• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2001년도 춘계학술발표회 초록집
• /
• pp.41-41
• /
• 2001

• 한국표면공학회:학술대회논문집
• /
• 한국표면공학회 2000년도 춘계학술발표회 초록집
• /
• pp.6-6
• /
• 2000

• Korean Chemical Engineering Research
• /
• 제50권4호
• /
• pp.696-701
• /
• 2012

사용후핵연료의 안정적 관리와 재활용을 위해 건식 처리공정이 관심을 끌고 있으며 현재 국내에서도 이를 중심으로 사용후핵연료 관리를 위한 방안이 모색되고 있다. 파이로 공정으로 불리는 사용후핵연료 고온 용융염 공정 중 전해환원 공정은 후속 공정인 전해정련 공정에 금속 물질을 공급하는 역할을 한다. 이를 위해 전해환원 공정은 고온 LiCl을 매질로 사용하여 전기화학적으로 생성된 Li과의 반응으로 산화물을 금속으로 전환시킨다. 사용후핵연료에 존재하는 다양한 핵종들은 전해환원 공정의 매질인 LiCl과 반응 매질인 Li에 대한 반응성에 차이에 의해 시스템 내에 분배하게 된다. 본 연구에서는 이와 같은 시스템에서 사용후핵연료 구성 성분들의 거동을 해석하기 위해 열역학적 계산을 통해 각 원소들의 반응성을 확인하였다. 공정온도에서 우라늄 및 초우란 원소들은 금속으로 환원되는 반면 Eu를 제외한 희토류 산화물들은 안정적인 산화물로 존재하게 된다. 또한, 본 연구에서는 공정온도에 대한 반응의 경향을 판단하였으며 공정 온도에서 기준 사용후핵연료를 대상으로 전해환원 반응에 따라 분배되는 상들의 방사능 및 열부하를 계산하여 공정 자료를 제시하였다.

• Journal of Power Electronics
• /
• 제16권5호
• /
• pp.1894-1903
• /
• 2016

In general, electrolytic capacitors are used to reduce power pulsations on PV-panels. However, this can reduce the reliability of the PV AC-module system, because electrolytic capacitors have a shorter lifetime than PV-panels. In addition, PV-panels generate irregular power and inject it into the grid because the output power of a PV-panel depends on the surrounding conditions such as irradiation and temperature. To solve these problems, a grid-connected photovoltaic (PV) AC-module with active power decoupling and energy storage is proposed. A parallel bi-directional converter is connected to the AC module to reduce the output power pulsations of PV-panels. Thus, the electrolytic capacitor can be replaced with a film capacitor. In addition, the irregular output power due to the surrounding conditions can be regulated by using a parallel energy storage circuit. To maintain the discontinuous conduction mode at low irradiation, the frequency control method is adopted. The design method of the proposed converter and the operation principles are introduced. An experimental prototype rated at 125W was built to verify the performance of the proposed converter.

• 한국표면공학회지
• /
• 제41권6호
• /
• pp.308-311
• /
• 2008

Oxide layers were prepared on Al2021 alloys substrate under a hybrid voltage of AC 200 V (60 Hz) combined with DC 260 V value at room temperature within $5{\sim}60\;min$ by plasma electrolytic oxidation (PEO). An optimized aluminate-fluorosilicate solution was used as the electrolytes. The surface morphology, thickness and composition of layers on Al2021 alloys at different reaction times were studied. The results showed that it is possible to generate oxide layers of good properties on Al2021 alloys in aluminate-fluorosilicate electrolytes. Analysis show that the double-layer structure oxide layers consist of different states such as ${\alpha}-{Al_2}{O_3}$ and ${\gamma}-{Al_2}{O_3}$. For short treatment times, the formation process of oxide layers follows a linear kinetics, while for longer times the formation process slows down and becomes a steady stage. During the PEO processes, the average size of the discharge channels increased gradually as the PEO treatment time increased.

• Design & Manufacturing
• /
• 제13권3호
• /
• pp.48-52
• /
• 2019

As the consumer market in the mold, automation and aerospace industries grows, the demand for chemical machining using on electrochemical polishing increases. To enhance the surface roughness and gloss of the micro-needle, we have studied for an electrochemical polishing. Electrochemical polishing requires the chemical reaction of solution and material according to the electrolyte and electrode. In this study, sulfuric acid(30%), phosphoric acid(50%), and DI-water(20%)were used as the electrolytic solution, and the electrolytic solution temperature used $58^{\circ}C$. Electrochemical polishing was carried out in experimental conditions, and the micro-needle experiment was carried out from the basic experiment to obtain the experimental conditions. Experimental results show that as the voltage and current increase, the surface roughness improved and the gloss is improved. So, the best result for this experiment was obtained in condition 6, which improved micro-needle.

