• Title/Summary/Keyword: Electron concentration

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Effect of Air Exposure on ZnO Thin Film for Electron Transport Layer of Quantum Dot Light-Emitting Diode (ZnO 박막 전자수송층의 공기 노출에 의한 양자점 발광다이오드의 특성 변화)

  • Eunyong Seo;Kyungjae Lee;Jeong Ha Hwang;Dong Hyun Kim;Jaehoon Lim;Donggu Lee
    • Journal of Sensor Science and Technology
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    • v.32 no.6
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    • pp.455-461
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    • 2023
  • We investigated the electrical characteristics of ZnO nanoparticles (NPs) with air exposure that is a widely used electron transport layer for quantum dot light-emitting diodes (QLEDs). Upon air exposure, we observed changes in the density of states (DOS) of the trap levels of ZnO NPs. In particular, with air exposure, the concentration of deep trap energy levels in ZnO NPs decreased and electron mobility significantly improved. Consequently, the air-exposed ZnO reduced leakage current by approximately one order of magnitude and enhanced the external quantum efficiency at the low driving voltage region of the QLED. In addition, based on the excellent conductivity properties, high-brightness QLEDs could be achieved.

Design and optimization of thermal neutron activation device based on 5 MeV electron linear accelerator

  • Mahnoush Masoumi;S. Farhad Masoudi;Faezeh Rahmani
    • Nuclear Engineering and Technology
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    • v.55 no.11
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    • pp.4246-4251
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    • 2023
  • The optimized design of a Neutron Activation Analysis (NAA) system, including Delayed Gamma NAA (DGNAA) and Prompt Gamma NAA (PGNAA), has been proposed in this research based on Mevex Linac with 5 MeV electron energy and 50 kW power as a neutron source. Based on the MCNPX 2.6 simulation, the optimized configuration contains; tungsten as an electron-photon converter, BeO as a photoneutron target, BeD2 and plexiglass as moderators, and graphite as a reflector and collimator, as well as lead as a gamma shield. The obtained thermal neutron flux at the beam port is equal to 2.06 × 109 (# /cm2.s). In addition, using the optimized neutron beam, the detection limit has been calculated for some elements such as H-1, B-10, Na-23, Al-27, and Ti-48. The HPGe Coaxial detector has been used to measure gamma rays emitted by nuclides in the sample. By the results, the proposed system can be an appropriate solution to measure the concentration and toxicity of elements in different samples such as food, soil, and plant samples.

Ethanol Production by a New Method of Alginate-Immobilization (새로운 Alginate 고정화 방법에 의한 에탄올 생산)

  • Kim, Eun-Young;Kim, Seung-Wook;Kim, Keun
    • Microbiology and Biotechnology Letters
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    • v.21 no.4
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    • pp.373-380
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    • 1993
  • When the cells of yeast K35 were immobilized in Ca-alginate gel, cell concentration and viability decreased as alginate concentration increased. Considering the results, 2% (w/v) Ca-alginate concentration would be suitable. Among various concentrations of additives and cross-lin-king agent, the addition of 1.67% (w/v) of bentonite together with 0.33% (v/v) of glutaraldehyde (ABG bead) resulted in the highest ethanol production of 1.8%(w/v), using YPD medium containing 2% glucose. ABG bead seemed to be more resistant to phosphate ion than Ca-alginate bead. 0.33%(w/v) of phosphate was a proper concentration for the ethanol production by ABG bead. Scanning electron microscopic observation depicted that the immobilized cells on the bead surface were coated by alginate gel and that the cells in the internal bead were cross-linked with alginate matrix. When repeated-batch culture was performed with ABG bead for 40 days in a packed-bed reactor, ethanol concentration of about 90~110 g/l-gel was maintained. Cell viability was maintained around 70%, and outgrowing cell concentration was below 6.3% of total cell concentration. Consequently, the results showed that ABG head was a potential carrier for continuous production of ethanol compared to conventional Ca-alginate bead.

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Effect of Na2SiO3 concentration on PEO film formation of Al6061 alloy (Al6061 합금의 PEO 피막 형성에 미치는 Na2SiO3 농도의 영향 )

  • Byung Geon Lee;Young Uk Han;Gibum Jang;Sung Youl Cho
    • Journal of Surface Science and Engineering
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    • v.57 no.2
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    • pp.86-91
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    • 2024
  • In this study, we investigated the effect of Na2SiO3 concentration on the Plasma Electrolytic Oxidation(PEO) film formation of Al6061 alloy. The morphology of the PEO films were examined by Optical Microscope(OM) and Scanning Electron Microscope(SEM). PEO film thickness increases as the Na2SiO3 concentration increases. The elemental analysis of PEO films was conducted using Dispersive X-ray Spectrometer(EDS). The cross-sectional elemental analysis result shows that the Si concentration tends to increase as the concentration of Na2SiO3 increases. X-Ray Diffraction(XRD) analysis was performed to confirm the degree of phase change according to Na2SiO3 concentration. In addition, Vickers hardness was measured to confirm the mechanical strength of the PEO film. As the concentration of Na2SiO3 increases, the hardness value also tends to increase.

