• Title/Summary/Keyword: Electrode form

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Electrical Properties of Liquid Insulation as a Function of Temperature (온도에 따른 액체 절연유의 전기적 특성 )

  • Tae-Hee Kim;Yong-Sung Choi
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.37 no.3
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    • pp.280-285
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    • 2024
  • In this paper, the electrical properties of liquid insulating oil were analyzed by changing the ambient temperature change at 10℃ in-tervals from 0℃ to 30℃ through an insulation breakdown experiment in order to analyze the insulation performance of liquid in-sulating oil that varies according to temperature changes. As a result, it was confirmed through experiments that the lower the am-bient temperature, the higher the insulation breakdown voltage, depending on both the electrode shape and the electrode interval, and it was determined that the lower the ambient temperature, the higher the insulation performance of the liquid insulating oil.

Adsorption Properties of Fuel-Cell Electrode Produced from Activated Carbon Fibers in Three Phase Distribution (삼상 계면대에서 활성 탄소섬유로 된 연료전지 전극의 흡착 특성)

  • 박수진;정효진;나창운
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.46-51
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    • 2003
  • In this work, the electrode far fuel cell was fabricated by mixing carbon blacks with activated carbon fibers (ACFs) in order to form the proper three phase distribution, and then the change of electrode in three phase distribution was investigated. Pt loading yield with ACF content and Pt particle size were determined by AAS and XRD measurements, respectively. And the pore structures, including specific surface area ($S_{BET}$), microporosity, and pore size distribution (PSD) for each electrode were systematically investigated by BET volumetric measurement. The morphology of electrode in three phase distribution was determined by SEM. As an experimental result, it was observed that Pt loading yield was not influenced on the content of ACF. While, the electrode in three phase distribution was largely improved in the case of 30% ACF addition on carbon blacks. These results were probably explained by the increase of the portion of micropores, resulting in increasing the active sites of catalyst.

EPD Thick Film Formation of Ceramic Powder Materials (세라믹 분말재료의 EPD 후막형성 기술)

  • Soh, Dea-Wha;Jeon, Yong-Woo
    • Journal of the Speleological Society of Korea
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    • no.75
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    • pp.49-54
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    • 2006
  • Electrophoretic Deposition (EPD) is the most convenient technology to deposit natural or oxide powders of nonconductive materials in alcoholic suspension solution with adding electrolyte of iodine to form ceramic thick film on metal substrate under applied electric field with double electric layer between electrode and metal substrate. In this research work, the important parameters and technical ways were studied to form EPD thick films of typical oxide ceramics of Al2O3, YBCO and tourmaline powders.

Facile Coating of Poly(3,4-ethylenedioxythiophene) on Manganese Dioxide by Galvanic Displacement Reaction and Its Electrochemical Properties for Electrochemical Capacitors

  • Kim, Kwang-Heon;Kim, Ji-Young;Kim, Kwang-Bum
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2529-2534
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    • 2012
  • Poly(3,4-ethylenedioxythiophene) coated Manganese Dioxide (PEDOT/$MnO_2$) composite electrode was fabricated by simply immersing the $MnO_2$ electrode in an acidic aqueous solution containing 3,4-ethylenedioxythiophene (EDOT) monomers. Analysis of open-circuit potential of the $MnO_2$ electrode in the solution indicates the reduction of outer surface of $MnO_2$ to dissolved $Mn^{2+}$ ions and simultaneously oxidation of EDOT monomer to PEDOT on the $MnO_2$ surface to form a PEDOT shell via a galvanic displacement reaction. Analysis of cyclic voltammograms and specific capacitance of the PEDOT/$MnO_2$, conductive carbon added $MnO_2$ and conductive carbon added PEDOT/$MnO_2$ electrodes suggests that the conductive carbon acted mainly to provide a continuous conducting path in the electrode to improve the rate capability and the PEDOT layer on $MnO_2$ acts to increase the active reaction site of $MnO_2$.