• 전력전자학회논문지
• /
• 제16권5호
• /
• pp.448-456
• /
• 2011

최근 디지털 광원으로서 각광받고 있는 고출력 LED(Light Emitting Diode)는 저소비전력과 장수명 그리고 점 소등 속도도 빨라서 고출력 LED의 효율을 향상시켜 일반 조명용으로 사용하려는 노력이 두드러지고 있다. 본 논문에서는 온도변화에 따른 전압 변동분만을 출력 콘덴서에 저장함으로서 출력 측에 사용하던 전해 콘덴서를 전압용량이 작고 수명이 긴 MLCC(Multi-Layer Ceramic Capacitor) 사용이 가능한 LED 구동 드라이브를 제안하고자 한다. 제안된 LED 구동 드라이브는 기존의 부스트 DC/DC 컨버터의 기본 토폴로지에서 출력 콘덴서를 입력 전원과 직렬로 연결하여 LED 광원의 온도변화에 따른 전압 변동분만을 출력 콘덴서에 저장함으로서 출력 콘덴서로 기존수명이 낮은 전해 콘덴서 대신 전력 손실이 적고 수명이 긴 MLCC 사용이 가능하게 된다.

• 한국재료학회지
• /
• 제22권3호
• /
• pp.155-158
• /
• 2012

In this work, AlON-$Al_2O_3$ coatings were prepared on Al2021 alloy by the electrolytic plasma processing (EPP) method. The experimental electrolytes include: 2 g/l NaOH as the electrolytic conductive agent, 10 g/l $Na_2AlO_2$ as the alumina formative agent, and 0.5 g/l $NaNO_2$, $NaNO_3$, and $NH_4NO_3$ as the nitride inducing agents. The effects of different nitrogen inducing agents were studied by a combined compositional and structural analyses of the ceramic coatings carried out by Xray diffractometry (XRD) and scanning electron microscopy (SEM) for the specimens EPP-treated at room temperature for 15 min under a hybrid voltage of 260 DC along with an AC 50 Hz power supply (200 V). Microhardness tests and wear tests were carried out to correlate the evolution of the microstructure and the resulting mechanical properties. Potentiodynamic polarizations and immersion corrosion tests were carried out in 3.5wt% NaCl water solutions under static conditions in order to evaluate the corrosion behavior of the coated samples. The results demonstrate that $NaNO_2$ is proven to be a good nitrogen inducing agent to produce high quality AlON-$Al_2O_3$ ceramic coatings.

• Journal of Welding and Joining
• /
• 제32권3호
• /
• pp.27-33
• /
• 2014

This paper presents a brief summary on a relatively new plasma aided electrolytic surface treatment process for light metals. A brief discussion regarding the advantages, principle, process parameters and applications of this process is discussed. The process owes its origin to Sluginov who discovered an arc discharge phenomenon in electrolysis in 1880. A similar process was studied and developed by Markov and coworkers in 1970s who successfully deposited an oxide film on aluminium. Several investigation thereafter lead to the establishment of suitable process parameters for deposition of a crystalline oxide film of more than $100{\mu}m$ thickness on the surface of light metals such as aluminium, titanium and magnesium. This process nowadays goes by several names such as plasma electrolytic oxidation (PEO), micro-arc oxidation (MOA), anodic spark deposition (ASD) etc. Several startups and surface treatment companies have taken up the process and deployed it successfully in a range of products, from military grade rifles to common off road sprockets. However, there are certain limitations to this technology such as the formation of an outer porous oxide layer, especially in case of magnesium which displays a Piling Bedworth ratio of less than one and thus an inherent non protective oxide. This can be treated further but adds to the cost of the process. Overall, it can be said the PEO process offers a better solution than the conventional coating processes. It offers advantages considering the fact that he electrolyte used in PEO process is environmental friendly and the temperature control is not as strict as in case of other surface treatment processes.

• 대한화학회지
• /
• 제13권2호
• /
• pp.165-169
• /
• 1969

On the electrolytic preparation of sodium chlorate, lead dioxide anode, instead of graphite was tested to find out the characteristics for current efficiency and life in various conditions. The results obtained are summerized as follows; 1. The current efficiency is slightly increased with the anode current density, until 25A/$dm^2$ 2. The higher the current concentrations. the lower current efficiencies are observed, particularly in case of both not-adding the potassium dichromate and large current concentration of more than 50A/l 3. The current efficiency may be improved linearly as the both temperature is raised.