• Title/Summary/Keyword: Electrode treatment

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A Study on the Fabrication of Periodic Holes on Metal Electrode for Electrodeionization System Application (전기탈이온시스템 응용을 위한 주기적 홀을 갖는 금속 전극 제작에 관한 연구)

  • Yeo, Jong-Bin;Sun, Sang-Wook;Lee, Hyun-Yong
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.26 no.3
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    • pp.227-231
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    • 2013
  • Electrodeionization is a hybrid separation process of electrodialysis and ion exchange to produce high purity water under electric field. This article provides a fabrication result of hole patterned metal electrode for elecrodeionization system. The hole patterns have been fabricated by nanosphere lithography (NSL). The technique utilizes the self-assembled nanospheres as lens-mask patterns and collimated laser beam source. The hole patterns have a periodic array structure. The images of hole pattern on metal electrode prepared were observed by SEM. We believe that the periodic hole patterned metal electrode structure is a useful device applicable for metal mat electrode in electrodeionization system.

Effect of Coating Layer on Electrode Life for Resistance Spot Welding of Al-Coated Hpf and Zn-Coated Trip Steels (Al 도금 HPF 강판과 전기아연도금 TRIP 강판의 저항 점 용접 시 연속타점 전극의 수명에 미치는 도금층의 영향)

  • Son, Jong Woo;Seo, Jong-Dock;Kim, Dong Cheol;Park, Yeong-Do
    • Corrosion Science and Technology
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    • v.11 no.1
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    • pp.29-36
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    • 2012
  • The resistance spot welding of high strength steel degrades the weldability because of its high strength with rich chemical composition and coating layer to protect from corrosion. During the each resistance welding process the electrodes tip reacts with coating layer, then subsequently deteriorates and shorten electrode life. In this study, the Al-coated HPF (Hot Press Forming) steels and Zn-coated TRIP steels were used to investigate the electrode life for resistance spot welding. Experimental results show that the reactivity of Al-coating on HPF steels to electrode tip surface behaviors different from the conventional Zn-coated high strength steels. The electrode tip diameter and nugget size in electrode life test of Al-coated HPF steels are observed to be constant with respect to weld numbers. For Al-coated HPF steels, the hard aluminum oxide layer being formed during high temperature heat treatment process reduces reactivity with copper electrode during the resistance welding process. Eventually, the electrode life in resistance spot welding of Al-coated HPF steels has the advantage over the galvanized steel sheets.

Electrochemical Degradation of Phenol and 2-Chlorophenol Using Pt/Ti and Boron-Doped Diamond Electrodes

  • Yoon, Jang-Hee;Shim, Yoon-Bo;Lee, Byoung-Seob;Choi, Se-Yong;Won, Mi-Sook
    • Bulletin of the Korean Chemical Society
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    • v.33 no.7
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    • pp.2274-2278
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    • 2012
  • To test the efficiency of the BDD electrode for complete mineralization of organic wastewater, phenol and 2-chlorophenol (2-CP) were treated electrochemically with both an active Pt/Ti electrode and a nonactive boron doped diamond (BDD) electrode, respectively, in neutral aqueous medium. Aqueous solutions of both phenol and 2-chlorophenol were treated electrochemically using an in-house fabricated flow through electrochemical cell (FTEC). The experimental variables included current input, treatment time, and the flow rate of the solutions. Depending on the magnitude of the applied current and reaction time, the compounds were either completely degraded or partially oxidized to other intermediates. Removal efficiencies reached as high as 93.2% and 94.8% both at the Pt/Ti electrode and BDD electrode, respectively, at an applied current of 200 mA for a 3.0 hr reaction and a flow rate of 4 mL/min. The BDD electrode was much more efficient for the complete mineralization of phenol and 2-chlorophenol than the Pt/Ti electrode.

