• 한국정밀공학회:학술대회논문집
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• 한국정밀공학회 2005년도 춘계학술대회 논문집
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• pp.1281-1284
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• 2005

In the micro electrochemical machining (ECM), unfavorable oxide/passive layer formation and overall corrosion of electrodes must be prevented. Generally, the stainless steel electrode corrodes, passivates or dissolves in the electrochemical cell according to the electrode potential. Therefore, the electrode must maintain stable potential. The stable electrode potentials of tool and workpiece were determined with the potentiodynamic polarization test and verified experimentally from the point of machining stability and machined surface quality.

• 조명전기설비학회논문지
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• 제22권2호
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• pp.57-62
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• 2008

본 논문에서는 전위상승에 대한 개별 접지전극과 연접된 접지전극의 비교를 다루었으며, 시험전류가 접지전극에 흐를 때 실시간으로 접지방식에 대한 전위상승이 측정 및 분석되었다. 접지시스템의 전위상승을 분석하기 위해 반구형 수조실험장치가 사용되었고, 이를 이용하여 접지방식 및 거리에 따라 전위상승이 측정되었다. 실험장치는 반구형 수조, 전원공급장치, 이송형 전위계측장치, 시험 접지전극으로 구성되었고 전위계측장치의 프로브가 수평방향으로 이송함에 따라 전위상승이 측정되었고, 접지전극으로는 80 : 1 축척의 봉형 접지전극을 사용하였다. 개별 접지전극의 전위상승이 연접된 접지전극보다 높게 나타났으며 전위분포는 접지전극으로부터의 거리에 의존하는 특성을 나타내었다.

• 한국재료학회지
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• 제27권11호
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• pp.624-630
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• 2017

In this study, we investigated the overpotential of precipitation related to the catalytic activity of electrodes on the initial process of electrodeposition of Co and Co-Ni alloys on polycrystalline Cu substrates. In the case of Co electrodeposition, the surface morphology and the magnetic property change depending on the film thickness, and the relationship with the electrode potential fluctuation was shown. Initially, the deposition potential(-170 mV) of the Cu electrode as a substrate was shown, the electrode potential($E_{dep}$) at the $T_{on}$ of electrodeposition and the deposition potential(-600 mV) of the surface of the electrodeposited Co film after $T_{off}$ and when the pulse current was completed were shown. No significant change in the electrode potential value was observed when the pulse current was energized. However, in a range of number of pulses up to 5, there was a small fluctuation in the values of $E_{dep}$ and $E_{imm}$. In addition, in the Co-Ni alloy electrodeposition, the deposition potential(-280 mV) of the Cu electrode as the substrate exhibited the deposition potential(-615 mV) of the electrodeposited Co-Ni alloy after pulsed current application, the $E_{dep}$ of electrodeposition at the $T_{on}$ of each pulse and the $E_{imm}$ at the $T_{off}$ varied greatly each time the pulse current was applied. From 20 % to less than 90 % of the Co content of the thin film was continuously changed, and the value was constant at a pulse number of 100 or more. In any case, it was found that the shape of the substrate had a great influence.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2004년도 학술대회 논문집
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• pp.111-114
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• 2004

There are many electricity, electronics, and communication equipment which need to Grounding in the building. When electric current flows into a certain Grounding system in the same building, the potential of other Grounding system rises. This potential interference repuire surface potential of electrods by electrode shape. In this paper basic formula is deduced on the basis of both electrodes surface potential of Grounding electrode as a source of the potential interference and Grounding electrode which receive the potential interference. The degree of potential interference as multiple Grounding electrode is verified the simulated results by means of the simple model in advance.

• 대한전기학회논문지:전기물성ㆍ응용부문C
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• 제54권8호
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• pp.371-377
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• 2005

This paper Presents the Potential gradient characteristics of structure grounding electrode when a test current flows through grounding electrode. In order to analyze the potential gradient of ground surface on structure grounding electrode, the reduced scale model has been used. The potential gradient has been measured and analyzed for types of structure using the hemispherical grounding simulation system in real time. The structures were designed through reducing real buildings and fabricated with four types on a scale of one-one hundred sixty. The supporter was made to put up with weight of structure and could move into vertical, horizontal, rotary direction. When a test current flowed through structure grounding electrodes, ground potential rise was the lowest value at electric cage type(type B). According to resistivity and absorption percentage In concrete attached to structure, the potential distribution of ground surface appeared differently.

