• Title/Summary/Keyword: Electrolytic

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A Study on the Electrolytic Reduction Mechanism of Uranium Oxide in a LiCl-Li$_2$O Molten Salt (LiCl-Li$_2$O 용융염계에서 우라늄 산화물의 전기화학적 금속전환 반응 메카니즘에 관한 연구)

  • 오승철;허진목;서중석;박성원
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.1 no.1
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    • pp.25-39
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    • 2003
  • This study proposed a new electrolytic reduction technology that is based on the integration of simultaneous uranium oxide metallization and Li$_2$O electrowinning. In this electrolytic reduction reaction, electrolytically reduced Li deposits on cathode and simultaneously reacts with uranium oxides to produce uranium metal showing more than 99% conversion. For the verification of process feasibility, the experiments to obtain basic data on the metallization of uranium oxide, investigation of reaction mechanism, the characteristics of closed recycle of Li$_2$O and mass transfer were carried out. This evolutionary electrolytic reduction technology would give benefits over the conventional Li-reduction process improving economic viability such as: avoidance of handling of chemically active Li-LiCl molten salt increase of metallization yield, and simplification of process.

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Analysis of Oxide Coatings Formed on Al1050 Alloy by Plasma Electrolytic Oxidation (Al1050 합금에 Plasma Electrolytic Oxidation으로 형성된 산화피막 분석)

  • Kim, Bae-Yeon;Lee, Deuk-Yong;Kim, Yong-Nam;Jeon, Min-Seok;You, Whan-Sik;Kim, Kwang-Youp
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.295-300
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    • 2009
  • The crystal structure of surface coatings on Al1050 alloy by PEO (Plasma Electrolytic Oxidation), were investigated. The electrolyte for PEO was Na-Si-P system solution. The main crystalline phase were $\gamma$-alumina and $\alpha$-alumina. Crystallinity was increased with applied voltage and applied time. The dominant crystalline phase were affected not only chemical composition of Al alloy substrate and electrolyte, but also the +/- ratio of applied voltage.

Study on the Antibacterial Properties of Electrochemically Synthesized Silver Nanocolloid (전기분해에 의한 은 나노 콜로이드 합성에 따른 항균 특성 연구)

  • Lee, Jae-Yong
    • Journal of Environmental Science International
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    • v.27 no.1
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    • pp.47-53
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    • 2018
  • In this study, high-purity silver nanocolloids were synthesized by an electrolytic reaction, and the effect of temperature on the nanocolloid concentration was analyzed by performing the reaction at $70^{\circ}C$ and $90^{\circ}C$. The antibacterial properties of the thus-synthesized silver nanocolloids were also studied. When the synthesis was performed at $90^{\circ}C$, the concentration of silver nanocolloid increased to 14 mg/L after 5 min, 1756 mg/L after 30 min, and 2147 mg/L after 60 min. The concentration of silver nanocolloid synthesized by electrolytic reaction at $70^{\circ}C$ and $90^{\circ}C$ for 60 min was 1,882 mg/L and 2147 mg/L, respectively. The preferred temperature at which the electrolytic synthesis is performed is $70^{\circ}C$ to obtain high concentrations of 1,000 mg/L or more. The antibacterial performance of the thus-synthesized silver nanocolloids was 99.9% for E. coli and 99.5% for Pseudomonas aeruginosa.

A Study on the the Grindig of SUS304 with Optimum In-Process Electrolytic Dressing (최적 연속 전해드레싱을 적용한 SUS304의 연삭에 관한 연구)

  • 김정두
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1997.10a
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    • pp.25-30
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    • 1997
  • In recent years, grinding techniques for precision machining of astainless steel used in shaft, screw parts and clear value have been improved by using superabrasive wheel and precision grinding machine. The completion of optimum dressing of superabrasive wheel makes possible the effective percision grinding of stainless steel. However, the present dressing system cannot have control of optimum dressing of the superabrabive wheel. In this study, a new system and the grinding mechanism of optimum in-process electrolytic dressing were proposed. This system can carry out optimum in-process dressing of superabrasive wheel. Therefore, the optimum in-process electrolytic dressing is a good method to obtain the efficiency and mirror-like grinding of stainless steel(SUS304).

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An Experimental Study on Accelerated Life Testing for Aluminum Electrolytic Capacitors (알루미늄전해콘덴서의 가속수명시험에 관한 실험연구)

  • Kim, Heung-Jin;Cheon, Ho-Sung;Kim, Seong-Deuk;Park, Young-Taek;Jin, Hong-Gee;Park, Chan-Woong
    • Journal of Korean Society for Quality Management
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    • v.23 no.4
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    • pp.128-147
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    • 1995
  • An accelerated life testing(ALT) for aluminum electrolytic capacitors is conducted and analyzed. A testing equipment, which consists of part fixtures, relay board, controller, video bridge and microcomputer, is made for the ALT. Load factors are temperature with four levels and voltage with three levels. Base on 'optimized 4:2:1 plan', 2,000 electrolytic capacitors are allocated at 12 experimental conditions(; 4 levels of temperature ${\times}3$ levels of voltage), and the ALT is conducted. From the experimental results, an acceleration model is derived and acceleration factors are estimated. A discussion on the experimental results is included.