An Electrolytic Treatment of Shipboard Sewage by Using DSA Electrode (I) -Batch Electrolytic Treatment- (DSA 전극에 의한 선박오폐수의 전해처리(I)-회분식 전해처리-)

  • 김인수;조권희;남청도
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.3 no.2
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    • pp.69-76
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    • 1997
  • Each factor for the most effective electrolytic reaction in treating shipboard sewage was enhanced by means of batch electrolyitc reactor using DSA electrode. The effective clearance was 6mm and pH was 5-6. In such case, more than 20% of sea water concentration was needed to attain 90% of COD removal rate. The suspended solids was effectively removed by electro-floatation in proportion as charged current density. The nitrogen and posporous were effectively removed in the electrolytic device when mixed seawater.

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Analysis on Metal Contact Resistance and Grain Boundary Barrier Height of Ceramic PTC Thermistor (Ceramic PTC thermistor의 금속접촉저항과 입계전위장벽)

  • Jeon, Yong-Woo;Lim, Byung-Jae;Hong, Sang-Jin;Soh, Dea-Wha
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.235-236
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    • 2006
  • The contact resistance and grain boundary potential barrier of ceramic $BaTiO_3$ PTCR were investigated. The electroless plated Ni, evaporated Al, and Ag paste were chosen as electrode materials of PTCR device for comparison analysis before and after heat treatment. The contact resistance of electrode were measured by electrometer (dc), digital multimeter (dc), and LCR meter (ac). In the case of Al electroded samples, the heat treatment and protective oxide layer had high resistance and effect on the stability of PTCR effect against contact resistance degradation, but the Ag-paste had comparably high contact resistance before heat treatment and decreased after heat treatment with safe. On the other hand, the samples with electroless plated Ni electrode had good properties of contact resistance against aging.

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Stereotactic Radiofrequency Gasserian Ganglionotomy (정위적 삼차신경절 고주파열응고술)

  • Shin, Keun-Man;Shin, Sam-Chyul;Cho, Yong-Roew;Lim, So-Young;Hong, Soon-Yong;Choi, Young-Ryong
    • The Korean Journal of Pain
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    • v.9 no.1
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    • pp.183-186
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    • 1996
  • When medical therapy fail to relieve pain at tolerable level for patients confirmed with trigeminal neuralgia, presence of mass lesion excluded, surgery is indicated. Innumerable surgical strategies have been attempted for the treatment of trigeminal neuralgia but only four have proven appropriate: (1)stereotactic radiofrequency gasserian ganglionotomy, (2) percutaneous glycerol gangliolysis, (3) percutaneous microcompression, (4) microvascular decompression. Radiofrequency thermocoagulation of the gasserian ganglion stems from the efforts of Sweet. This technique is the surgical treatment of choice around the world for surgical treatment for trigeminal neuralgia. Since 1986, over 14,000 cases have been reported utilizing this technique. To improve the treatment method further, an electrode with a flexible curved tip has been developed for easier and more precise electrode placement and lesion production during the thermocoagulation of gasserian ganglion. This operation was performed recently on three patients at Hallym University Hospital. using a curved tip electrode. Complete relief of pain was achieved for all patient. However, some complications were noted.

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A study of DSC using Ultrasonic and Thermal treatment on Photo-Electrode (염료감응형 태양전지 광전극 초음파 열처리에 관한 연구)

  • Hong, Ji-Tae;Kim, Mi-Jeong;Sim, Ji-Yong;Seo, Hyun-Woong;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2007.07a
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    • pp.1291-1292
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    • 2007
  • Recently, there were many researches for efficiency improvement of DSC. Among of these works, research of surface treatment is still a prerequisite for electron diffusion, light-harvesting and surface state of DSC.[1] Using of the surface treatment, it can be raise up porosity of $TiO_2$ nano-crystalline structure on photo-electrode. There are chemical, physical, electrical and optical methods which raise up its porosity. In this paper, we have designed and manufactured MOPA-type ultrasonic circuit (100W, frequency and duty variable). Manufactured ultrasonic circuit to use to force cavity density and power into $TiO_2$ paste. Then, we have optimized forcing time, frequency and duty of ultrasonic irradiation for surface treatment of photo-electrode of DSC. In I-V characteristic test of DSC, ultrasonic and thermal treated DSC shows 19% improved its efficiency against monolithic DSC. And it shows stability of light-harvesting from drastically change of light irradiation test.

