• 방사선산업학회지
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• 제18권3호
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• pp.235-240
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• 2024

Electron beam technology has recently attracted attention as one of the powerful air pollution control methods. In this study, methyl mercaptan decomposition by electron beam in a continuous gas flow system was studied. To this, the effect of gas flowrate, which is one of important operating variables in the continuous gas flow electron beam process, on methyl mercaptan treatment efficiency was studied. In particular, the treatment efficiency and the reaction kinetics of methyl mercaptan decomposition were compared when calculated based on the absorbed dose and when calculated based on the current intensity of electron beam. When based on the electron beam absorbed dose, the treatment efficiency and 1st-order reaction constant increased as the gas flowrate was increased, contrary to the trends in general chemical reactions. However, when based on the current intensity, the treatment efficiency and 1st-order reaction constant increased as the gas flowrate was decreased, which can be theoretically explained. This is due to the fact that the current intensity increased as the gas flowrate was increased, resulting in improved the electron beam treatment efficiency. In conclusion, it is necessary to consider not only the absorbed dose but also the current intensity of electron beam in order to explain the results of reaction efficiencies and kinetics in the continuous flow electron beam gas treatment process.

• 대한방사선기술학회지:방사선기술과학
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• 제22권2호
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• pp.53-56
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• 1999

A Gaussian distribution was parametrized for the initial distribution of the electron beam emitted from a 6MeV medical linear accelerator. A percent depth dose was measured in a water phantom and the corresponding Monte Carlo calculations were performed starting from a Gaussian distribution for a range of standard deviations, ${\sigma}=0.1$, 0.15, 0.2, 0.25, and 0.3 with being the mean value for the Incident beam energy. When measurement and calculation were compared, the calculation with the Gaussian distribution for ${\sigma}=0.25$ turned out to agree best with the measurement. The results from the present work can be utilized as input energy data in planning an electron beam therapy with a Monte Carlo calculation.

• Journal of Radiation Protection and Research
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• 제45권1호
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• pp.11-15
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• 2020

Background: There have been various studies to investigate the mechanisms of DNA damage from low-energy electrons. To understand the mechanism of these strand breaks, it is necessary to investigate the dissociation mechanism of the DNA constituents, that is, bases, sugars, and phosphates. Materials and Methods: We studied the dissociation of thymine base upon interaction with low-energy electrons. For this experiment, thymine powder was pressed onto the indium base and irradiated by 5 eV electrons. Results and Discussion: Non-irradiated and irradiated thymine samples were compared and analyzed using the X-ray photoelectron spectroscopic technique to analyze the dissociation patterns of the molecular bonds after low-energy electron irradiation of thymine. Conclusion: With 5 eV electron irradiation, C-C and N-C = O bonds are the primary dissociations that occur in thymine molecules.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 하계학술대회 논문집 Vol.3 No.2
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• pp.878-881
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• 2002

Energy distribution function for electrons in $SF_6+Ar$ mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range 30 ~ 300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6+Ar$ mixtures were measured by time-of-flight(TOF) method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

• 대한전기학회:학술대회논문집
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• 대한전기학회 1990년도 하계학술대회 논문집
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• pp.257-260
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• 1990

Monte Carlo simulations of electron impact ionization in silicon utilizing simple spherical band approximation including L valley are presented. The mean energy of electron at high electric field is lowered and the threshold energy of electron impact ionizaiotn is smeared out to $E_x$ by including L valley. This work also presents the importance of the modeling of L valley by calculating the electron population rate of it over the threshold energy of eletron impact ionization, which is higher than 10%

• 한국결정성장학회지
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• 제6권4호
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• pp.543-551
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• 1996

단결정 표면 및 에피 증착증 표면에 대한 연구가 많아지면서 고에너지전자회절 및 반사전자현미겨의 이용도 늘고 있다. 국내에서는 아직 보편화 되지 않은 이들 두 기술을 위한 시편분비 과정을 요약하였고, 고에너지전자회절 연구시 매우 유용하게 쓰이는 연속 고에너지전자회절 패턴 지도 작성법에 대해 설명하고 그 예를 제시하였다.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2007년도 하계학술대회 논문집 Vol.8
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• pp.468-469
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• 2007

In this paper, the electron transport characteristics in $CF_4$ has been analysed over the E/N range 1~300[Td] by a two-tenn approximation Boltzmann equation method and by a Monte Carlo simulation. The motion has been calculated to give swarm parameters for the electron drift velocity, longitudinal diffusion coefficient, the ratio of the diffusion coefficient to the mobility, electron ionization and attachment coefficients, effective ionization coefficient, mean energy, collision frequency and the electron energy distribution function. The swarm parameter from the swarm study are expected to serve as a critical test of current theories of low energy electron scattering by atoms and molecules, in particular, as well as crucial information for quantitative simulations of weakly ionized plasmas.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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• pp.578-580
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• 2005

Energy distribution function for electrons in SF6-Ar mixtures gas used by MCS-BEq algorithm has been analysed over the E/N range 30~300[Td] by a two term Boltzmann equation and by a Monte Carlo Simulation using a set of electron cross sections determined by other authors, experimentally the electron swarm parameters for 0.2[%] and 0.5[%] $SF_6$-Ar mixtures were measured by TOF method, The results show that the deduced electron drift velocities, the electron ionization or attachment coefficients, longitudinal and transverse diffusion coefficients and mean energy agree reasonably well with theoretical for a rang of E/N values. The results obtained from Boltzmann equation method and Monte Carlo simulation have been compared with present and previously obtained data and respective set of electron collision cross sections of the molecules.

• 방사선산업학회지
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• 제7권2_3호
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• pp.167-170
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• 2013

Lignin can be a valuable natural chemical resource. Structurally, lignin is a three-dimensional polymer made up of condensed C-C bonds and some ether linkages, most of which are not readily degraded. In this study, lignin carbonization under various electron beam pretreatment conditions was characterized through a thermogravimetric analysis (TGA), X-ray diffraction (XRD) and Raman spectroscopy. Lignin stabilization was controlled by various doses of electron beam irradiation corresponding to 50, 100, 200, 500 and 1,000 kGy; the carbonization process was performed under a nitrogen gas atmosphere at $1000^{\circ}C$ for 1 h. The TGA results showed that a 1,000 kGy lignin dose increased the residue weight from 39.96% to 45.23%, compared to non-irradiated lignin. This observation is in agreement with the XRD and Raman spectroscopy results, in which the two theta degrees and the degree of crystallization were improved by increasing the electron beam irradiation.

• Bulletin of the Korean Chemical Society
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• 제13권4호
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• pp.385-388
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• 1992

The transition probabilities for the thermal intramolecular electron transfer and the optical intervalence transfer band for a symmetric mixed-valence Cu(I)-Cu(II) compound were used to extract the PKS parameters $\varepsilon$ = -1.15, ${\lambda}$ = 2.839, and ${\nu}g$- = 923 $cm^{-1}$. These parameters determine the potential energy surfaces and vibronic energy levels. Three pairs of vibrational levels are below the top of the energy barrier in the lower potential surface. The contribution of each vibrational state to the intramolecular electron transfer was calculated. It is shown that the three pairs of vibrational states below the top of the barrier are responsible for most of the electron transfer at 261-306 K. So the intramolecular electron transfer in this system is a tunneling process. The transition probability exhibits the usual high-temperature Arrhenius behavior, but at lower temperature falls off to a temperature-independent value as tunneling from the lowest levels becomes the limiting process.