• 제목/요약/키워드: Electrolytic process

검색결과 320건 처리시간 0.024초

산화전리수를 이용한 질소와 황 계열 악취 및 악취전구물질의 제거 (Removal of nitrogen and sulfur odorous compounds and their precursors using an electrolytic oxidation process)

  • 신승규;안해영;김한승;송지현
    • 상하수도학회지
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    • 제25권2호
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    • pp.223-230
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    • 2011
  • An electrolytic oxidation process was applied to remove odorous compounds from non-point odor sources including wastewater pipelines and manholes. In this study, a distance between the anode and the cathode of the electrolytic process was varied as a system operating parameters, and its effects on odor removal efficiencies and reaction characteristics were investigated. Odor precursors such as sediment organic matters and reduced sulfur/nitrogen compounds were effectively oxidized in the electrolytic process, and a change in oxidation-reduction potential (ORP) indicated that an stringent anaerobic condition shifted to a mild anoxic condition rapidly. At an electrode distance of 1 cm and an applied voltage of 30 V, a system current was maintained at 1 A, and the current density was 23.1 $mA/cm^{2}$. Under the condition, the removal efficiency of hydrogen sulfide in gas phase was found to be 100%, and 93% of ammonium ion was removed from the liquid phase during the 120 minute operating period. Moreover, the sulfate ion (${SO_4}^{2-}$) concentration increased about three times from its initial value due to the active oxidation. As the specific power consumption (i.e., the energy input normalized by the effective volume) increased, the oxidation progressed rapidly, however, the oxidation rate was varied depending on target compounds. Consequently, a threshold power consumption for each odorous compound needs to be experimentally determined for an effective application of the electrolytic oxidation.

은 함유 폐수의 연속 순환 전해처리 시 유량변화가 회수 공정에 미치는 영향 (Effect of Flow Rate on the Continuous Cycling Electrolytic Treatment Process for Silver Ion Containing Wastewater)

  • 정원주;김동수
    • 한국물환경학회지
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    • 제23권5호
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    • pp.577-580
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    • 2007
  • The influence of flow rate has been investigated on the treatment efficiency of continuous cycling electrolytic process employing artificial and actual photographic wastewater which containing silver ion. For artificial wastewater, the treatment efficiency of process was found to rise ca. three times when the flow rate of wastewater was increased from 3 mL/min to 15 mL/min. The process efficiency was doubled under the same condition regarding actual wastewater. The effect of flow rate on the treatment efficiency was observed to be altered according to the metal ionic form and solution composition. The coefficient of mass transfer was estimated using model equation, which verified that the raised treatment efficiency at higher flow rate was due to the increased mobility of ionic species.

DSA 전극을 사용한 에멀젼 함유폐수의 전해처리 (I) -회분식 전해처리- (Electrolytic Treatment of Emulsified Oily Wastewater Using DSA Electrode (I) - Batch Treatment -)

  • 김인수;송영채
    • 해양환경안전학회지
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    • 제2권1호
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    • pp.67-75
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    • 1996
  • An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

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Influence of Electrolytic KF on the Uniform Thickness of Oxide Layers Formed on AZ91 Mg Alloy by Plasma Electrolytic Oxidation

  • Song, Duck-Hyun;Lim, Dae-Young;Fedorov, Vladimir;Song, Jeong-Hwan
    • 한국재료학회지
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    • 제27권9호
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    • pp.495-500
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    • 2017
  • Oxide layers were formed by an environmentally friendly plasma electrolytic oxidation (PEO) process on AZ91 Mg alloy. PEO treatment also resulted in strong adhesion between the oxide layer and the substrate. The influence of the KF electrolytic solution and the structure, composition, microstructure, and micro-hardness properties of the oxide layer were investigated. It was found that the addition of KF instead of KOH to the $Na_2SiO_3$ electrolytic solution increased the electrical conductivity. The oxide layers were mainly composed of MgO and $Mg_2SiO_4$ phases. The oxide layers exhibited solidification particles and pancake-shaped oxide melting. The pore size and surface roughness of the oxide layer decreased considerably with an increase in the concentration of KF, while densification of the oxide layers increased. It is shown that the addition of KF to the basis electrolyte resulted in fabricating of an oxide layer with higher surface hardness and smoother surface roughness on Mg alloys by the PEO process. The uniform thickness of the oxide layer formed on the Mg alloy substrates was largely determined by the electrolytic solution with KF, which suggests that the composition of the electrolytic solution is one of the key factors controlling the uniform thickness of the oxide layer.

