• Title/Summary/Keyword: Electrolytic

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Continuous Removal of Nitrate and Coliform using Bipolar ZVI Packed Bed Electrolytic Cell (영가철 충진 복극전해조를 이용한 질산성질소 및 대장균의 연속식 제거)

  • Jeong, Joo-Young;Park, Jeong-Ho;Choi, Won-Ho;Park, Joo-Yang
    • Journal of Korean Society of Water and Wastewater
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    • v.25 no.5
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    • pp.651-658
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    • 2011
  • Nitrate is a common contaminant in industrial wastewater and ground water. The maximum contaminant level set by EPA for nitrate of 10 mg/L as N. In this study, nitrate was removed using bipolar ZVI packed bed electrolytic cell that maximized the contact area between each electrode and contaminants under 600 V. Also this study investigates the simultaneously deals with removal of ammonia by operating air stripping tower. In addition to the air stripping also helped to precipitate iron ions to the form of iron oxides. Bipolar ZVI packed bed electrolytic cell was also effective in removing coliform by electrical power. In the continuous experiments for the simulated wastewater (initial nitrate for 25 mg/L as N), maximum 96.3% removal of nitrate was achieved in the applied 600 V at the flow rate of 6 mL/min.

Research on Assessment of Potential Interference between Individual Grounding Electrodes Using an Electrolytic Tank Modeling Method

  • Gil, Hyoung-Jun;Kim, Dong-Ook;Choi, Chung-Seog
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.22 no.3
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    • pp.27-33
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    • 2008
  • This paper deals with the assessment of potential interference between individual grounding electrodes using an Electrolytic Tank Modeling method. When a test current was passed through a grounding electrode, potential rise was measured and analyzed using an electrolytic tank in real time. In order to analyze the potential interference between grounding electrodes, a reduced scale modeling method was studied. Potential interference between isolated grounding electrodes was evaluated as a function of the separation distance between grounding electrodes and the configuration of grounding electrode to be induced. It was found that the separation distance between grounding electrodes was a major factor in reducing the potential interference.

The Comparison Analysis of Field Test Cases on Technical Specifications of Electrolytic Corrosion in Urban Railway (국내 도시철도 전식방지 기술기준에 따른 시험사례 비교분석)

  • Kim, Jae-Moon;Jung, Ho-Sung;Kim, Yang-Su
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.59 no.3
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    • pp.305-310
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    • 2010
  • DC electricity feeder system operating in the urban railway is typically a feedback circuit consisted of the contact wire and electric railway vehicle via rail. But stray current is flowed on a structure that is not part of the intended electrical circuit with respect to a given structure. This paper presents comparison analysis of field test cases based on criteria of electrolytic corrosion protection of buried metallic structures adjacent to DC traction systems. As a result of it, we confirmed that measurement methods are different from each other about the same tests. Therefore measurement methods to prevent electrolytic corrosion need to establish electrical facilities standards to be applied domestic.

Third Harmonic Injection Circuit to Eliminate Electrolytic Capacitors in Light-Emitting Diode Drivers

  • Yoo, Jin-Wan;Jung, Kwang-Hyun;Jeon, In-Ung;Park, Chong-Yeun
    • Journal of Electrical Engineering and Technology
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    • v.7 no.3
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    • pp.358-365
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    • 2012
  • A new third harmonic injection circuit for light-emitting diode (LED) drivers is proposed to eliminate electrolytic capacitors and thereby extend the lifetime of LED drivers. When a third harmonic current is injected to the input current of the LED driver, the required capacitance of the driver can be reduced. The proposed circuit can control an injection ratio and has simple circuitry. The synchronous third harmonic is generated by a phase locked loop (PLL), a 1/3 counter, and op-amps and applied to a power factor correction circuit. Thus, the storage capacitor can install film capacitors instead of the electrolytic capacitor. The value of storage capacitance can be reduced to 78% compared to an input power factor of 100%. The proposed circuit is applied to the 80W prototype LED driver to experimentally verify the performances.

Failure Prediction Monitoring of DC Electrolytic Capacitors in Half-bridge Boost Converter (단상 하프-브리지 부스트 컨버터에서 DC 전해 커패시터의 고장예측 모니터링)

  • Seo, Jang-Soo;Shon, Jin-Geun;Jeon, Hee-Jong
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.63 no.4
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    • pp.345-350
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    • 2014
  • DC electrolytic capacitor is widely used in the power converter including PWM inverter, switching power supply and PFC Boost converter system because of its large capacitance, small size and low cost. In this paper, basic characteristics of DC electrolytic capacitor vs. frequency is presented and the real-time estimation scheme of ESR and capacitance based on the bandpass filtering is adopted to the single phase boost converter of uninterruptible power supply to diagnose its split dc-link capacitors. The feasibility of this real-time failure prediction monitoring system is verified by the computer simulation of the 5[kW] singe phase PFC half-bridge boost converter.

