• 제목/요약/키워드: Electronic equilibrium

검색결과 186건 처리시간 0.022초

$e^-$-$CF_4$산란중에서 전자군의 확산계수 및 에너지분포함수 연구 (Analysis of Electron Swarm Diffusion Coefficients and Energy Distribution Function in $e^-$-$CF_4$ Scattering)

  • 하성철;임상원
    • E2M - 전기 전자와 첨단 소재
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    • 제10권4호
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    • pp.342-348
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    • 1997
  • In this paper, the behavior of electron swarm parameters and energy distribution function of the discharge under high E/N condition in e$^{-10}$ -CF$_{4}$ gas have been analysed over the E/N range from 1-300(Td) by the MCS and BEq methods using set of electron collision cross section determined by the authors. The swarm parameters and energy distribution function have been calculated for the pulsed Townsend, steady-state Townsend and Time of Flight methods. The results gained that the value of electron swarm parameters such as the electron drift velocity, the electron ionization and attachment coefficients and longitudinal diffusion coefficients in agreement with the experimental and theoretical data for a range of E/N. The electron energy distribution function has been explained and analysed in e$^{-10}$ -CF$_{4}$ at E/N : 5, 10, 100, 200, 300(Td) for a case of the equilibrium region in the mean electron energy and respective set of electron collision cross sections. The validity of the results has been confirmed by TOF and SST methods.

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A study on sliding surface design

  • Zhang, Yifan.;Lee, Sanghyuk
    • 중소기업융합학회논문지
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    • 제4권2호
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    • pp.25-31
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    • 2014
  • 비선형시스템에 대한 슬라이딩 모드제어 기법에 대한 연구를 수행하였다. 비선형 시스템의 파라미터가 제어성능과 간인성에 대한 관계를 구명하였다. 제어성능을 파악하기 위하여 역진자 시스템에적용하여 보았고, 다른 초기값, 슬라이딩 표면 그리고 입력값의 변화를 통하여 비교결과를 얻었다. 제어값은 제한적이었으며 슬라이딩 표면 역시 예외없이 제한폭을 나타냈다. 채터링 현상은 피할수 없이 존재하였으며, 이를 극복하기 위하여 수정된 불연속 제어기를 사용하여 현상을 감소시켰다.

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Synthesis and Properties of High Voltage Silicone Rubber by Platinum-based Flame Retardant

  • Jung, Se-Young;Kim, Byung-Kyu
    • Transactions on Electrical and Electronic Materials
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    • 제7권6호
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    • pp.283-292
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    • 2006
  • So that high-strength and electrical properties apply by excellent high voltage insulator electricity material, ATH content and platinum-based flame retardant that influence in flame retardant and tracking characteristic among composite of silicone rubber studied mechanical strength and influence getting to electrical properties. Composition of ${\alpha}$, ${\omega}-vinyl$ poly (dimethyl-methylphenyl) siloxane(VPMPS) of a polymer quantity made doing mole of D4, $D3^{Me,Ph}$ and VMS by 1000:15:0.2 mole ratio and uses basic catalyst tetramethylammonium silanolate(TMAS) and do opening equilibrium polymerization to be used to main polymer for high voltage insulation insulator. Control ATH content and content of platinum-based flame retardant and made high voltage insulation silicone rubber. Measured mechanical strength of making silicone rubber using UTM, and tracking characteristic according to standard of IEC 60587, flame retardant test studied effect that flame retardant characteristic gets in tracking characteristic, measuring according to UL94V method of test.

$CH_4$ 기체의 전자에너지 분포함수 해석 (The Analysis of Electron Energy Distribution Function in $CH_4$ Gas)

  • 김상남;성낙진
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2004년도 춘계학술대회 논문집
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    • pp.43-46
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    • 2004
  • This paper describes the information for quantitative simulation of weal이y ionized plasma. We must grasp the meaning of the plasma state condition to utilize engineering application and to understand materials of plasma state. Using quantitative simulations of weakly ionized plasma, we can analyze gas characteristic. In this paper, the electron transport characteristic in $CH_4$ has been analysed over the E/N range 0.1~300[Td], at the $300[_{\circ}K]$ by the two tenn approximation Boltzmann equation method and Monte Carlo Simulation. Boltzmann equation method has also been used to predict swarm parameter using the same cross sections as input. The behavior of electron has been calculated to give swarm parameter for the electron energy distribution function has been analysed in $CH_4$ at E/N=10, 100 for a case of the equilibrium region in the mean energy. The result of Boltzmann equation and Monte Carlo Simulation has been compared with experimental data by Ohmori, Lucas and Carter. The swarm parameter from the swarm study are expected to sever as a critical test of current theories of low energy scattering by atoms and molecules.

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Fluorescence Enhancement of 7-Diethylamino-4-methylcoumarin by Noncovalent Dipolar Interactions with Cucurbiturils

  • Park, Mee Ock;Moon, Myung Gu;Kang, T.J.
    • Bulletin of the Korean Chemical Society
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    • 제34권5호
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    • pp.1378-1382
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    • 2013
  • We have investigated the complex forming behavior of cucurbit[6]urils(CB6) and cucurbit[7]urils(CB7) with 7-diethylamino-4-methylcoumarin(C460) in water. The electronic absorption maximum of C460 shows bathochromic shift with the addition of CB7 and fluorescence intensity is greatly increased, while CB6 has no noticeable effects on the spectroscopic properties of C460. It is noted that CB7 interacts more strongly with C460 than CB6 does. Fluorescence lifetime also significantly increased for the CB7 complex, which is attributed to reduced polarity surrounding C460 and/or C460 being in a restricted environment. The stoichiometry for the complex formation determined from the fluorescence titration measurement indicates that 2:1 complex in which two CB7 molecules bind to C460 is formed. Thus, two step equilibrium processes are suggested for the complex formation and the binding constants are estimated. The semi-empirical electronic structures calculations indicate that C460 is not included in the CB7 cavity but interacts noncovalently with the portal carbonyls of CB7.