전해 인프로세스 드레싱 연삭에서 AE를 이용한 가공안정성 감시에 관한 연구 (A Study on the Monitoring of Grinding Stability Using AE Sensor in Electrolytic In-Process Dressing Grinding)

  • 김태완;이종렬;이득우;송지복;최대봉
    • 대한기계학회논문집A
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    • 제23권6호
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    • pp.1011-1017
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    • 1999
  • Electrolytic in-process dressing grinding technique which enables application of metal bond wheels with fine superabrasives in mirror surface grinding operations has developed. It is possible to make efficient precision machining of hard and brittle material such as ceramic and hard metal by the employment of this technique. However, in order to ensure the success of performances such as efficient machining, surface finish, and surface quality, it is important to sustain the insulating layer that has sharply exposed abrasives in wheel surface. Using AE(Acoustic Emission) sensor, this paper will show whether the insulating layer sustains stably or not in real grinding time. And by comparing AErms value and surface roughness their thresholds for stable electrolytic in-process dressing grinding will be determined.

전해 드레싱을 이용한 고품의 내면 연삭 가공에 관한연구 (A Study on the Internal Grinding with High Quality Using Interval Type Electrolytic Dressing Method)

  • 강재훈
    • 한국생산제조학회지
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    • 제9권2호
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    • pp.138-143
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    • 2000
  • The establishment of a practical ultra-precision grinding technique using Diamond and CBN wheels is one of the major key technolo-gies to improve production techniques for machine-to-difficult materials without finishing process such as lapping and polishing. But the special efficient dressing technique for ultra-fine grit type grinding wheels to stabilize the grinding ability was not developed. Recently electrolytic in-process dressing technique is proposed to ultra-fine grit type metal bonded diamond wheels to protrude abra-sives continuously from the tool surface. This technology can be widely used to surface grinding and cylindrical grinding but cannot be used efficiently to internal grinding because of the electrode attachment trouble. This paper describes the effect of interval type electrolytic dressing as proposed newly to cast iron bonded diamond wheel for efficient internal grinding with mirror type high quality ground surface.

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최적 연속 전해드레싱을 적용한 SUS304의 연삭에 관한 연구 (A Study on the the Grindig of SUS304 with Optimum In-Process Electrolytic Dressing)

  • 김정두
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1997년도 추계학술대회 논문집
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    • pp.25-30
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    • 1997
  • In recent years, grinding techniques for precision machining of astainless steel used in shaft, screw parts and clear value have been improved by using superabrasive wheel and precision grinding machine. The completion of optimum dressing of superabrasive wheel makes possible the effective percision grinding of stainless steel. However, the present dressing system cannot have control of optimum dressing of the superabrabive wheel. In this study, a new system and the grinding mechanism of optimum in-process electrolytic dressing were proposed. This system can carry out optimum in-process dressing of superabrasive wheel. Therefore, the optimum in-process electrolytic dressing is a good method to obtain the efficiency and mirror-like grinding of stainless steel(SUS304).

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최적 연속 전해드레싱에 의한 연삭기구의 규명 및 시스템 개발에 관한연구 (A Study on the Analysis of Grinding Mechanism and Development of Dressig System by using Optimum In-process Electrolytic Dressing)

  • 이은상
    • 한국공작기계학회:학술대회논문집
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    • 한국공작기계학회 1997년도 춘계학술대회 논문집
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    • pp.96-101
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    • 1997
  • In recent years, grinding techniques for precision machining of brittle materials used in electric, optical and magnetic parts have been improved by using superabrasive wheel and precision grinding machine. The present dressing system cannot have controll of optimum dressing of the superabrasive wheel. In this study, a new system and the grinding mechanism of optimum in-process electrolytic dressing were proposed. This system can carry out optimum in-process dressing of superabrasive wheel, and give very effective control according to unstable current and gap increase. Therefore, the optimum in-process electrolytic dressing is a good method to obtain the efficiency and mirror-like grinding of brittle materials.

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