Preparation of Conduction Polymer for Solid Type Aluminum Electrolytic Capacitor (알미늄 고체 전해 커패시터용 도전성 고분자막의 제조)

  • 양성현;유광균;이기서
    • The Transactions of the Korean Institute of Electrical Engineers
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    • v.43 no.3
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    • pp.528-531
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    • 1994
  • Digitalization in electronic system is required the capacitor which have a large capacitance with small size, low impedance at high frequency, and high reliability. The fabrication and its properties of aluminum solid electrolytic capacitor are investigated. Employing conduction polymer film such as, polypyrrole as solid electroylte, solid type aluminum electrolytic capacitors were made. The surface of insulationg oxide is covered with conducting polymer layer prepared by chemical oxidative polymerization. Thereafter this conducting layer is covered with conducting polymer prepared by electrochemical polymerization. The dielectric properties of these capacitors were also measured and discussed. Regarding on frequency characteristics of the trial made capacitor, impedance and ESR at high frequency is lower than those of the stacked type film capacitor. It is alo confirmed that temperature coefficient of capacitance and dissipation factor of the capacitor are lower than those of film capacitor and liquid type aluminum electrolytic capacitor.

MOLTEN SALT VAPORIZATION DURING ELECTROLYTIC REDUCTION

  • Hur, Jin-Mok;Jeong, Sang-Moon;Lee, Han-Soo
    • Nuclear Engineering and Technology
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    • v.42 no.1
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    • pp.73-78
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    • 2010
  • The suppression of molten salt vaporization is one of the key technical issues in the electrolytic reduction process developed for recycling spent nuclear fuel from light-water reactors Since the Hertz-Langmuir relation previously applied to molten salt vaporization is valid only for vaporization into a vacuum, a diffusion model was derived to quantitatively assess the vaporization of LiCl, $Li_2O$ and Li from an electrolytic reducer operating under atmospheric pressure. Vaporization rates as a function of operation variables were calculated and shown to be in reasonable agreement with the experimental data obtained from thermogravimetry.

Microstructure analysis of 8 ㎛ electrolytic Cu foil in plane view using EBSD and TEM

  • Myeongjin Kim;Hyun Soon Park
    • Applied Microscopy
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    • v.52
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    • pp.2.1-2.6
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    • 2022
  • With the lightening of the mobile devices, thinning of electrolytic copper foil, which is mainly used as an anode collection of lithium secondary batteries, is needed. As the copper foil becomes ultrathin, mechanical properties such as deterioration of elongation rate and tear phenomenon are occurring, which is closely related to microstructure. However, there is a problem that it is not easy to prepare and observe specimens in the analysis of the microstructure of ultrathin copper foil. In this study, electron backscatter diffraction (EBSD) specimens were fabricated using only mechanical polishing to analyze the microstructure of 8 ㎛ thick electrolytic copper foil in plane view. In addition, EBSD maps and transmission electron microscopy (TEM) images were compared and analyzed to find the optimal cleanup technique for properly correcting errors in EBSD maps.

Study on Governing Equations for Modeling Electrolytic Reduction Cell (전해환원 셀 모델링을 위한 지배 방정식 연구)

  • Kim, Ki-Sub;Park, Byung Heung
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.12 no.3
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    • pp.245-251
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    • 2014
  • Pyroprocess for treating spent nuclear fuels has been developed based on electrochemical principles. Process simulation is one of the important methods for process development and experimental data analysis and it is also a necessary approach for pyroprocessing. To date, process simulation of pyroprocessing has been focused on electrorefining and there have been not so many investigations on electrolytic reduction. Electrolytic reduction, unlike electrorefining, includes specific features of gas evolution and porous electrode and, thus, different equations should be considered for developing a model for the process. This study summarized required concepts and equations for electrolytic reduction model development from thermodynamic, mass transport, and reaction kinetics theories which are necessitated for analyzing an electrochemical cell. An electrolytic reduction cell was divided and equations for each section were listed and, then, boundary conditions for connecting the sections were indicated. It is expected that those equations would be used as a basis to develop a simulation model for the future and applied to determine parameters associated with experimental data.

Application of Phase-Field Theory to Model Uranium Oxide Reduction Behavior in Electrolytic Reduction Process (전해환원 공정의 우라늄 산화물 환원 거동 모사를 위한 Phase-Field 이론 적용)

  • Park, Byung Heung;Jeong, Sang Mun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.16 no.3
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    • pp.291-299
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    • 2018
  • Under a pyro-processing concept, an electrolytic reduction process has been developed to reduce uranium oxide in molten salt by electrochemical means as a part of spent fuel treatment process development. Accordingly, a model based on electrochemical theory is required to design a reactor for the electrolytic reduction process. In this study, a 1D model based on the phase-field theory, which explains phase separation behaviors was developed to simulate electrolytic reduction of uranium oxide. By adopting parameters for diffusion of oxygen elements in a pellet and electrochemical reaction rate at the surface of the pellet, the model described the behavior of inward reduction well and revealed that the current depends on the internal diffusion of the oxygen element. The model for the electrolytic reduction is expected to be used to determine the optimum conditions for large scale reactor design. It is also expected that the model will be applied to simulate the integration of pyro-processing.