• The Korean Journal of Ceramics
• /
• v.4 no.4
• /
• pp.292-296
• /
• 1998

In wet powder processing of alumina, a number of organic molecules such as dispersant and binder are used to produce the flow behavior and properties requisite for shape forming. In this study, interparticle forces of alumina particles suspended in aqueous media were controlled by suspension pH, poly (methacrylic acid) (PMAA, used as dispersant) and poly (vinyl alcohol) (PVA, used as binder). The combined adsorption isotherms of the dispersant and binder additives on alumina were determined by total organic carbon analyzer, while the adsorption of dispersant was differentiated from binder in the mixed additive system by ultraviolet spectroscopy. The electrokinetic behavior of alumina suspensions were then correlated with the adsorption characteristics of dispersant and binder onto alumina particles. It was found that the isoelectric ($pH_{iep}$) of alumina shifted from pH 8.9${\pm}$0.1 to acidic pH as PMAA concentration increased, while PVA adsorption did not affect the $pH_{iep}$ but caused a decrease in the near surface potential.

• Geomechanics and Engineering
• /
• v.11 no.2
• /
• pp.197-209
• /
• 2016

Clayey rock has large clay mineral content. When in contact with water, this expands considerably and may present a significant hazard to the stability of the rock in geotechnical engineering applications. This is particularly important in the present work, which focused on mitigating some unwelcomed properties of clayey rock. Changes in its physical properties were simulated by subjecting the rock to a low voltage direct current (DC) using copper, steel and aluminum electrodes. The modified mechanism of the coupled electrical and chemical fields acting on the clayey rock was analyzed. It was concluded that the essence of clayey rock electrochemical modification is the electrokinetic effect of the DC field, together with the coupled hydraulic and electrical potential gradients in fine-grained clayey rock, including ion migration, electrophoresis and electro-osmosis. The aluminum cathodes were corroded and generated gibbsite at the anode; the steel and copper cathodes showed no obvious change. The electrical resistivity and uniaxial compressive strength (UCS) of the modified specimens from the anode, intermediate and cathode zones tended to decrease. Samples taken from these zones showed a positive correlation between electric resistivity and UCS.

• Structural Engineering and Mechanics
• /
• v.10 no.4
• /
• pp.299-312
• /
• 2000

The response of an embedded body to dynamic loads is greatly influenced by the reactions of the soil to the motion of the body. The properties of the soil surrounding embedded bodies (e.g., piles) may be different than those of the far-field for a variety of reasons. It may be weakened or strengthened according to the method of installation of piles, or altered due to applying one of the soil strengthening technique (e.g., electrokinetic treatment of soil, El Naggar et al. 1998). In all these cases, the shear strength of the soils and its shear modulus vary gradually in the radial direction, resulting in a radially inhomogeneous soil layer. This paper describes an analysis to compute vertical and torsional dynamic soil reactions of a radially inhomogeneous soil layer with a circular hole. These soil reactions could then be used to model the soil resistance in the analysis of the pile vibration under dynamic loads. The soil layer is considered to have a piecewise, radial variation for the complex shear modulus. The model is developed for soil layers improved using the electrokinetic technique but can be used for other situations where the soil properties vary gradually in the radial direction (strengthened or weakened). The soil reactions (impedance functions) are evaluated over a wide range of parameters and compared with those obtained from other solutions. A parametric study was performed to examine the effect of different soil improvement parameters on vertical and torsional impedance functions of the soil. The effect of the increase in the shear modulus and the width of the improved zone is investigated.

• Journal of Korean Society of Environmental Engineers
• /
• v.28 no.7
• /
• pp.764-769
• /
• 2006

In the electrokinetic(EK) process, oxygen production by electrolysis was proportional to current density. The dissolved oxygen (DO) concentration in anode tank and bioreactor increased with the circulation rate of electrolyte. The bacterial population in bioreactor rapidly increased by the supplement of current, but the DO concentration deceased by the increased bacterial oxygen consumption. From the results of EK bioremediation for pentadecane-contaminated soil, the bacterial population and removal efficiency at 1.88 $mA/cm^2$ were lower than those at 0.63 $mA/cm^2$. This is because the high oxygen production rate largely increased the production rate of organic acids, which reduced the electrolyte pH and bacterial activity. At 0.63 $mA/cm^2$, the highest bacterial population and removal efficiency could be obtained due to the appropriate oxygen production and small decrease in pH.

• KSCE Journal of Civil and Environmental Engineering Research
• /
• v.26 no.5C
• /
• pp.291-301
• /
• 2006

In this study the characteristics of electrokinetic remediation, which is dependent on a various electrode configuration, was predicted from 2-D numerical analysis program (HERO-2D). Based on the predicted results for one dimensional and two dimensional electrode configurations, the optimized electrode configuration was determined by analyzing remediation efficiency, consumed electric power, installation cost of electrode and so on. When proposed electrode configurations were applied for in-situ remediation of the soils contaminated by heavy metals, the electrode configuration of high remediation efficiency should be chosen in case the high removal effect would be required, and one dimensional electrode configuration should be chosen in case the hard field works would be expected. Because the rectangular electrode configuration is better than others for consumed electric power, remediation efficiency per unit power, installation cost of electrode and so on, it can obtain the best results for the cost reduction.

