• Title/Summary/Keyword: Electrolytic treatment

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Continuous removal of phosphorus in water by physicochemical method using zero valent iron packed column (영가철 충진 컬럼을 이용한 연속적인 물리화학적 수중 인 제거)

  • Jeong, Jooyoung;Ahn, Byungmin;Kim, Jeongjoo;Park, Jooyang
    • Journal of Korean Society of Water and Wastewater
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    • v.27 no.4
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    • pp.439-444
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    • 2013
  • Excessive phosphorus in aquatic systems causes algal bloom resulting in eutrophication, DO depletion, decline in recreational value of water and foul tastes. To treat wastewater containing phosphorus including effluent of wastewater treatment plant, the continuous experiments were performed by using electrochemical way. The spherical ZVI and silica sand which act as physical filter are packed at appropriate volume ratio of 1:2. Electric potential is applied externally which can be changed as per the operational requirement. The results indicate that optimum hydraulic retention time of 36 minutes (10 mL/min at 1 L reactor) was required to meet the effluent standards. Lower concentrations of phosphorus (<10 mg/L as phosphate) were removed by precipitation by contact with iron. Thus, additional electric potential was not required. In order to remove high concentration phosphorus around 150 mg/L as phosphate, external electric potential of 600 V was applied to the reactor.

Depletion of Solid Solution Elements and Change of Carbides in Artificially Aging Heat Treated 2.25CrMo Steel (인공 경년열화 열처리된 2.25CrMo 강에서의 고용원소 고갈 및 탄화물 변화)

  • Byeon, Jal Won;Pyo, S.W.;Kwun, S.I.
    • Journal of the Korean Society for Heat Treatment
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    • v.15 no.2
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    • pp.70-75
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    • 2002
  • The depletion of solid solution elements from matrix and the change of carbides during artificial aging of 2.25CrMo steel at $630^{\circ}C$ were investigated. The Mo and Cr elements were found to be depleted drastically in the early stage of aging. The change of carbides was confirmed by analyzing the XRD patterns of electrolytically extracted carbides. Four type of carbides, $M_{23}C_6$, $M_3C$, $M_2C$ and $M_6C$, were found to exist in the specimen before aging. The amount of $M_6C$ carbides increased with aging time, while that of $M_3C$ carbides diminished after short aging time.

Evaluation on Design Factors of Electrolytic Flotation Reactor by Measuring Polarization Curve (분극곡선 측정을 통한 전해부상조의 설계인자 평가)

  • Lim, Bong-Su;Jin, Jing-Zhu;Choi, Chan-Soo
    • Journal of Korean Society on Water Environment
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    • v.23 no.2
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    • pp.244-250
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    • 2007
  • This study was carried out to obtain the optimum design factors for an eletrolytric flotation reactor. When the effluent of the leachate treatment facility was treated under the condition of 10 volts, 30 minutes, at the Al-Al electrode system; COD removal efficiency was 45%, and total phosphorus removal efficiency was 98%. The high removal efficiency was caused by the fact that phosphate was removed by leaching $Al^{3+}$ from two electrodes. The leachate containing high ammonium nitrogen concentration was treated by a batch test under the condition of 60 minutes reaction time and added chloride ion; ammonium nitrogen removal efficiency was 89%. This high efficiency was affected by added chloride ion to wastewater. To find the optimum current density and voltage of the leachate containing chloride ion (ratio of $Cl^-/NH_4-N$ is 11) a electrochemical polarization curve was used. These values were found to be $4.5mA/cm^2$ and about 2.1 V, respectively. When C-Al electrode system was used at a batch test, the total nitrogen removal efficiency was increased by 1.8 to 3.3 times, compared to Al-Al electrode system due to high $Cl_2$ gas production.

A study on treatment of emulsified oil waste water in vessels by electrochemical treatment system (전기화학적 처리장치에 의한 유화된 선저폐수의 처리에 관한 연구)

  • Kwon K. S.;Jeong H. J.;Lee B. H.
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.6 no.3
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    • pp.45-53
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    • 2003
  • Discharging untreated bilge to the ocean is a cause of marine pollution. In general, bilge water contains free and/or emulsified forms of oil. Free form of oil can easily be separated by gravimetric flotation and/or proper filtration processes. However, those simple physicochemical processes could not separate emulsified oil without adding proper chemicals. Electrolytic flotation is one of promising technologies able to fulfill the effluent standard requirement, which is below 15 ppm of oil content. In this research, Electrochemical process consisting of electrochemical flotation basin was studied for the treatment of emulsified oil. In order to estimate, the effectiveness of oil separation equipment influent concentration of oil and HRT(Hydraulic retention time) were considered. Also, lab-scale electrochemical process was designed and operated in the condition of various HRT, current density, and electrode gap. Through the research, following results were obtained. From the experiment of bench scale electrochemical treatment process, it was demonstrated that the emulsified oil was treated effectively and the removal efficiency of emulsified oil from wastewater was increased with HRT and current density.