Improved Efficiency by Insertion of TiO2 Interfacial Layer in the Bilayer Solar Cells

  • Xie, Lin;Yoon, Soyeon;Kim, Kyungkon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2016.02a
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    • pp.432.1-432.1
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    • 2016
  • We demonstrated that the power conversion efficiency (PCE) of bilayer solar cell was significantly enhanced by inserting interfacial layer between the organic bilayer film and the Al electrode. Moreover, the water contact angle shows that the bilayer solar cells suffer from the undesirable surface component which limits the charge transport to the Al electrode. The AFM measurement has revealed that the pre- and post-thermal annealing treatments results in different morphologies of the interfacial layer which is critical for the higher PCE of the bilayer solar cells. Furthermore we have investigated the electrical properties of the bilayer solar cells and obtained insights into the detailed device mechanisms. The transient photovoltage measurements suggests that the significantly enhanced Voc is caused by reducing the recombination at the interface between the organic films and the Al electrode. By inserting the TiO2 layer between the bilayer film and Al electrode, the open circuit voltage (Voc) was increased from 0.37 to 0.66V. Consequently, the power conversion efficiency (PCE) of bilayer solar cells was significantly enhanced from 1.23% to 3.71%. As the results, the TiO2 interfacial layer can be used to form an ohmic contact layer, serveing as a blocking layer to prevent the penetration of the Al, and to reduce the recombination at the interface.

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The Warpage Phenomena of Electrolyte Layer During the Sintering Process in the Layered Planar SOFC Module (적층 평판형 SOFC 모듈에서 소결 시 전해질 층의 휨 현상)

  • Oh, Min-Wook;Gu, Sin-Il;Shin, Hyo-Soon;Yeo, Dong-Hun
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.25 no.3
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    • pp.241-246
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    • 2012
  • A layered planer SOFC module was designed from planar-type SOFC. It was prepared by multi-layered ceramic technology. To form the cathode and the anode in the layered structure, reliable channels should be made on the both side of electrolyte perpendicularly. However, monolithic SOFC using multi-layered ceramic technology hasn't been studied another group, and the warpage of electrolyte in the channel, also, hasn't been studied, when electrode is printed on the electrolyte. In this study, the channels are prepared with electrode printing, and their warpage are evaluated. In the case of YSZ without electrode, the warpages are nothing in the limit of measurement using optical microscope. The warpage of 'YSZ-NiO printed' increases than that of 'NiO printed', and also, the case of 'double electrode printed' is similar to 'YSZ-NiO printed'. It is thought that, in the printed electrolyte, the warpage is related to the difference of the sintering behavior of each material.

Preparation of Coated-Wire Nitrate Ion Selective Electrode and its Application for Environmental Analysis (질산이온 선택성 피복선 전극의 제작 및 환경분석에의 응용)

  • 李龍根;金昌圭;朴廷泰;金京燮;黃圭子
    • Journal of Korean Society for Atmospheric Environment
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    • v.1 no.1
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    • pp.99-107
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    • 1985
  • A coated wire ion selective electrode for nitrate (nitrate-CWE_ was constructed using epoxy resin, ion exchanger and plasticizer as a polymer membrane. It's stility, the composition of a polymer membrane, the response characteristics, the selectivity were examined and applied to the environmental analysis. The nitrate-CWE was prepared using a copper wire, wihch was coated with epoxy resin being incorporated with the nitrate ion exchanger and plasticizer. The best composition of the polymer membrane for the nitrate-CWE was obtained by mixing epoxy resin, ion exchanger and plasticizer in the ratio of 2:1:0.4. The potential (56.3$\pm$0.5 mV) of stick form nitrate-CWE in this composition was close to that (59.2 mV) of Nernstian response. The detection limit for nitrate ion were found to the about $6 \times 10^{-5}M$ and the useful pH was 2.5 $\sim$ 10.3. Furthermore, the selectivity of iodide and perchrorate for the nitrage-CWE was also much improved compared with that for a liquid membrane nitrate electrode. The nitrate-CWE was used to determind $NO_x$ in stack gas. The results were in good agreement with those obtained either by electrode method or by the improved NEDA method within a relative error of 4.0%.

