• Title/Summary/Keyword: Electrode bar

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Li[Co0.50Li0.17Mn0.33]O2 양극물질의 고율 충방전 특성 (High Rate Performance of Li[Co0.50Li0.17Mn0.33]O2 Cathode)

  • 박용준
    • 한국전기전자재료학회논문지
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    • 제19권8호
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    • pp.737-743
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    • 2006
  • [ $Li[Co_{0.50}Li_{0.17}Mn_{0.33}]O_2$ ] powder was prepared using a simple combustion method. specially, ratio of 2:1, 3:2, 1:1, 2:3, 1:2 was adopted as acetate source/nitrate source. The diffraction pattern of $Li[Co_{0.50}Li_{0.17}Mn_{0.33}]O_2$ powder showed that this compound could be classified as hexagonal $a-NaFeO_2$ structure (space group : $R\bar{3}m$). The size of powder was less than $1{\mu}m$. Small particle size of cathode powder would give a good ionic and electronic conductivity to cathode electrode, which made of cathode powder. As the increase of nitrate source-ratio, discharge capacity of $Li[Co_{0.50}Li_{0.17}Mn_{0.33}]O_2$ at high charge-discharge rate was increased. When the ratio of acetate source/nitrate source was 1:2, discharge capacity at 10 C rate (2000 mA/g) was 180 mAh/g. It was $10{\sim}15%$ larger than that of powder, which have 2:1 as acetate source/nitrate ratio.

전도성 흑연을 포함하는 발열 필름의 열적 특성 (Thermal Characteristics of Heating Films Including Conductive Graphite)

  • 최규연;오원태
    • 한국전기전자재료학회논문지
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    • 제33권6호
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    • pp.500-504
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    • 2020
  • Heating films were prepared with composites of poly (methyl methacrylate) and conductive graphite. The as-prepared composite was deposited on a PET film and then fabricated using a bar coater to produce a film with uniform thickness. Copper electrodes were attached to both ends of the as-prepared film, and the heating characteristics of the film were analyzed while applying a DC voltage. The electrical conductivity and heating temperature of the heating films depended on the size, structure, content, and the dispersion characteristics of the graphite in the composite. The thermal energy was adjusted by controlling the electrical energy, based on the Joule heating theory. The electrical resistance of the film was altered in proportion to Ohm's law, and the heating temperature was changed according to the structure of the film (interelectrode spacing or electrode length) and the conductive graphite content. When the content of conductive graphite in the film increases, the electrical resistance decreases, and the heating temperature increases; however, there is no significant change above a certain content (50%).

LiNbO$_3$ 광 도파로의 전계분포 및 설계에 관한 연구 (A Study on the electric field distribution of design of LiNbO$_3$ optical waveguide)

  • 강기성;소대화
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.288-293
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    • 2000
  • BPM simulation was used in order to fabricate the LiNbO$_3$optical waveguide with optical source of He-Ne laser(λ=0.6328[$\mu$m]). we observed electric field E$_{x}$, E$_{y}$ in the x,y-direction are simulated at the LiNbO$_3$substrate (X1 55[$\mu$m]$\times$Z1 5000[$\mu$m]), where the depth, width and buffer layer of waveguide are 0.2[$\mu$m],4[$\mu$m] and 0.02[$\mu$m] respectively. By applying these parameters of single waveguide to simulate a X-switch, we have chosen index change of 0.002, width of 3[$\mu$m] and angle of 0.4$^{\circ}$~0.6$^{\circ}$of optical waveguide and under these conditions, optical beam propagates cross-side at 0.4$^{\circ}$. When applied switching voltage of 25[V], optical beam of X-switch turns cross-side to bar-side at intersection angle 0.4$^{\circ}$, index change of 0.002, waveguide width of 3[$\mu$m], electrode gap 2[$\mu$m]. By the above results, we can obtain design conditions of theoretical analysis of an X-switch optical waveguide.e.e.