Characteristics of PCE Reductive Dechlorination using Benzoate as an Electron Donor (벤조산염을 전자공여체로 이용한 PCE의 환원성 탈염소화 특성)

  • Lee, Il-Su;Bae, Jae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.28 no.3
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    • pp.292-299
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    • 2006
  • Batch experiments were performed to evaluate the effects of the electron donor dosage and the initial biomass on the reductive dechlorination of perchloroethene(PCE) with benzoate as an electron donor. When benzoate was added less than the theoretical requirement for dechlorination(electron donor/acceptor ratio=0.5 and 1), the dechlorination efficiency increased from 71% to 94.3% with the increase in benzoate dosage, but the fraction of electron equivalent utilized for dechlorination decreased from 92.7% to 79.6%. Methane production was observed when the hydrogen concentration was higher than the threshold value(10 nM) after PCE and trichloroethene (TCE) were reduced to cis-1,2-dichloroethene(cDCE). When benzoate was added more than the theoretical requirement, the residual hydrogen converted into methane after the completion of dechlorination. The increase in the seeding biomass shortened the lag time for dechlorination, but it did not affect the maximum dechlorination rate as it was mainly governed by the benzoate fermentation rate. When the seeding biomass concentration was high, active dechlorination during the early period increased dechlorination efficiency while decreasing methane production.

Comparison of Dustiness of Eleven Nanomaterials using Voltex Shaker Method (볼텍스쉐이커를 이용한 11개 나노물질의 분진날림 비교)

  • Lee, Naroo;Park, Jinwoo
    • Journal of Korean Society of Occupational and Environmental Hygiene
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    • v.28 no.3
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    • pp.273-282
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    • 2018
  • Objectives: Dustiness of nanomaterials is considered as exposure index of essential material. Research on dustiness of nanomaterial is needed to control exposure in workplaces. Method: Dustiness measurement using vortex shaker were installed in the laboratory. Nanomaterials, 1 g, was put in the glass test tube and shaked using vortex shaker. Aerosol dispersed was measured using scanning mobility particle sizer(SMPS) and optical particle counter(OPC). Mass concentration using PVC filter and cassette was measured and TEM grid sampling was conducted. Total particle concentration and size distribution were calculated. Image and chemical composition of particles in the air were observed using transmission electron microscopy and energy dispersive X-ray spectrometer. Eleven different test nanomaterials were used in the study. Results: Rank of mass concentration and particle number concentration were coincided in most cases. Rank of nanomateirals with low concentration were not coincided. Two types of fumed silica had the highest mass concentration and particle number concentration. Indium tin oxide, a mixture of indium oxide and tin oxide, had high mass concentration and particle number concentration. Indium oxide had very low mass concentration and particle number concentration. Agglomeration of nanoparticles in the air were observed in TEM analysis and size distribution. In this study, mass concentration and particle number concentration were coincided and two index can be used together. The range of dustiness in particle number concentration were too wide to measure in one method. Conclusion: Particle number concentration ranged from low concentration to high concentration depend on type of nanomaterial, and varied by preparation and amount of nanomaterial used. Further study is needed to measure dustiness of all nanomaterial as one reference method.

Optimization of Extraction Conditions of Sarcodon aspratus by Response Surface Methodology (반응표면분석에 의한 능이버섯 추출물의 추출조건 최적화)

  • Lee, Hye-Jin;Jung, Sung-Keun;Do, Jeong-Ryong;Kim, Hyun-Ku
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.44 no.3
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    • pp.464-469
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    • 2015
  • Response surface methodology (RSM) was used to monitor extraction characteristics of extracts from Sarcodon aspratus. Based on a central composite design, independent variables were microwave power (30~150 W), ethanol concentration (0~100%), and extraction time (1~9 min). Dependent variables were yield, electron-donating ability, total phenol contents, and SOD-like activity. Coefficients of determination ($R^2$) for dependent variables ranged from 0.80 at 0.97. The maximum extraction yield was 50.28% under conditions of 125.1 W microwave power, 18.67% ethanolic concentration, and 7.06 min extraction time. The maximum extraction electron-donating ability was 22.14% under conditions of 31.09 W, 45.76%, and 4.32 min. The maximum extraction total polyphenol content was 30.54 mg tannic acid equivalent/g at 122.54 W, 48.05%, and 8.36 min. The maximum extraction SOD-like activity was 33.44% at 121.17 W, 47.42%, and 8.41 min. Based on superimposition of four dimensional RSM with respect to extraction yield, electron-donating ability, total polyphenol content, and SOD-like activity obtained under various extraction conditions, optimum ranges of extraction conditions were found to be microwave power of 78~88 W, ethanol concentration of 39~57%, and extraction time of 3.5~9 min.

Development of a Blended Corrosion, Scale and Micro-Organism Inhibitor for Open Recirculating Cooling System

  • Choi, Dong-Jin;You, Seung-Jae;Kim, Jung-Gu;Hwang, Woo-Suk
    • Corrosion Science and Technology
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    • v.4 no.3
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    • pp.89-94
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    • 2005
  • This paper presents the results of a study that was undertaken to optimize the ratio of the components of a new multi-component inhibitor blend composed of orthophosphate/ phosphonates/ acrylate copolymer/ isothiazolone. The effects of newly developed inhibitor on carbon steel dissolution in synthetic cooling water were studied through weight loss tests, electrochemical tests, scale tests, and micro-organism tests. The obtained results were compared to blank (uninhibited specimen) and showed that developed inhibitor revealed very good corrosion, scale, and micro-organism inhibition simultaneously. All measurements indicated that the efficiency of the blended mixture exceeded 90 %. The inhibitive effects arose from formation of protective films which might contain calcium phosphate, calcium phosphonate, and iron oxide. The nature of protective films formed on the carbon steel was studied by scanning electron microscopy (SEM) and auger electron spe ctroscopy (AES). Inhibitor used in this study appeared to have better performance for scale inhibition due to their superior crystal modification effect and excellent calcium carbonate scale inhibition properties. The effect of inhibitor on microorganisms was evaluated through minimum inhibitory concentration (MIC) test. All kinds of micro-organisms used in this study were inhibited under 78ppm concentration of inhibitor.