• Journal of Soil and Groundwater Environment
• /
• v.14 no.1
• /
• pp.36-43
• /
• 2009

The feasibility of electrokinetic remediation was investigated in the laboratory to treat contaminated soil with Zn, Ni and F. Electro-migration and electro-osmosis are the major removal mechanisms because fluorines desorbed from soil exist as an anionic form in soil pores, and Zn and Ni exist as a cationic form. Desorption of fluorine was enhanced under the alkaline condition, but that of Zn and Ni increased under the acidic condition. Sequential pH control was effective to control the mixed wastes from contaminated soil. 2 V/cm was applied to reactor to evaluate the effect of constant voltage gradient, after two weeks, the removal efficiency of Zn, Ni and F was 20.5%, 2.5% and 57.4%, respectively. Even though the removal of Zn and Ni was very low, the pH control enhanced transport of Zn and Ni significantly. As a result, sequential pH control is a effective method to remediate mixed waste-contaminated soil.

• Journal of Korean Society of Water and Wastewater
• /
• v.23 no.3
• /
• pp.353-362
• /
• 2009

A new method and equipment for measuring the zeta potential of the external surface of hollow fiber (HF) membranes is reported. An existing commercial streaming potential analyzer in conjunction with home-made test cells was used to determine the electrokinetic surface characteristics of various HF membranes. It was shown that measurements of the external surface of HF membrane using the home-made test cells designed in this study were easy and reliable. The zeta potential values were quite accurate and reproducible. By varying the physical shape of the test cells to adjust hydrodynamics inside the test cells, several upgrade versions of home-made test cells were obtained. It was shown that the zeta potential of the external surface of HF membranes was most influenced by membrane materials as well as the way of surface modification. However, the overall surface charge of tested HF membranes were much less than that of commercial polyamide thin-film-composite (TFC) reverse osmosis (RO) membranes due to the lack of surface functional groups. For the HF membranes with the same material, the effect of pore size on the zeta potential was not significant, implying the potential of accurate zeta potential measurements for various HF membranes. The results obtained in this study are expected to be useful for better understating of electrokinetic surface characteristics of the external surface of HF membranes.

• Korea-Australia Rheology Journal
• /
• v.17 no.4
• /
• pp.207-215
• /
• 2005

We present a finite difference solution for electrokinetic flow in rectangular microchannels encompassing Navier's fluid slip phenomena. The externally applied body force originated from between the nonlinear Poisson-Boltzmann field around the channel wall and the flow-induced electric field is employed in the equation of motion. The basic principle of net current conservation is applied in the ion transport. The effects of the slip length and the long-range repulsion upon the velocity profile are examined in conjunction with the friction factor. It is evident that the fluid slip counteracts the effect by the electric double layer and induces a larger flow rate. Particle streak imaging by fluorescent microscope and the data processing method developed ourselves are applied to straight channel designed to allow for flow visualization of dilute latex colloids underlying the condition of simple fluid. The reliability of the velocity profile determined by the flow imaging is justified by comparing with the finite difference solution. We recognized the behavior of fluid slip in velocity profiles at the hydrophobic surface of polydimethylsiloxane wall, from which the slip length was evaluated for different conditions.

• 한국지구물리탐사학회:학술대회논문집
• /
• 2005.05a
• /
• pp.197-202
• /
• 2005

The electromagnetic signals associated with the seismic activity in the south-east offshore of Kii peninsula, Japan, were clearly recorded at the MT sites in Jeju island, Korea. In this research, we have identified the co-seismic electromagnetic signals associated with the seismic activity and have analyzed the characteristics of significant electromagnetic variations. The analysis of phase velocity, power spectral density, MT impedance and polarization direction shows that the significant earthquake signals have the frequency band of about 0.05 to 0.5 Hz and that the sources of electromagnetic field are local effects of passing seismic waves. The simple approximation using electrokinetic effect successfully explains the co-seismic EM signals coincides with measured data but cannot explain the localities of electromagnetic variations.

• Proceedings of the KSR Conference
• /
• 2010.06a
• /
• pp.1997-2001
• /
• 2010

Generally, railroad soil around turnout was caused by leakage of lubricant oils during its maintenance. So, TPH concentration in soil was much higher than standard in Soil Envirnment Law. In additiont, railroad site was still difficult to assess due to railcar operation. This research was conducted to investigate the effect on electrolyte concentration during the Electrokinetic-Fenton process for contaminated soil around railroad turnout. As a result, experimental result shows that TPH removal in soil and amount of EOF were changed depending on electrolyte concentration. In future, the removal efficiency can be enhanced to optimize concentration in EK-Fenton Process.