• Title/Summary/Keyword: Electrode potential

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A Study on the Amendments of the Cathodic Protection Criteria Considering IR Drops (전압강하를 고려한 전기방식 기준 개정에 관한 연구)

  • Ryou, Young-don;Lee, Jin-han;Jo, Young-do;Kim, Jin-Jun
    • Journal of the Korean Institute of Gas
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    • v.20 no.4
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    • pp.50-57
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    • 2016
  • According to the urban gas business legislation, cathodic protection systems should be applied for buried steel gas pipelines to prevent corrosion. In advanced countries including United States, the criteria for Cathodic Protection Potential is at least -850mV with respect to a saturated copper/copper sulfate electrode(CSE) when the CP applied, and the IR drops must be considered for valid interpretation. However, the IR drop through the pipe to soil boundary has been neglected in Korea. According to KGS code, a reference electrode must be placed in proximity to gas pipelines possible when measuring the CP potential. In this study, we have installed several solid reference electrodes around the buried pipeline(1.2m depth), lower surface(0.5m depth), and the surface individually in order to measure the CP potentials through the each reference electrode and find out the IR drops according to the location of each reference electrode. We have found the IR drop is the greatest when measuring the CP potential through the electrode placed on the ground and the IR drop is the smallest through the electrode installed near pipeline. Therefore, we have suggested the solid reference electrode should be installed as close as possible to buried pipeline in order to measure the correct CP potential without IR drop. We have also suggested the amendment of CP criteria considering IR drop.

Investigations with respect to the electrochemical properties of carbon paste electrode fabricated using polybutadiene binder (폴리부타디엔 결합재를 이용하여 만든 탄소반죽전극의 전기화학적 특성에 관한 연구)

  • Yoon, Kil-Joong
    • Analytical Science and Technology
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    • v.20 no.1
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    • pp.49-54
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    • 2007
  • For the practical use as a biosensor, a rubber electrode bound by polybutadiene was newly devised for the determination of hydrogen peroxide. Then its electrochemical behaviors were investigated. The signal could be obtained at low electrode potential between 0.0 ~ -0.5 V (vs. Ag/AgCl) with a detection limit of $1.4{\times}10^{-4}M$ and its potential dependence was linear in the experimental range. Especially its Lineweaver-Burk plot showed a very good linearity giving the evidence of a good enzyme immobilization on the surface of the electrode. And mechanical stability of the electrode resulted from using rubber binder presented a new possibility for the practical use of biosensor.

Relative Measurement of Differential Electrode Impedance for Contact Monitoring in a Biopotential Amplifier

  • Yoo, Sun-K.
    • International Journal of Control, Automation, and Systems
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    • v.5 no.5
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    • pp.601-605
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    • 2007
  • In this paper, we propose a simple and relative electrode contact monitoring method. By exploiting the power line interference, which is regarded as one of the worst noise sources for bio-potential measurement, the relative difference in electrode impedance can be measured without a current or voltage source. Substantial benefits, including no extra circuit components, no degradation of the body potential driving circuit, and no electrical safety problem, can be achieved using this method. Furthermore, this method can be applied to multi-channel isolated bio-potential measurement systems and home health care devices under a steady measuring environment.

The Response Characteristic of Hydrogen-responsive Glass Electrode in Methanol, N, N-dimethylformamide and Acetonitrile (Methanol, N,N-dimethylformamide 및 Acetonitrile 속에서 유리전극의 pH 응답성)

  • Su Chan Moon
    • Journal of the Korean Chemical Society
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    • v.16 no.3
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    • pp.149-156
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    • 1972
  • The responsive characteristics of hydrogen-responsive glass electrode in various buffer solutions of methanol, N,N-dimethylformamide and acetonitrile were examined. The potentials were attained more rapidly with an electrode stored in the same solvent medium than that stored in water before use. However, the time to be required for a stable potential increased with the basicity of buffer solution, and it was not provide a constant potential in the strong basic solution of these solvent. Even in acidic solution, the potential was varied according to the past usage of the electrode.

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Study on Electrochemical Performance of Solid-State-Electrode on Steel bar in Chloride Solution (염화물 수용액 중의 철근에 대한 고체전극의 전기화학적 성능 연구)

  • Park, Dong-Jin;Park, Jang-Hyun;Lee, Han-Seung;Subbiah, Karthick
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2018.05a
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    • pp.147-148
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    • 2018
  • In order to compare the electrochemical performance with that of Calomel Electrode, MnO2 solid-state-electrode was fabricated and its potential and impedance were measured in chloride aqueous solution. As a result, the SCPS without chloride ions showed a potential of -200 mV or more and an impedance over 2000 Ωcm, but the potential below -600 mV and the impedance below -200 Ωcm showed as the chloride concentration in the solution increased. It is considered electrochemical studies on the corrosion of rebar are necessary for the MOE, which shows the same tendency as SCE and exhibits electrochemical performance, over the Mortar level in the future.

