• Title/Summary/Keyword: Electronic coupling

Search Result 939, Processing Time 0.021 seconds

Multistep Quantum Master Equation Theory for Response Functions in Four Wave Mixing Electronic Spectroscopy of Multichromophoric Macromolecules

  • Jang, Seog-Joo
    • Bulletin of the Korean Chemical Society
    • /
    • v.33 no.3
    • /
    • pp.997-1008
    • /
    • 2012
  • This work provides an alternative derivation of third order response functions in four wave mixing spectroscopy of multichromophoric macromolecular systems considering only single exciton states. For the case of harmonic oscillator bath linearly and diagonally coupled to exciton states, closed form expressions showing all the explicit time dependences are derived. These expressions can provide more solid physical basis for understanding 2-dimensional electronic spectroscopy signals. For more general cases of system-bath coupling, the quantum master equation (QME) approach is employed for the derivation of multistep time evolution equations for Green function-like operators. Solution of these equations is feasible at the level of 2nd order non-Markovian QME, and the new approach can account for inter-exciton coupling, dephasing, relaxation, and non-Markovian effects in a consistent manner.

A study on the improvement of thermostability and dielectric breakdown strength for packaging and impregnating epoxy composite materials for electrical machines and apparatus (전기 기기용 봉지 및 함침 에폭시 복합 재료의 내열성 및 절연파괴 특성 개선에 관한 연구)

  • 김명호;김재환
    • Electrical & Electronic Materials
    • /
    • v.7 no.6
    • /
    • pp.527-533
    • /
    • 1994
  • In this study, it was studied on dielectric breakdown strength and thennostability properties due to the structure variation of matrix resin and treatment of coupling agent of epoxy insulating materials. The interpenetrating network structure was formed by simultaneous heating curing the epoxy resin with single network structure and the methacrylic acid resin. Also inner structure was observed and the glass transition temperature was measured on these three type specimens. Dielectric breakdown properties were investigated by applying DC, AC and impulse voltage. As a result, the glass transition temperature and the dielectric breakdown strength of specimen with interpenetrating network structure was more higher than another two type specimens.

  • PDF

Poling Effect on Piezoeletric Ceramics for Air Medium (공기 매질에 의한 압전 세라믹스의 분극효과)

  • Kim, Yong-Hyuk
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.23 no.6
    • /
    • pp.464-470
    • /
    • 2010
  • A new method for the poling of piezoelectric ceramics with an air insulation medium in stead of silicon oil is described. A similar variation of electromechanical coupling coefficient $K_t$, for an air medium is observed in comparison to that of the material poled by the conventional poling method using a silicon oil medium. Different poling parameters such as dielectric constant $\varepsilon^T$ and frequency deviation ${\Delta}f$ are studied as well as the influence on the aging effect. The required poling factors to achieve the optimal piezoelectric characteristics are electric field, 2 kV/mm, temperature $100^{\circ}C$, and poling time 30 Min. From this result electric field 3 kV/mm atmosphere airs there being will be able to use with the polarization insulation medium about the piezoelectric material, confirmed.

Trajectory of Resonant Displacement of Thickness Vibration Mode Piezoelectric Devices According to Diameter/Thickness Ratio (두께와 직경 비에 따른 두께진동모드 압전소자의 공진 변위 궤적)

  • Jeong, Yeong-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.25 no.2
    • /
    • pp.105-109
    • /
    • 2012
  • In this study, thickness vibration mode piezoelectric devices for AE sensor application were simulated using ATILA FEM program, and then fabricated. Trajectory resonant displacement and electro mechanical coupling factors of the piezoelectric devices were investigated. The simulation results showed that excellent displacement and electro mechanical coupling factor was obtained when the ratio of diameter/thickness($\Phi/T$) was 0.75. The piezoelectric device of $\Phi/T$=0.75 exhibited the optimum values of fr= 183 kHz, displacement= $4.44{\times}10^{-7}[m]$, $k_{33}$= 0.69, which were suitable for the application of AE sensor piezoelectric device.

Optimization of 1-3 Type Piezocomposite Structures Considering Inter-Pillar Vibration Modes (Inter-Pillar 진동 모드를 고려한 1-3형 압전복합체의 구조 최적화)

  • Pyo, Seonghun;Kim, Jinwook;Roh, Yongrae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.26 no.6
    • /
    • pp.434-440
    • /
    • 2013
  • With polymer properties and ceramic volume fraction as design variables, the optimal structure of 1-3 piezocomposites has been determined to maximize the thickness mode electromechanical coupling factor. When the piezocomposite vibrates in a thickness mode, inter-pillar resonant modes are likely to occur between lattice-structured piezoceramic pillars and polymer matrix, which significantly deteriorates the performance of the piezocomposite. In this work, a new method to design the structure of the 1-3 type piezocomposite is proposed to maximize the thickness mode electromechanical coupling factor while preventing the occurrence of the inter-pillar modes. Genetic algorithm was used for the optimal design, and the finite element analysis method was used for the analysis of the inter-pillar mode.