• 한국조명전기설비학회:학술대회논문집
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• 한국조명전기설비학회 2005년도 춘계학술대회논문집
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• pp.349-354
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• 2005

Recently, there are many equipment of electricity, electronics, and communication which need to grounding in the building. When the electric current flows into a certain grounding system in the same building, the potential rise of other grounding system is possible to be affected by its potential rise. This potential interference was affected by the surface potential, it is deeply related whit the electrode shape. In this paper, basic formula is deduced on the basis of both electrodes surface potential of grounding electrode in a source of the potential interference and groundidng electrode which receive the potential interference. Therefore the degree of potential interference as multiple groundidng electrode can be verified the simulated results by means of the simple model in advance. This is for investigating the grounding resistance of grounding electrodes, the experiment was performed with model-scale of the grounding system and the scaled model grounding system was to this experiment using a water tank of a stainless steel-hemisphere shape. since mesh electrodes have been widely in the general building, we're tried to analyze that this water tank model and it's simulation as well.

• Korean Chemical Engineering Research
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• 제45권5호
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• pp.433-441
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• 2007

본 논문에서는 질산염 이온의 환원을 위한 Sn의 흡착 또는 전착을 가지는 Sn-modified Pt 전극의 안정성이 평가되었다. 전극의 불안정성의 원인을 찾기 위하여 전극이 접하는 용액과 전극에 가해지는 전압에 따른 Pt 표면에서 Sn의 전기화학적 및 재료적 변화가 조사되었다. 제작된 Sn-modified Pt 전극 표면의 Sn은 hydroxide 형태로 존재하여 물, 특히 산 용액에서 방치하는 것에 의해서도 용해되어 쉽게 전극의 활성이 감소되었으며, 질산염 이온의 환원 시 전극에 $Sn(OH)_2$와 Sn의 산화-환원 평형 전압 보다 음의 전압이 가해질 때 전극 표면의 Sn hydroxide는 Sn으로 환원되어 Pt 전극 내부로 고체 확산되었고, 이는 Sn-modified Pt 전극의 활성을 감소시켰다. Sn의 고체 확산은 전극에 가해주는 전압에 비례하였다. Sn을 Pt에 코팅시키기 위하여 UPD 조건에서 흡착하는 것 보다 많은 Sn을 Pt 표면에 붙일 수 있는 Sn을 Pt에 전해 전착시키는 것이 질산염 이온의 환원하는 동안 전극의 건전성을 유지하는데 유리하였다.

• 조명전기설비학회논문지
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• 제27권2호
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• pp.95-101
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• 2013

This paper presents the comparison of the earth resistivity obtained from the measurements made with the three-electrode and four-electrode fall-of-potential techniques. The ${\rho}-a$ curve obtained from Wenner four-electrode method in undisturbed earth is in good agreement with the ${\rho}-l$ curve obtained from the three-electrode method based on the fall-of- potential method. However, The ${\rho}-a$ curve in disturbed earth with moisture and freezing is significantly different with the ${\rho}-l$ curve. The ${\rho}-a$ curve is considerably sensitive to the freezing and the moisture present in the earth surface compared to the ${\rho}-l$ curve. Thus to determine the actual earth resistivity, it is necessary to take into account the earth surface conditions when measuring the earth resistivity.

• Bulletin of the Korean Chemical Society
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• 제11권6호
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• pp.487-493
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• 1990

A complete potential profile of an electrical double layer is calculated from a distribution function of charged particles based upon a model where the effect of a charged electrode and the finite size of ion are explicitly included. Electrons which are distributed on the electrode surface are assumed not to penetrate the electrode/electrolyte boundary. Formation of the constant density regions and their effects on potential and the electrical double layer capacitances are studied in great detail. The distribution of surface electrons as well as the constant density regions are found to be essential in characterizing the electrical double layer. The introduction of the ion size into the prior electrical double layer model of an ideally polarizable electrode/point charged electrolyte system, shows a great improvement in its characteristics mostly at negative potential region.

• Bulletin of the Korean Chemical Society
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• 제10권6호
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• pp.585-591
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• 1989

The effects of the charged metal on the overall electrostatic potential profiles and the capacitances of the electrical double layer are brought out. A model with a simplified jellium and a point-charged electrolyte is utilized in the present calculations. Electrons are assumed not to penetrate electrode surface due to a strong screening of electrolyte at the interface. Electron density functions and ion density functions are obtained, which are also based upon the Poisson equation and Boltzmann equation on either side of the interface. A complete potential profile starting from bulk electrode and ending at bulk electrolyte is obtained by connecting the two potential profiles (one inside the metal electrode, the other inside the electrolyte) with proper boundary conditions. In spite of the simplicity of the model, the present model reveals the importance of the effect of the charged metal on the electrostatic potential profile and the electrical double layer capacitances. The results are discussed and compared with the predictions by Gouy Chapman theory.