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A Study on the Micro Tool Fabrication Technology employing ELID(Electrolytic In-process Dressing) Technique (전해 연속 드레싱을 이용한 마이크로 공구 제작 기술)

  • 최재영;이현우;최헌종;이석우;정해도
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2002.05a
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    • pp.508-511
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    • 2002
  • With increasing the needs for micro and precision parts, micro machining technology using micro tools has been studied to fabricate a small part with high density such as electronics, optics, communications, and medicine industry more than before. Though these micro tools have developed rapidly, it is difficult to apply them to micro fabrication technologies, because of the inherent manufacturing. In this study, micro tools(wc) to produce micro structures and parts were manufactured by cylindrical grinding machine employing ELID(Electrolytic In-process Dressing) technique and good dimensional accuracy was achieved. Furthermore we researched the characteristics of machining on the micro drilling using micro drills and manufactured micro tools. Finally it is confirmed that manufactured micro tools can be used for micro machining.

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Surface Treatment of Dielectric Ceramic Resonator for High Frequency Devices (고주파용 유전체 세라믹 공진기의 표면처리)

  • Park, Hae-Duck;Kang, Sung-Goon
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.923-928
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    • 2001
  • An electrolytic silver plating process has been successfully developed for terminated electrode parts of dielectric ceramic resonator. High adhesion strength and high Qu is obtained and blister occurance is minimized under plating condition with $HNO_3$750 $m\ell/\ell$ and HF $ 250m\ell/\ell$ solution at $25^{\circ}C$ for 20 minutes. Adhesion strength has the highest value, 3.2 kg/mm$^2$ at etching temperature of $25^{\circ}C$. Adhesion strength, Qu and blister occurance are monotonically increased with the thickness of electrodeposition layer. In case of electrodeposition of Ag, Qu value of 380 has obtained higher than in case of electrolytic Cu plating with Qu value of 325. Therefore, terminated electrode parts of dielectric ceramic resonator reducing dielectric loss can be obtained using prensent process.

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A Study on the Analysis of Grinding Mechanism and Development of Dressig System by using Optimum In-process Electrolytic Dressing (최적 연속 전해드레싱에 의한 연삭기구의 규명 및 시스템 개발에 관한연구)

  • 이은상
    • Proceedings of the Korean Society of Machine Tool Engineers Conference
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    • 1997.04a
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    • pp.96-101
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    • 1997
  • In recent years, grinding techniques for precision machining of brittle materials used in electric, optical and magnetic parts have been improved by using superabrasive wheel and precision grinding machine. The present dressing system cannot have controll of optimum dressing of the superabrasive wheel. In this study, a new system and the grinding mechanism of optimum in-process electrolytic dressing were proposed. This system can carry out optimum in-process dressing of superabrasive wheel, and give very effective control according to unstable current and gap increase. Therefore, the optimum in-process electrolytic dressing is a good method to obtain the efficiency and mirror-like grinding of brittle materials.

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A Study on The Characteristics of Ultra Precision Lapping of Machinable Ceramic($Si_3N_4$) by Free & Fixed abrasive (자유지립 및 고정지립을 적용한 머신어블 세라믹($Si_3N_4$)의 초정밀 래핑 가공 특성에 관한 연구)

  • 장진용;이은상;조명우;조원승;이재형
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2004.10a
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    • pp.537-542
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    • 2004
  • Machinble Ceramics have some excellent properties as the material for the mechanical components. It is, however, very difficult to grind ceramics with high efficiency because of their high strength, hardness and brittleness. Lapping used diamond slurry and lapping by in-process electrolytic dressing is developed to solve this problem. On this paper, a comparative study of processing ability of lapping used diamond slurry and lapping by in-process electrolytic dressing.

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Research on Buried Depth Dependent Characteristics of Potential Rise for Structure (구조물 전위상승의 매설깊이 의존특성에 관한 연구)

  • Gil, Hyoung-Jun;Kim, Hyang-Kon;Kim, Dong-Ook;Choi, Chung-Seog
    • The Transactions of the Korean Institute of Electrical Engineers P
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    • v.56 no.2
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    • pp.104-108
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    • 2007
  • This paper deals with an approach to the reduction of potential rise according to the buried depth of structure. In order to analyze the surface potential rise of structure, an electrolytic tank which simulates the semi-infinite earth has been used. The potential rise has been measured and analyzed for types of structure using an electrolytic tank experimental apparatus in real time. The structure models were designed through reducing real buildings and fabricated with four types on a scale of one-one hundred sixty. When a test current flowed through structure models, potential gradient was the highest value in case of the outline frame type(structure model A). The distributions of surface potential rise are dependent on the resistivity and absorption percentage in concrete attached to structure model.