유리섬유/에폭시 복합절연재료의 계면 접착력 개선에 관한 연구 2

  • 김순태;황영한;박홍태;엄무수;이규철;이종호
    • Electrical & Electronic Materials
    • /
    • v.8 no.4
    • /
    • pp.434-442
    • /
    • 1995
  • To improve dielectric and mechanical properties of insulating composite by plasma surface treatment, new plasma surface treatment process is designed with concentric and hemi-circle electrodes system. the plasma, which is generated between anode and cathode, is induced to the upper side of the electrode system and treats the surface of the insulators. The optimal surface treatment condition is that pressure : 0.5[torr], flux density : 100[gauss], discharge current : 500[mA] and treatment time : 3 minutes. The composite filled with glass cloth surface-treated by plasma shows the improvement in electric and mechanical properties, comparing non- and coupling agent treated samples.

  • PDF

A Study on the Characteristics of Circular Piezoelectric Transformner which has Multi-layered Crescent-Shaped Input Electrode (적층형 Crescent-Shaped Input Type 원형 압전변압기의 특성)

  • Jeong, Seong-Su;Park, Tae-Gone
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2006.11a
    • /
    • pp.223-224
    • /
    • 2006
  • This paper present a new disk-type piezoelectric transformer. The input side of the transformer has a crescent-shaped electrode and the output side has a focused poling direction. This transformer has multi-layered structure. The piezoelectric transformers operated m each transformer's resonance vibration mode. The electrodes and poling directions on commercialy available piezoelectric ceramic disks were designed so that the planar or shear mode coupling factor ($k_p,\;k_{15}$) becomes effective rather than the transverse mode coupling factor ($k_{31}$). The Resonance frequency is 65.22[kHz] and maximum voltage step-up ratio is 149. Multi-layered transformer has better efficiency and step-up ratio than the single-layered transformer.

  • PDF

Microstructure and Ferroelectric Properties of Low Temperature Sintering PMN-PNN-PZT Ceramics with Sintering Temperature (저온소결 PMN-PNN-PZT세라믹스의 소결온도에 따른 미세구조 및 강유전특성)

  • Yoo, Ju-Hyun;Lee, Hyun-Seok;Lee, Sang-Ho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.19 no.12
    • /
    • pp.1118-1122
    • /
    • 2006
  • In this study, in order to develop the low temperature sintering multilayer piezoelectric actuator, PMN-PNN-PZT system ceramics were manufactured and their microstructure, ferroelectric and piezoelectric properties were investigated. By increasing sintering temperature, remanent polarization$(P_r)$ was increased due to the increase of sinterability and grain size. However, coercive $field(E_c)$ showed an opposite tendency to remanent polarization owing to the feasibility of domain wall motion. At the sintering temperature of $900^{\circ}C$, dielectric $constant({\varepsilon}_r)$, electromechanical coupling $factor(k_p)$, piezoelectric $constant(d_{33})$ and mechanical quality $factor(Q_m)$ showed the optimal value of 1095, 0.60, 363 and 1055, respectively, for multilayer piezoelectric actuator application.

Polarizations and Electrical Properties of PMS-PZT Ferroelectric Materials (PMS-PZT계 강유전 재료의 분극과 전기적 특성)

  • Kim, J.R.;Kim, H.S.;Lee, H.Y.;Oh, Y.W.
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
    • /
    • v.17 no.12
    • /
    • pp.1314-1319
    • /
    • 2004
  • The rosen types of piezo-transformers were prepared and electrical properties were investigated in order to establish the optimum parameters in the process of polarization for ferroelectric materials. Polarization was readily originated with increasing the external energy such as an applied voltage, time, and temperature so that the planar coupling factor and voltage gain were saturated under the conditions of over 14$0^{\circ}C$, applied voltage and time of 4 kV/mm and 3 minutes respectively. The empirical equation for domain rotation probability, which was in proportion to square of an applied voltage and temperature and square root of time, as functions of the above parameters was defined.

Development of dual band directional coupler utilizing Low Temperature Co-fired ceramics technology (저온 동시소성 기술을 이용한 Dual band 방향성 결합기 개발에 관한 연구)

  • Yoo, Myong-Jae;Yoo, Jo-Shua;Park, Seong-Dae;Lee, Woo-S.;Kang, Nam-K.
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 2004.07b
    • /
    • pp.574-577
    • /
    • 2004
  • A coupler is a microwave passive component used for power coupling or dividing. Regarding the trend of current telecommunication systems it is highly desirable for monolithic integration of passive components as such LTCC(Low temperature cofired ceramics) technology offers potential advantage in size, cost and performance. Utilizing LTCC technology a 2012 size type dual band coupler for DCS and EGSM band was fabricated. Its characteristics such as coupling, insertion loss, isolation and directivity was measured and compared with simulation results

  • PDF