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Electrochromic Performance of NiOx Thin Film on Flexible PET/ITO Prepared by Nanocrystallite-Dispersion Sol

  • Kwak, Jun Young;Jung, Young Hee;Park, Juyun;Kang, Yong-Chul;Kim, Yeong Il
    • 대한화학회지
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    • 제65권2호
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    • pp.125-132
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    • 2021
  • An electrochromic nickel oxide thin film was fabricated on a flexible PET/ITO substrate using a nanocrystallite- dispersed coating sol and bar coater. Nanocrystalline NiOx of 3-4 nm crystallite size was first synthesized by base precipitation and thermal conversion. This NiOx nanocrystallite powder was mechanically dispersed in an alcoholic solvent mixed with a silane binder to prepare a coating sol for thin film. This sol method is different from the normal sol-gel method in that it does not require the conversion of precursor by heat treatment. Therefore, this method provides a very facile method to prepare NiOx thin films on any kind of substrate and it can be easily applied to mass production. The electrochromic performance of this NiOx thin film on PET/ITO electrode with a thickness of about 400 nm was investigated in a nonaqueous LiClO4 electrolyte solution by cyclic voltammetric and repeated chronoamperometric measurements in conjunction with spectrophotometry. The visible light modulation of 44% and the colorization efficiency of 41 ㎠/C at 550 nm were obtained at the step potentials of -0.8/+1.2 V vs Ag and a duration of 30 s.

대면적 Multi busbar 모듈 전력 손실 저감을 위한 태양전지 설계 (Solar Cell Design for Large Area Multi Busbar Module Power Loss Reduction)

  • 김주휘;이재형
    • Current Photovoltaic Research
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    • 제11권1호
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    • pp.34-37
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    • 2023
  • Solar energy had become the main energy industry of renewable energy along with hydroelectric power generation. One of the technologies that contributed to the popularization of photovoltaic power and the decrease in the unit price of photovoltaic modules was the large-area solar cell. However, as the area increased, the light receiving area increased and the current value increased accordingly. Since power loss occurs when the current value was large, the number of busbar was increased to increase the current collection rate, and a technology to lower the current value through half-cutting was developed. The bus bar of the solar cell served as a passage through which the generated current was transmitted. This was because when the number of busbar decreases, the moving distance of electrons increased, so the amount of power generation decreases and when it increases, shadows occured. An important aspect of the electrode design was the optimal balance of these busbars and number of fingers. Therefore, in this study, the characteristics of the solar cell according to the number of front bus bars of the large-area solar cell were simulated using Griddler 2,5 pro. After selecting the number of busbar with the best characteristics, the difference was compared by varying the number of fingers and a better direction for the number of cutting was presented.

Nanophase Catalyst Layer for Direct Methanol Fuel Cells

  • Chang Hyuk;Kim Jirae
    • 전기화학회지
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    • 제4권4호
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    • pp.172-175
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    • 2001
  • 마그네트론 스퍼터링 방법에 의하여 Nanophase 촉매층을 형성하여 Direct Methanol Fuel Cell(DMFC)에 적용하였다. 일반적인 박막 증착 방법보다 높은 압력 (Ar/He혼합기체)에서 금속 Target과 탄소 Target을 동시에 스퍼터링하여 내피온막 위에 직접 코팅함으로써 기공성 있는 PtRu혹은 Pt및 탄소입자를 포함한 새로운 구조의 촉매층을 형성하였다. 본 방법에 의하여 $1.5mg/cm^2$의 PtRu(Anode) 및 $1mg/cm^2$ Pt(Cathode) 로딩으로 2M Methanol, 1 Bar공기, $80^{\circ}C$조건에서 $45mW/cm^2$의 출력을 얻을 수 있었으며, 이는 기존의 상용방법에 의하여 제조된 전극보다 같은 조건에서 $30\%$의 성능향상을 제시한 것이다. 이는 Nanophase촉매층 구조로 인하여 초미세 분말을 적용하였고, 많은 량의 원자들이 입계에 배열하게 됨으로써 촉매반응을 원활하게 하고,연료의 공급을 효율적으로 해준 것에 기안한 것으로 판단된다. 그러므로, 본 연구의 결과를 응용할 경우 DMFC를 휴대용 전자기기에 적용함에 있어서 성능향상 및 가격경쟁력 확보에 도움을 줄 것으로 기대된다.