몬테칼로법을 이용한 Ar기체의 전자수송계수에 관한 연구 (A study on the electron transport coefficients using monte carlo method in argon gas)

  • 하성철;전병훈
    • E2M - 전기 전자와 첨단 소재
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    • 제8권6호
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    • pp.685-692
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    • 1995
  • The electron transport coefficients in argon gas is studied over the range of E/N values from 85 to 566 Td by the Monte Carlo method considering the latest cross section data. The result of the Monte Carlo method analysis shows that the value of the electron transport coefficients such as the electron drift velocity, the ratio of the longitudinal and transverse diffusion coefficients to the mobility. It is also found that the electron transport coefficients calculated by the two-term approximation analysis agree well with those by Monte Carlo calculation. The electron energy distributions function were analysed in argon at E/N=283, and 566 Td for a case of the equilibrium region in the mean electron energy. A momentum transfer cross section for the argon atom which was consistent with both of the present electron transport coefficients was derived over the range of mean electron energy from 10.3 to 14.5 eV, also suggested as a set of electron cross section for argon atom. The validity of the results obtained has been confirmed by a Monte Carlo simulation method.

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$SF_{6+}Ar$혼합기체의 전자수송특성 개선에 관한 연구 (A Study on the Improvement of the Electron Transport Properties in $SF_{6+}Ar$ Mixtures Gas)

  • 하성철;김상남;유회영;서상현;임상원;전병훈
    • 한국전기전자재료학회논문지
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    • 제11권1호
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    • pp.67-73
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    • 1998
  • In this paper, the electron swarm parameters in the 0.5% and 0.2% SF\ulcorner+Ar mixtures are measured by time of flight method over the E/N(Td) range from 30 to 300(Td). The measurements have been carried out by the double shutter drift tube with variable drift distance from the cathod. A two-term approximation of the boltzmann equation analysis and Monte Carlo simulation have been also used to study electron transport coefficients. We have calculated W, $ND_L,\;ND_T,\;\alpha,\;\eta,\;\alpha-\eta$, and the limiting breakdown electric field to gas mixtures ratio in pure $SF_6$+Ar mixtures. The electron energy distribution function has been analysed in $SF_6$+Ar mixtures at E/N : 200(Td) for a case of the equilibrium region in the mean electron energy. The measured results and the calculated results have been compared each other.

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First-principles study of the initial-stage oxidation of Si(1110)-(7x7)

  • Lee, Sung-Hoon;Kang, Myung-Ho
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2000년도 제18회 학술발표회 논문개요집
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    • pp.147-147
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    • 2000
  • Chemisorption of oxygen molecules on the Si(111)-(7x7) surface has been studied extensively as a model for the initial-stage oxidation of the surface. The basic step to the surface oxidation is the dissociation of the adsorbed O2 molecules, but the dissociation procedure and the atomic structure of the reaction products still remains as a subject of debates. We present here density-functional theory calculations on the initial-stage oxidation states of the Si adatom site for all possible dissociation configurations that can be generated by multiple O2 reactions. We determine the equilibrium structures and analyze their electronic and vibrational properties in comparison with measured UPS, XPS, and EELS spectra. The O(ad) atom bonded on top of the Si adatom is always less stable than the O(ins) atom inserted into one of the adatom backbonds. Our electronic and vibrational analysis demonstrates further that the O(ad) and O(ins) atoms account well for the metastable and stable features in previous experiments, respectively. Moreover, the calculated decay pathways of the metastable structures and the comparison of the calculated O ls core-level shifts with XPS data provides a convincing argument in unambiguously identifying the experimental metastable and stable structures, thereby making it possible to build a correct atomic-scale picture of the initial-stage oxidation process on this surface.

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Ultrafast probes of coherent oscillations in Fe-based superconductors

  • Kim, K.W.
    • 한국초전도ㆍ저온공학회논문지
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    • 제19권1호
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    • pp.1-4
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    • 2017
  • Forefront ultrafast experimental techniques have recently proven their potential as new approaches to understand materials based on non-equilibrium dynamics in the time domain. The time domain approach is useful especially in disentangling complicated coupling among charge, spin and lattice degrees of freedom. Various ultrafast experiments on Fe-based superconductors have observed strong coherent oscillations of an $A_{1g}$ phonon mode of arsenic ions, which shows strong coupling to the electronic and magnetic states. This paper reviews the recent reports of ultrafast studies on Fe-based superconductor with a focus on the coherent oscillations. Experimental results with ultrashort light sources from the terahertz-infrared pulses to the hard X-rays from a free electron laser will be presented.

게임이론을 이용한 제조업체의 직접마케팅 진입전략 분석 (Game Theoretic Analysis of the Direct Marketing Channel Strategy of a Manufacturer)

  • 이민호;조형래
    • 산업경영시스템학회지
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    • 제32권3호
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    • pp.168-177
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    • 2009
  • The proliferation of the internet and electronic commerce has given the manufacturers the opportunity of direct marketing. This study analyzes the decision of manufacturers regarding whether to sell the products through independent sales company or to sell the products to the consumer directly. To do this, a new demand function is proposed and sub and super games are modeled and analyzed based on the demand function. By analyzing the Nash equilibria, it is shown that the manufacturers' decision of direct or indirect marketing not only depends on the competitiveness between the products but the absolute and relative marketing capabilities of the manufacturers. It is also shown that, in some cases, the manufactures have incentive to rise the competitiveness between the products to maximize the channel profit.