• Title/Summary/Keyword: Electrolytic corrosion

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On-site Investigation of the Stray Current Condition in DC-Powered Subway System (지하철 직류 급전시스템의 표유전류 실태조사)

  • Ha, Yoon-Cheol;Bae, Jeong-Hyo;Ha, Tae-Hyun;Lee, Hyun-Goo;Kim, Dae-Kyeong
    • Proceedings of the KIEE Conference
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    • 2003.11a
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    • pp.373-375
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    • 2003
  • The subway, a typical electrified transit, is operated by the 1500 V DC-powered system with the overhead positive feeder and the rails negative return. This return path would bring about considerable stray current circuits, that is, from the bottom of rails to sell and then to the station ground, unless the rail-to-soil resistance is sufficiently high. The stray current can cause electrolytic corrosion of subway metallic structures and adjacent underground utilities. In this paper, we reports on-site investigation of the stray current condition, especially influenced by drainage method. The drainage method including both forced drainage and polarized drainage, extensively adopted as a countermeasure for electrolytic corrosion of underground pipelines, was found out to exert a harmful influence upon rail components as well as the pipelines.

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Effects of Na3PO4 Concentration on the Porosity of Plasma Electrolytic Oxidation Coatings Surface on the 6061 Al Alloy, and Subsequent-NaAlO2 Sealing (6061 알루미늄 합금의 플라즈마 전해산화 피막의 표면기공율 및 부식특성에 미치는 Na3PO4 농도 및 NaAlO2 봉공처리의 영향)

  • Song, Euiseok;Kim, Yong-Tae;Choi, Jinsub
    • Journal of the Korean institute of surface engineering
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    • v.52 no.3
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    • pp.117-122
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    • 2019
  • In this study, surface porosity and corrosion resistance of PEO coatings prepared on the 6061 Al alloy were investigated in terms of sodium phosphate ($Na_3PO_4$) concentrations in an alkaline solution and $NaAlO_2$ sealing. The surface morphologies of the PEO coatings clearly show that the coatings film formed in $9g\;L^{-1}$ had the lowest porosity. The $NaAlO_2$ sealing was found to remove micropores and cracks existing on the surface of PEO coatings. As a result, the $NaAlO_2$ sealing resulted in the movement of corrosion potential toward more positive value and lower corrosion current density.

Electrochemical Behavior of Plasma Electrolytic Oxidized Films Formed in Solution Containing Mn, Mg and Si Ions

  • Lim, Sang-Gyu;Choe, Han Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.80-80
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    • 2017
  • Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electro-chemical oxidation is a novel method to form ceramic coatings on light metals such as tita-nium and its alloys. This is an excellent re-producibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magne-sium (Mg) have a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth, and development. Mn influences regulation of bone remodeling be-cause its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Pre-studies have shown that Mg plays very im-portant roles in essential for normal growth and metabolism of skeletal tissue in verte-brates and can be detected as minor constitu-ents in teeth and bone. In this study, Electrochemical behavior of plasma electrolytic oxidized films formed in solution containing Mn, Mg and Si ions were researched using various experimental in-struments. A series of Si-Mn-Mg coatings are produced on Ti dental implant using PEO, with the substitution degree, respectively, at 5 and 10%. The potentiodynamic polarization and AC impedance tests for corrosion behav-iors were carried out in 0.9% NaCl solution at similar body temperature using a potentiostat with a scan rate of 1.67mV/s and potential range from -1500mV to + 2000mV. Also, AC impedance was performed at frequencies anging from 10MHz to 100kHz for corrosion resistance.

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Analysis on IBEM for consideration on reinforced concrete slab resistance

  • Kyung, Je-Woon;Tae, Sung-Ho;Lee, Han-Seung;Lee, Sung-Bok
    • Computers and Concrete
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    • v.5 no.6
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    • pp.545-558
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    • 2008
  • The corrosion of RC structures demonstrates very complicated forms of deterioration intermingled together but all pointing to a decrease in the durability of RC structures due to the corrosion of reinforcing bars. Until now, nondestructive techniques, such as half-cell potential and polarization resistance, have been widely available in the world. The former provides information on the probability of corrosion while the latter is associated with information concerning corrosion rates. Inversion by the boundary element method (IBEM) was developed for considering concrete resistivity. The applicability of the procedure was examined through a numerical analysis and electrolytic tests for RC slabs. A distribution in such concrete resistivity is relatively inhomogeneous including cracks on the surface of slabs. Regarding cracks in concrete, the relative coefficient of concrete resistance was introduced to perform its analysis. Further, the procedure will be developed to identify the corroded region visually using 3-D VRML.

Effect of Electrolyte Composition on Corrosion Behavior of PEO Treated AZ91 Mg Alloy

  • Park, Kyeong Jin;Lee, Jae Ho
    • Corrosion Science and Technology
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    • v.8 no.6
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    • pp.227-231
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    • 2009
  • Mg and Mg alloys have been used for lots of applications, including automobile industry, aerospace, mobile phone and computer parts owing to low density. However, Mg and Mg alloys have a restricted application because of poor corrosion properties. Thus, improved surface treatments are required to produce protective films that protect the substrate from corrosive environments. Environmental friendly Plasma Electrolytic Oxidation (PEO) has been widely investigated on magnesium alloys. PEO process combines electrochemical oxidation with plasma treatment in the aqueous solution. In this study, AZ91 Mg alloys were treated by PEO process in controlling the current with PC condition and treated time, concentration of NaF, NaOH, and $Na_2SiO_3$. The surface morphology and phase composition were analyzed using SEM, EDS and XRD. The potentiodynamic polarization tests were carried out for the analysis of corrosion properties of specimen. Additionally, salt spray tests were carried out to examine and compare the corrosion properties of the PEO treated Mg alloys.