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COMPARISON OF RETENTIVE FORCE OF REPAIR RESIN BY VARIOUS SURFACE TREATMENT METHODS IN THE REPAIR OF FRACTURED PORCELAIN FUSED TO METAL CROWN (도재소부전장관(陶材燒付前奬冠) 파절수리시(破折修理時) 표면처리(表面處理) 방법(方法)에 따른 수복(修復)레진의 유지력(維持力)에 관(關)한 연구(硏究))

  • Lim Heon-Song;Heo Seong-Joo;Cho In-Ho
    • The Journal of Korean Academy of Prosthodontics
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    • v.30 no.1
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    • pp.73-83
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    • 1992
  • Now composite resin restoration is clinically accepted in the repair of fractured PFM case, many mechanical surface treatment methods are performed to increase retentive force. The main purpose of this study was to compare the retentive force among the possible surface treatments and to insure the best method for the clinical application to the fractures porecelain and the exposed metal surface. To compare and to analyze the retentive force of repair resin, porcelain specimen were divided into 2 groups, etching group and non-etching group, and etching group were treated with 37% $H_3PO_4$, 1.23% APF, 10% HF and non-etching groups were treated with diamond bur, micro-sandblasasting. Also, metal specimens were divided by 2 groups : one was non-precious metal group which was treated with diamond bur, micro-sandblasting and tin plating and electrolytic etching, the other was precious metal group which was composed of micro-sandblasting treatment only and tin plating treatment with micro-sandblasting. Each specimen had been restored for 48 hours and the bond strength of each specimen was calculated with Universal testing machine. The results were as follows : 1. Porcelain specimen had higher bonding strength than metal specimen for the repair resin(P<0.01). 2. In porcelain specimen, 10% HF etching group had the highest bonding strength among etching and non-etching group. 3. Metal specimen treated with micro-sandblasting had highest bonding strength among the non-sandblasting had hightest bonding strength among the non-precious group, tin plating group had higher bonding strength than micro-sandblasting group between the precious metal groups. 4. Bonding strength of tin plating was increased in precious metal group only.

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THE EFFECT OF SUREACE TREATMENTS ON THE REBONDED RESIN-BONDED RETAINERS

  • Kim Sang-Pil;Kang Dong-Wan
    • The Journal of Korean Academy of Prosthodontics
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    • v.40 no.6
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    • pp.590-596
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    • 2002
  • The resin : metal interface is at the basis of most bonding failures in resin-bonded prosthesis. Although debonding has been a problem with adhesive fixed partial dentures, various dentists classify them as long-term restorations. The advantages of resin-bonded fixed partial dentures include minimal tooth reduction and the possibility of rebonding. if resin-bonded protheses can be easily rebounded, it is of clinical importance to know if the lutingagents rebond as well the second time as they did originally. Several retentive systems for resin-to-metal bonding have recommended. Treatments such as electrolytic etching and silicone coating, despite the good result of bond strength, have proved to be time-consuming and technique-sensitive. Therefore a simple and more reliable method is desirable. This study evaluated the effect of metal surface treatments on the rebond strength of panavia 21 cement to a nickel-chromium(Ni-Cr) alloy. The samples were received the following surface treatments : Group No.1 (control or served as the control) treatment with sandblasting with 50um aluminum oxide and ultrasonically cleaned for 10minutes in double-deionized water, Group No.2 were no surface treatments. Group No.3 were treated with metal primer. Group No.4 were treated with sandblasting as previously described, and then metal priming. From the analysis of the results, the following conclusions were drawn. 1. Sandblasting and metal priming appears to be an effective method for treatment of metal after accidental debonding. 2. Group without surface treatment had significantly lower bond strengths compared with other groups. 3. The combination of sandblasting and metal priming may not develop superior bonding strengths compared with other techniques that used the Ni-Cr alloys. 4. Combination of cohesive and adhesive failures were the most common type observed. The results support the use of sandblasting as a viable procedure when rebonding accidentally lost adhesive partial denture. We concluded that sandblasting and metal priming of metal surface before bonding could provide the adequate bond strength during rebonding of resin-bonded fixed partial denture.

