• Title/Summary/Keyword: Electron concentration

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Innovative Remediation of Arsenic in Groundwater by Nano Scale Zero-Valent Iron

  • Kanel, Sushil-Raj;Kim, Ju-Yong;Park, Heechul
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2003.09a
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    • pp.87-90
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    • 2003
  • This research examines the feasibility of using laboratory-synthesized nano scale zero-valent iron particles to remove arsenic from aqueous phase. Batch experiments were performed to determine arsenic sorption rates as a function of the nano scale zero-valent iron solution concentration. Rapid adsorption of arsenic was achieved with the nano scale zero-valent iron. Typically 1 mg $L^{-1}$ arsenic (III) was adsorbed by 5 g $L^{-1}$ nano scale zero-valent iron below the 0.01 g $L^{-1}$ concentration within 7min. The kinetics of the arsenic sorption followed pseudo-first-order reaction kinetics. Observed reaction rate constants ( $K_{obs}$) varied between 11.4 to 129.0 $h^{-1}$ with respect to different concentrations of nano scale zero-valent iron. A variety of analytical techniques were used to study the reaction products including HGAAS (hydride generator atomic adsorption spectrophotometer), SEM (scanning electron microscopy) and TEM (transmission electron microscopy). Our experimental results suggest novel method for efficient removal of arsenic Iron groundwater.r.

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Removal of methylene blue using lemon grass ash as an adsorbent

  • Singh, Harminder;Dawa, Tshering B.
    • Carbon letters
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    • v.15 no.2
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    • pp.105-112
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    • 2014
  • Wastewater from textile industries is a major cause of water pollution in most developing countries. In order to address the issues of water pollution and high cost for treatment processes, the use of an inexpensive and environmentally benign adsorbents has been studied. The objective was to find a better alternative to the conventional methods. Lemon grass waste (ash) collected from a lemon grass stream distillation subunit in Bhutan was tested for dye removal from aqueous solutions. The study investigated the removal of methylene blue using the following operational parameters: initial concentration (100-600 mg/L), contact time, adsorbent dose (0.1-0.55 gm/100 mL), and pH (3-10). It was found that the percentage removal of dye increased with a decrease of the initial concentration and increased contact time and dose of adsorbent. The basic pH solution of dye showed better adsorption capacity as compared to the acidic dye solution. Langmuir and Freundlich adsorption isotherms were fitted to the data well. Data fitted better to Lagergren pseudo 2nd order kinetics than a 1st order kinetic model. Surface morphology was also examined via scanning electron microscopy. An elemental analysis was also carried out and the chemical composition and functional groups were analyzed using energy dispersive X-ray spectroscopy and Fourier transform infrared spectroscopy techniques, respectively. The obtained results indicate that lemon grass ash could be employed as a low cost alternative to commercial activated carbon in wastewater treatment for the removal of dyes.

Ultrastructural Study of Induced Otic Vesicle from Isolated Xenopus Presumptive Ectoderm (Xenopus 초기배의 이낭과 동물극분리배양에서 유도된 이낭간의 형태비교)

  • Yoon, Chun-Sik;Kim, Hong-Duck;Cheong, Seon-Woo
    • Applied Microscopy
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    • v.27 no.2
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    • pp.189-196
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    • 1997
  • The ultrastrucures of Xenopus otic vesicle from normal embryo (st. 43) and induced otic vesicle from animal cap assay with Activin A were compared. Activin A was applied to the presumptive ectoderm at various concentrations for three days at $20^{\circ}C$. The results were almost identical to the reference studies, but it was found that the otic vesicle was induced at the concentration of 10 ng/ml in to)v rate. This otic vesicle may be secondarily induced by the neural tissue showed commonly at the concentration of 10 ng/ml. Otoliths were observed as three or four-axis crystaline bodies in the lumen of otic vesicle. In electron micrograph of the normal embryo, two kinds of microvilli were observed on the apical position of hair cells. One was small and common, the other was large-sized and sparsely distributed. In both cell of otic vesicle, mitochondria, golgi apparatus and multivesicular body were rich, so, they showed a lot of similarities in ultrastructure. However, the otolith was not found and microvilli were overexpressed in the otic vesicle induced by Activin A.