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Analysis of Partial Discharge Pattern according to Needle Electrode Slope in XLPE for Ultra High Voltage insulators (침 전극 기울기에 따른 초고압 절연체 XLPE의 부분방전 패턴해석)

  • Ahn, Byung-Chul;Kim, Tag-Yong;Lee, Kang-Won;Lee, Duck-Jin;Shin, Jong-Yeol;Lee, Chung-Ho;Hong, Jin-Woong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2006.11a
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    • pp.162-163
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    • 2006
  • XLPE is used to insulator for Ultra High Voltage power cable. It is easy to processing also has a good insulating property. The study for diagnosis of lifetime and improvement is proceeding continuously. In this paper, it is investigated partial discharge distribution according to slope of needle electrode 0, 20, $40^{\circ}$. Applied voltage is 0.5 [kV/s] by step form for inception voltage. As the result of study, we conformed that increase of slope led to reduce of discharge number and total discharge quantity.

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Effectiveness of the Electrochemical Sensor for the Free Chlorine Measurement (잔류염소 측정용 전기화학센서의 유효성)

  • Kim, Hong-Won;Chung, Nam-Yong
    • Journal of the Korean Society of Manufacturing Technology Engineers
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    • v.21 no.5
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    • pp.720-725
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    • 2012
  • Sodium hypochlorite is used worldwide as a water disinfectant and in bleaching agent. Sodium hypochlorite applied to water initially undergoes hydrolysis to form free chlorine consisting of hypochlorous acid(HOCl) and hypochlorite ion($OCl^-$). For free chlorine determination, an electrochemical method is simple due to the electroactivity of free chlorine; it measures current and is free of most reagents. Amperometric free chlorine sensor has been developed with gold (Au)-based electrode. The 3-electrode free chlorine sensor whose working and counter electrodes were Pt exhibited excellent response to HClO at +400mV vs. Ag/AgCl/sat. KCl. In addition, the use of a pH error correction algorithm provided a reliable measurement of residual free chlorine in water sample without any pretreatment in the normal pH range(pH 6~8) of municipal water supply. The free chlorine sensor installed in on-line monitoring system could be used to continually monitor the level of residual free chlorine in real samples.

Effect of Electrode Diameter on Pine Ceramic Pattern Formed by Using Pin-To-Pin Type Electro-Hydrodynamic Printing (핀-핀 형 전극의 전기-수력학 프린팅에서 전극 직경이 미세 세라믹 패턴 형성에 미치는 영향)

  • Lee Dae-Young;Yu Jae-Hun;Yu Tae-U;Hwang Jungho;Kim Yong-Jun
    • Transactions of the Society of Information Storage Systems
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    • v.1 no.1
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    • pp.108-114
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    • 2005
  • The generation of fine relics of suspensions is a significant interest as it holds the key to the fabrication of electronic devices. These processes offer opportunities for miniaturization of multilayer circuits, for production of functionally graded materials, ordered composites and far small complex-shaped components. Some novel printing methods of depositing ceramic and metal droplets were suggested in recent years. In an electro-hydrodynamic printing, the metallic capillary nozzle can be raised to several kilovolts with respect to the infinite ground plate or pin-type electrode positioned a few millimeters from the nozzle tip. Depending on the electrical and physical properties of the liquid, for a given geometry, it Is possible to generate droplets in any one of three modes, dripping, cone-jet and multi-jet. In this experiment, an alumina suspension flowing through a nozzle was subjected to electro-hydrodynamic printing using pin-type electrodes in the cone-jet mode at different applied voltages. The pin-type electrodes of 1, 100, 1000${\mu}m$ in diameter were used to form fine ceramic patterns onto the substrates. Various feature sizes with applied voltages and electrode diameters were measured. The feature sizes increased with the electrode diameter and applied voltages. The feature size was as fine as $30 {\mu}m$.

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