stokes’ shift of 7-aminocoumarins with the solvent polarity parameters and the ground state dipole moment obtained by the semi-empirical calculations, the excited state dipole moment was estimated. The fluorescence lifetime change of 7-aminocoumarins in binary solvent mixtures was measured and the results are explained in terms of molecular conformation and solvent polarity. The study indicates the empirical solvent polarity $E_T$ (30) is a good measure of microscopic solvent polarity and it probes in general the non-specific solvent interactions.