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Optimization of Wave Forms for Pulsed Amperometric Detection of Cyanide and Sulfide with Silver-Working Electrode

  • Park, Seong U;Hong, Seong Uk;Yu, Jae Hun
    • Bulletin of the Korean Chemical Society
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    • v.17 no.2
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    • pp.143-146
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    • 1996
  • A continuous potential pulse is applied to a silver-working electrode on a pulsed amperometric detector (PAD) for detection of free cyanide and sulfide. The moving phase is 0.1 M sodium hydroxide, 0.5 M sodium acetate and 5% (v/v) ethylenediamine mixture, and the flow rate is 0.7 mL/min. Optimized pulse conditions include a -200 mV (vs. Ag/AgCl reference electrode) detection potential(Ed) for 60 msec and 50 mV cleaning potential (Ec) for 120 msec. The silver working electrode surface is not poisoned by cyanide or sulfide, and the PAD maintains long-term stability without loss of sensitivity and reproducibility at these pulse conditions. The detection limit of cyanide and sulfide separated by ion chromatography using an anion exchange column is 0.1 ppm and 0.05 ppm, respectively.

Analysis of the Ground Surface Potential Rise using a Hemisphere-Shaped Test Model (반구형 실험모델을 이용한 대지표면 전위상승의 분석)

  • Yoo, Jae-Duk;Cho, Yong-Seung;Lee, Bok-Hee
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.24 no.12
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    • pp.208-213
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    • 2010
  • This paper deal with an analysis of the ground surface potential profiles using a hemispherical scaled-model. Because it is very difficult to draw valid conclusions concerning a general grounding problem from actual field data, scale model tests can be used to determine the ground surface potential profile around the grounding electrodes according to the configuration of grounding electrodes. In this work, a hemispherical vessel with a diameter of 1,100 [mm] was employed to simulate uniform soil and CDEGS program was employed to compare the measured and simulated results. As a result, the ground surface potential around the grounding electrode was significantly raised and the ground surface potential at the just upper point of ground electrode particularly was higher than other points. The ground surface potential of counterpoise was higher than other grounding electrodes such as mesh and grounding rods and the ground surface potential strongly depends on the frequency responses of grounding electrodes. Also the results measured with the small-sized model were in reasonably agreement with the data obtained from simulation.

presumption of Earth Resistance by Water Tank Model (수조모델 실험에 의한 접지저항 추정)

  • 고희석;최종규;김주찬;이충식
    • Proceedings of the Korean Institute of IIIuminating and Electrical Installation Engineers Conference
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    • 2002.11a
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    • pp.125-131
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    • 2002
  • It is very important to assume potential distribution to be generated in electrode environs and grounding resistance by current beforehand, when incoming at grounding electrode to plan efficient grounding facilities In this paper, we analyzed grounding resistance through a simulation experiment by a water tank scaled model electrode of the rectangular earth plate, a theoretical Calculation result of the rectangular earth plate and measurement of grounding resistance buried rectangular earth plate analysing earth surface potential.

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Surface Potential Distribution according to Grounding Electrode Shapes (접지전극 형상에 따른 대지표면전위분포)

  • Baek, Young-Hwan;Lee, Bok-Hee;Li, Feng;Yang, Soon-Man;Lee, Kyu-Sun
    • Proceedings of the KIEE Conference
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    • 2008.07a
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    • pp.1360-1361
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    • 2008
  • This paper presents the surface potential rise distribution near grounding electrodes produced by ground fault currents. The small-scale model with the foundation pedestal in hemispherical tank was used to simulate the ground fault condition of the electrical installations for street lamps. When entering the fault current through the test ground electrode, surface potential rise, potential gradient, touch and step voltages for different grounding electrode shapes were measured, and the results obtained were discussed.

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Study for the Grounding Resistance of the Mesh Grounding Electrode by Water Tank Model (수조모델을 이용한 메쉬접지극의 접지저항에 관한 연구)

  • Kim, Ju-Chan;Kim, Sung-Sam;Choi, Jong-Gyu;Lee, Chung-Sik;Koh, Hee-Seog
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.20 no.3
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    • pp.28-35
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    • 2006
  • Recently, a number of equipments related with electricity, electronics, and communication in the same building are needed to the grounding system for safety from unexpected accidents. When the faulted electric current flows into a certain grounding system, the potential rise in that system takes place and it might induce the potential rise to other grounding system. This potential interference was strongly affected by the surface potential, which was deeply related with the electrode shape. In this paper, the fundamental formula was deduced on the basis of surface potential of two grounding electrodes. Which corresponds to source of the potential interference and other grounding electrode, respectively. Therefore, the degree of potential interference in this mesh grounding electrode system was verified by the simple model simulation. In addition, in order to identify the difference between the grounding resistance in the realistic construction site and the expected value from the corresponding simulation, the experiment was performed with model on a reduced scale about the realistic grounding system. It consists of stainless steel hemisphere electrodes in a water tank. From this work, the grounding resistance in the mesh grounding electrode showed the good coincidence results between those. Consequently, it is confirmed that the grounding resistance in the mesh electrode is possible to be estimated by performing the experiment using the water tank model.