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Influence of Fast Neutron Irradiation on the Electrical and Optical Properties of Li Doped ZnSnO Thin Film Transistor (Li 도핑된 ZnSnO 박막 트랜지스터의 전기 및 광학적 특성에 대한 고속 중성자 조사의 영향)

  • Cho, In-Hwan;Kim, Chan-Joong;Jun, Byung-Hyuk
    • Korean Journal of Materials Research
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    • v.30 no.3
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    • pp.117-122
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    • 2020
  • The effects of fast neutron irradiation on the electrical and optical properties of Li (3 at%) doped ZnSnO (ZTO) thin films fabricated using a sol-gel process are investigated. From the results of Li-ZTO TFT characteristics according to change of neutron irradiation time, the saturation mobility is found to increase and threshold voltage values shift to a negative direction from 1,000 s neutron irradiation time. X-ray photoelectron spectroscopy analysis of the O 1s core level shows that the relative area of oxygen vacancies is almost unchanged with different irradiation times. From the results of band alignment, it is confirmed that, due to the increase of electron carrier concentration, the Fermi level (EF) of the sample irradiated for 1,000 s is located at the position closest to the conduction band minimum. The increase in electron concentration is considered by looking at the shallow band edge state under the conduction band edge formed by fast neutron irradiation of more than 1,000 s.

Organic Solar Cells with CuO Nanoparticles Mixed PEDOT:PSS Buffer Layer (산화구리 나노입자를 혼합한 PEDOT:PSS 박막을 이용한 유기 태양전지)

  • Oh, Sang Hoon;Heo, Seung Jin;Kim, Hyun Jae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.27 no.2
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    • pp.121-125
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    • 2014
  • In this research, nanocomposite layers consisting of poly (3,4,-ethylene dioxythiophene):polystyrene sulfonic acid (PEDOT:PSS) and CuO nanoparticles were investigated as hole transport layers in organic solar cells based on poly (3-hexylthiophene) (P3HT) as the electron donor and (6.6) phenyl-C61-butyric acid methyl ester (PCBM) as the electron acceptor. The addition of CuO nanoparticles to PEDOT:PSS layer improved the solar cell performance with 0.5% CuO nanoparticle concentration. At optimized concentration, CuO mixed PEDOT:PSS films had good electrical ($4.131{\Omega}{\cdot}cm$) and optical (transmittance > 90%) properties for using hole transporting layer. We investigated that improved solar cell performance with CuO nanoparticles mixed PEDOT:PSS films.

Calculation of Electron concentration and Electrostatic potential profile for $Al_{x}Gal{-x}As/Ga_{x}In1$_{-x}$As/GaAs HEMT device by 2-Dimensional Quantum Mechanical analysis) (2차원 양자 역학적 해석에 의한 고속 통신용 $Al_{x}Gal{-x}As/Ga_{x}In1$_{-x}$As/GaAs HEMT 소자의 전자 농도 및 전위분포 계산)

  • 송영진;황호정
    • Journal of the Korean Institute of Telematics and Electronics A
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    • v.30A no.3
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    • pp.76-87
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    • 1993
  • We present a self-consistent, 2-dimensional solution of the Poisson and Sch rodinger equation based on the finite difference method with a nonuniform mesh size for a AlGaAs/GaInAs/GaAs HEMT devide. During the interative self-consistent calculation, however, we calculate Schrodinger equation only a some region of device, not a fully region in order to save the moemory and the speed-up of computation, and then use the approximated data for the other region using by a interpolation method with a given values. Also we adopt the proper matrix transformation method that allows preservation of the symmetric, form of the discretized Schrodinger equation, even with the use of a nonumiform mesh size, therefor, can reduce the computation time. We calculate the wavefunction, eigenstates and the electron concentration uat channel layer nder the thermal equilibrium and the biased conditions, respectively. Also,these parameters are used to solve 2-dimensional tdistribution of potential in he entire region of device. It is proved that the method is very efficient in finding eigenstages extending over relatively large spatial area without loss of accuracy. So, it can be used rather easily in any sarbitrary modulation doped utucture.

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Relationship between Film Density and Electrical Properties on D.C. Magnetron Reactive Sputtered Sn-doped ${In_2}{O_3}$Films (D.C. 마그네트론 반응성 스퍼터링법에 의한 Sn-doped ${In_2}{O_3}$ 박막의 밀도와 전기적 특성과의 관계)