Effect of pre-treatment in 0.5 M oxalic acid containing various NH4F concentrations on PEO Film Formation of AZ91 Mg Alloy (NH4F가 첨가된 0.5 M 옥살산 전처리가 AZ91 마그네슘 합금의 PEO 피막 형성에 미치는 영향)

  • Kwon, Duyoung;Song, Pung-Keun;Moon, Sungmo
    • Journal of the Korean institute of surface engineering
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    • v.55 no.1
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    • pp.24-31
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    • 2022
  • This study investigated the effect of pre-treatment on the PEO film formation of AZ91 Mg alloy. The pre-treatment was conducted for 10 min at room temperature in 0.5 M oxalic acid (C2H2O4) solution containing various ammonium fluoride (NH4F) concentrations. The pre-treated AZ91 Mg specimens were anodized at 100 mA/cm2 of 300 Hz AC for 2 min in 0.1 M NaOH + 0.4 M Na2SiO3 solution. When AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with NH4F concentration less than 0.3 M, continuous dissolution of the AZ91 Mg alloy occurred together with the formation of black smuts and arc initiation time for PEO film formation was very late. It was noticed that corrosion rate of the AZ91 Mg alloy became faster if small amount of NH4F concentration, 0.1 M, is added. The fast corrosion is attributable to fast formation of porous fluoride together with porous oxides in the reaction products. On the other hand, when AZ91 Mg alloy was pretreated in 0.5 M oxalic acid with sufficient NH4F more than 0.3 M, a thin and dense protective film was formed on the AZ91 Mg alloy surface which resulted in faster initiation of arcs and formation of PEO film.

Localization Development of On-Site High Sodium Hypochlorite Generation (고농도 차아염소산나트륨 발생장치 국산화 개발)

  • Kim, Jung Sik;Shin, Hyun Su;Lee, Eun Kyoung;Jung, Bong Ik
    • Transactions of the KSME C: Technology and Education
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    • v.1 no.1
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    • pp.83-90
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    • 2013
  • The purpose of this study is to replace existing liquid chlorine with localization of on-site high (12%) sodium hypochlorite generation system. On-site high (12%) sodium hypochlorite generation system is higher the current efficiency of 38.7%, 54.6% reduction of salt consumption, and 97.3% lower rate of chlorate than on-site low (0.8%) sodium hypochlorite generation system.

STATUS OF PYROPROCESSING TECHNOLOGY DEVELOPMENT IN KOREA

  • Song, Kee-Chan;Lee, Han-Soo;Hur, Jin-Mok;Kim, Jeong-Guk;Ahn, Do-Hee;Cho, Yung-Zun
    • Nuclear Engineering and Technology
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    • v.42 no.2
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    • pp.131-144
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    • 2010
  • The Korea Atomic Energy Research Institute (KAERI) has been developing pyroprocessing technology for recycling useful resources from spent fuel since 1997. The process includes pretreatment, electroreduction, electrorefining, electrowinning, and a waste salt treatment system. This paper briefly addresses unit processes and related innovative technologies. As for the electroreduction step, a stainless steel mesh basket was applied for adaption of granules of uranium oxide. This basket was designed for ready handling and transfer of feed material. A graphite cathode was used for the continuous collection of uranium dendrite in the electrorefining system. This enhances the throughput of the electrorefiner. A particular mesh type stirrer was designed to inhibit uranium spill-over at the liquid Cd crucible. A residual actinide recovery system was also tested to recover TRU tracer. In order to reduce the waste volume, a crystallization method is employed for Cs and Sr removal. Experiments on the unit processes were tested successfully, and based on the results, engineering-scale equipment has been designed for the PRIDE (PyRoprocess Integrated inactive DEmonstration facility).

A Experimental Study on Improvement of Marine Clay through the Electrolytic Leaching Effect in Aluminum Electrode (알루미늄 전극의 용출에 따른 해성점토의 개량에 관한 실험적 연구)

  • Kim, Jong-Yun;Yun, Myung-Suk;Jung, Seung-Yong;Kim, Soo-Sam
    • Proceedings of the Korean Geotechical Society Conference
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    • 2006.03a
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    • pp.1173-1180
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    • 2006
  • In this study, aluminum electrodes were put in marine clay which was taken from the south coast in Korea to increase the undrained shear strength by inducing the densification and cementation between clay particles and precipitates which were developed by electric decomposition in an electrode. To raise the cementation rate and reduce treatment time, high electric current (2.5A) was applied in each electrode at a semi-pilot scale soil box with marine clay. After the tests, the undrained shear strength was measured at designated points using a static cone penetration test device and sampling was conducted simultaneously in order to measure water content, pH and electric conductivity which would be the key for configuring the cementation effects indirectly. In the results of electric decomposition in aluminum electrode, the measured shear strength was increased considerably compared to the initial shear strength because of the cementation effect between iron ions and soil particles.

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