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Performance of BDD Electrodes Prepared on Various Substrates for Wastewater Treatment (다양한 기판에 형성된 BDD 전극의 폐수처리 특성)

  • Kwon, Jong-Ik;You, Mi-Young;Kim, Seo-Han;Song, Pung-Keun
    • Journal of Surface Science and Engineering
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    • v.52 no.2
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    • pp.53-57
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    • 2019
  • Stability and activity of boron doped diamond (BDD) electrode are key factors for water treatment. In this study, BDD electrodes were prepared on various substrates such as Nb, Si, Ti, and $TiN_x/Ti$ by hot filament chemical vapor deposition (HFCVD) method. BDD/Ti film showed the delamination between BDD and Ti substrate due to the formation of TiC layer caused by diffusion of carbon. On the other hand, $BDD/TiN_x/Ti$ showed remarkably improved stability, compared to BDD/Ti. It was confirmed that $TiN_x$ intermediate layer act as barrier layer for diffusion of carbon. High potential window of 2.8 eV was maintained on the $BDD/TiN_x/Ti$ electrode and, better wastewater treatment capability and longer electrode working life than BDD/Nb, BDD/Si and BDD/Ti were obtained.

The Improvement of Surface Roughness of Poly-$Si_{1-x}Ge_x$Thin Film Using Ar Plasma Treatment (아르곤 플라즈마처리에 의한 다결정 $Si_{1-x}Ge_x$박막의 표면거칠기 개선)

  • 이승호;소명기
    • Journal of the Korean Ceramic Society
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    • v.34 no.11
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    • pp.1121-1128
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    • 1997
  • In this study, the Ar plasma treatment was used to improve the surface roughness of Poly-Si1-xGex thin film deposited by RTCVD. The surface roughness and the resistivity of Si1-xGex thin film were investigated with variation of Ar plasma treatment parameters (electrode distance, working pressure, time, substrate temperature and R.F power). When the Ar plasma treatment was used, the cluster size decreased by the surface etching effect due to the increasing surface collision energy of particles (ion, neutral atom) in plasma under the conditions of decreasing electrode distance and increasing pressure, time, temperature, and R. F power. Although the surface roughness value decreased by the reduction of the cluster size due to surface etching effect, however, the resistivity increased. This may be due to the surface damage caused by the increasing surface collision energy. It was concluded that the surface roughness could be improved by the Ar plasma treatment, while the resistivity was increased by the surface damage on the substrate.

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Electrolytic Treatment of Emulsified Oily Wastewater Using DSA Electrode (I) - Batch Treatment - (DSA 전극을 사용한 에멀젼 함유폐수의 전해처리 (I) -회분식 전해처리-)

  • 김인수;송영채
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.2 no.1
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    • pp.67-75
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    • 1996
  • An innovative batch electrolytic system consisted of electrolytic basin, which was equipped with DSA(Dimensionally Stable Anode) type insoluble electrode, Ti/IrO2 anode and H-C metal cathode, and flotation separator was developed for the efficient treatment of shipboard emulsified oily wastewater. The electorod cleance and current density of elecrolytic basin to ensure maximum treatment efficiency of oily wastewater was evaluated as 6 mm, 3 A/dm3, respectively. The electrolytic efficiency of oily wastewater was affected by the operationtemperature, and it means that the temperature controller to ensure the stabiity of the process is required. The conductivity in the electrolytic basin was increased with the percentage of sea water in the oily wastewater, and over 90% of treatment efficiency of oily wastewater could be obtained at 7% of sea water. The oil removal rate was increased according to the increase of the quantity of electricity, and the maximum value of electrilyic rate constant was 288 mgoil/A.min. The information obtained from this study might be used for development of an efficient continuous electrolytic system treating the emulsified oily wastewater.

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