  • 이정일;최시경
    • Journal of the Korean Ceramic Society
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    • v.37 no.7
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    • pp.686-692
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    • 2000
  • Tin-doped In2O3 (ITO) films were fabricated using a d.c. magnetron reactive sputteirng of a In-10 wt% Sn alloy target in an Ar and O2 gas mixture. To understand the behavior of the carrier mobility in ITO films with O2 partial pressure, the resistivity, carrier concentration and mobility, film density, and intrinsic stress in the films were measured with O2 partial pressure. It was found experimentally that the carrier mobility increased rapidly as the film density increased. In the ITO film with the density close to theoretical one, the mean free path was the same as the columnar diameter. This indicated that the mobility in ITO films was strongly influenced by the crystall size. However, in the case where the film density was smaller than a theoretical density, the mean free paths were also smaller the columnar diameter. It was analyzed that the electron scattering at pores and holes within the crystalline was the major obstacle for electron conduction in ITO films. The measurement of intrinsic stress in ITO films also made it clear that the density of ITO films was controlled by the bombardment of oxygen neutrals on the growing film.

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Fabrication of Polycarbonate Nano Fibers Using Electrospinning (전기방사법을 이용한 Polycarbonate 나노 섬유 제조)

  • Kim Giltae;Park Sangkyoung;Lee Jaekeun;Ahn Youngchull
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.4 s.235
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    • pp.512-518
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    • 2005
  • Polymeric fibers with nanometer-scale diameters are produced by electrospinning. When the electrical forces at the surface of a polymer solution or melt overcome the surface tension then electrospinning occurs. Polycarbonate has been electrospun. Electrospun fibers are observed by scanning electron microscopy and transmission electron microscopy. The surface morphology of e-spun fiber has been studied by many variables that are involved in different polymer concentrations, solvent mixing ratios and ambient parameters. The average diameters of the electrospun fibers range from 200 nm to 4,570 nm when the PC concentration is decreasing from 15.5\;wt{\%}\;to\;25\;wt{\%}.$ The higher concentration of the polymer solution makes the fibers thicker due to preventing the fiber stretching. With respect evaporation effects, the solvent mixing ratios cause significant changes of the fiber size distribution. As a matter of fact the fiber diameter steadily increases with increasing amount of DMF until the solvent mixture is at THF:DMF ratio of 60:40.

Physiological Activity and Antioxidative Effect of Methanol Extract from Onion (Allium cepa L.) (양파 메탄올 추출물의 생리활성 및 항산화효과)

  • 김현구;곽희진;권영주;정필호;권중호
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.29 no.2
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    • pp.349-355
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    • 2000
  • Onion was extracted by methyl alcohol and some physiological activities and antioxidative effect of the extracts on soybean oil, corn oil, lard and shortening were compared with commercial antioxidants such as $\alpha$-tocopherol and BHT. The electron donating ability was about 70% at concentration above of 30mg/mL. Nitrite scavenging effects of all concentrations diminished at higher pH, while in the case of pH 1.2, it showed a nitrite scavenging effect of more than 80% af concentration above of 30mg/mL. And also, the angiotensin I-converting enzyme inhibitory effect was good above 80%. The soybean oil, corn oil, lard and shortening containing different levels of the onion extract were stored at 6$0^{\circ}C$ to evaluate the antioxidative activity of onion extracts. Peroxide value, acid value and TBA value of each oil were detected. Onion extract was very effective to retard oxidation of soybean oil, corn oil and lard, and especially, the very high antioxidative effect was observed for lard.

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A Study about the Efficiency of Organic Photovoltaic Device as a function of the Material Concentration (박막의 조성비율에 따른 유기태양전지의 효율성 연구)

  • Kim, Seung-Ju;Lee, Dong-Keun;Park, Jae-Hyung;Gong, Su-Cheol;Kim, Won-Ki;Ryu, Sang-Ouk
    • Journal of the Semiconductor & Display Technology
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    • v.8 no.3
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    • pp.1-5
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    • 2009
  • In this study, we have shown the power conversion efficiency of organic thin film photovoltaic devices utilizing a conjugated polymer/fullerene bulk-hetero junction structure. We use MDMO-PPV(Poly[2-methoxy-5-(3,7-dimethyloctyloxy -1,4-phenylenevinylene) as an electron donor, PCBM([6,6]-Phenyl C61 butyric acid methyl ester) as an electron accepter, and PEDOT:PSS used as a HTL(Hole Transport Layer). We have fabricated OPV(Organic Photovoltaic) devices as a function of the MDMO-PPV/PCBM concentration from 1:1 to 1:5. The electrical characteristics of the fabricated devices were investigated by means of I-V, P-V, F·F(Fill Factor) and PCE(power conversion efficiency). The power conversion efficiency was gradually increased until 1:4 ratio, also the highest efficiency of 0.4996% was obtained at the ratio.

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