Characteristics of the AlON-Al2O3 Ceramic Coatings on the Al2021 Alloy by Electrolytic Plasma Processing

  • Wang, Kai;Byeon, Sang-Sik;Kim, Geun-Woo;Park, Keun-Young;Ahmed, Faheem;Koo, Bon-Heun
    • Korean Journal of Materials Research
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    • v.22 no.3
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    • pp.155-158
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    • 2012
  • In this work, AlON-$Al_2O_3$ coatings were prepared on Al2021 alloy by the electrolytic plasma processing (EPP) method. The experimental electrolytes include: 2 g/l NaOH as the electrolytic conductive agent, 10 g/l $Na_2AlO_2$ as the alumina formative agent, and 0.5 g/l $NaNO_2$, $NaNO_3$, and $NH_4NO_3$ as the nitride inducing agents. The effects of different nitrogen inducing agents were studied by a combined compositional and structural analyses of the ceramic coatings carried out by Xray diffractometry (XRD) and scanning electron microscopy (SEM) for the specimens EPP-treated at room temperature for 15 min under a hybrid voltage of 260 DC along with an AC 50 Hz power supply (200 V). Microhardness tests and wear tests were carried out to correlate the evolution of the microstructure and the resulting mechanical properties. Potentiodynamic polarizations and immersion corrosion tests were carried out in 3.5wt% NaCl water solutions under static conditions in order to evaluate the corrosion behavior of the coated samples. The results demonstrate that $NaNO_2$ is proven to be a good nitrogen inducing agent to produce high quality AlON-$Al_2O_3$ ceramic coatings.

Characteristics of Plasma Electrolytic Oxidation Coatings on Mg-Zn-Y Alloys Prepared by Gas Atomization (가스 분사법으로 제조한 Mg-Zn-Y 합금의 플라즈마 전해 산화 피막 특성에 관한 연구)

  • Chang, Si-Young;Cho, Han-Gyoung;Lee, Du-Hyung;Kim, Taek-Soo
    • Journal of Powder Materials
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    • v.14 no.6
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    • pp.372-379
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    • 2007
  • The microstructure, mechanical and electrochemical properties of plasma electrolytic coatings (PEO) coatings on Mg-4.3 wt%Zn-1.0 wt%Y and Mg-1.0 wt%Zn-2.0 wt%Y alloys prepared by gas atomization, followed by compaction at 320 for 10 min under the pressure of 700 MPa and sintering at 380 and 420 respectively for 24 h, were investigated, which was compared with the cast Mg-1.0 wt%Zn alloy. All coatings consisting of MgO and $Mg_2SiO_4$ oxides showed porous and coarse surface features with some volcano top-like pores distributed disorderly and cracks between pores. In particular, the surface of coatings on Mg-1.0 wt%Zn-2.0 wt%Y alloy showed smaller area of pores and cracks compared to the Mg-4.3 wt%Zn-1.0 wt%Y and Mg-1.0 wt%Zn alloys. The cross section micro-hardness of coatings on the gas atomized Mg-Zn-Y alloys was higher than that on the cast Mg-1.0 wt%Zn alloy. Additionally, the coated Mg-1.0 wt%Zn-2.0 wt%Y alloy exhibited the best corrosion resistance in 3.5%NaCl solution. It could be concluded that the addition of Y has a beneficial effect on the formation of protective and hard coatings on Mg alloys by plasma electrolytic oxidation treatment.

The Specific Resistance Analysis and Measurement of the Ground at the site of the Anode Laying for the Electrolytic Protection for the Electrical Anticorrosive (전기방식용 양극 매설부지 대지 비저항 측정 및 분석)

  • Hong, Sung-Taek;Shin, Gang-Wook;Lee, Dong-Keun;Lee, Eun-Chun
    • Proceedings of the KIEE Conference
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    • 2005.07e
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    • pp.115-117
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    • 2005
  • The electrolytic protection is classified according to the current supplied. And there are the Sacrificial Anode System, the Impressed Current System, the Polarized Drainage System, the Forced Drainage System. This study is intended to design and analyze the electrolytic protection at water transmission pipes which is occurred the corrosion, and to show the methods protecting corrosions at water transmission pipes.

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The study on the ground wire size (접지선 굵기에 관한 연구)

  • 최홍규;최병숙;송영주
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2003.11a
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    • pp.97-102
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    • 2003
  • Ground in must choose enough sectional area of conductor endurably in maximum fault current, fault duration time, maximum allowable temperature and have strong durability and life-time can bear enough from spontaneous corrosion or electrolytic corrosion and must choose material that problem does not exist electrically and mechanically when connection or junction. In this paper, modeled new ground wire size numerical formula, and examine and compare of modeled numerical formula and abroad regulation, and proved and analyzed validity of the new ground wire size computation method because do simulation to computer program.

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