수근관 증후군의 임상증상정도와 감각신경전도검사와의 관계 (The Relationship between Clinical Grading of Carpal TunnelSyndrome and Sensory nerve Conduction Velocity)

  • 곽재혁;이동국
    • Annals of Clinical Neurophysiology
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    • 제6권2호
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    • pp.98-102
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    • 2004
  • Background: Carpal tunnel syndrome (CTS) is a common condition characterized by entrapment neuropathy of the median nerves. Clinical manifestations are the most important findings for diagnosis and assessment of therapeutic effects. But, objective indicators, such as electrophysiological findings, are also valuable supplementary tools. This study investigated the relationship between clinical grading and sensory nerve conduction velocity (SNCV) of median proper palmar digital nerve (MPPDN) in CTS patients. Method: This study was done on 90 upper limbs of 53 patients with CTS (men: 6, women: 47, age: 26~69 years, mean age; 52 years). Each SNCV of MPPDN was recorded with bar electrode using antidromic method. Each SNCV was compared with clinical grading of CTS. The clinical grades of CTS were designated as follows; group 1 is mild symptoms, 2 is moderate symptoms, and 3 is severe and longstanding symptoms. Result: In thumb, the SNCV of MPPDN was not different significantly between 3 groups (p=0.817). In the index finger, the SNCV was the fastest in the group 1, but faster in group 3 than in group 2 (p=0.001). In the middle and ring fingers, SNCV was decreased in higher clinical grading groups (middle finger: p=0.015, ring finger: p=0.044). Conclusion: SNCV of MPPDN of middle and ring finger correlated with the clinical grading of CTS. SNCV of index finger was the fastest in group 1. But SNCV of thumb did not correlate with the clinical grading of CTS.

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Bisphenol A ethoxylate diacrylate를 가교제로 사용한 PEO계 고분자 전해질의 전기화학적 특성 및 물성 (Electrochemical Characterization and Mechanical Properties of PEO-like Solid Polymer Electrolyte Based on Bisphenol A Ethoxylate Diacrylate)

  • 김석구;강영구;이희우;이창진
    • 폴리머
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    • 제25권4호
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    • pp.568-574
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    • 2001
  • Bisphenol A ethoxylate diacrylate를 가교제로 사용하여 PEO계 고분자 고체전해질을 제조하였으며, 이의 전기화학적 특성 및 기계적인 물성을 조사하였다. 제조된 고분자 고체전해질은 이온전도도를 높이기 위해 비휘발성의 PEGDMe [poly(ethylene glycol) dimethyl ether]를 가소제로 도입하였다. 첨가된 PEGDMe 함량이 높을수록 전기전도도는 증가하였다. 최대 이온전도도는 30에서 1.0 ${\times}$ 10$^{-3}$S/cm [Bisphenol A ethoxylate diacrylate ([EO]/[phenol]=15), PEGDMe250 80 wt%, LiCF$_3SO_3$]이었다. 제조된 고분자 전해질의 인장강도는 0.4 ~ 5 MPa이었으며 ${\phi}$=3 mm 봉에 대해 90$^{\circ}$ 및 180$^{\circ}$ 의 굽힘에도 균열을 발생하지 않았다. 리튬 기준전극에 대해 4.5 V 이상의 산화전위에도 전기화학적으로 안정하였다.

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0.5 mm 이내의 두께를 갖는 4층 구조의 스마트 윈도우에 적용되는 전기변색 ECD(electro-chromic device) 필름 제조 및 특성 (Characteristics of an electrochromic ECD (electro-chromic device) film in applications for smart windows with a 4-layer structure, a thickness of 0.5 mm)

  • 김남일;김극태
    • 한국결정성장학회지
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    • 제34권1호
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    • pp.16-21
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    • 2024
  • 전기변색(electrochromic devices, ECD) 방식을 이용하여 외부 전압 인가에 의해 착색된 상태에서 투명한 상태로 색 변화를 일으킬 수 있는 필름 형태의 스마트 윈도우를 제조하였다. 기존 유리 대신 투명 PET 필름을 기재로 사용하였고 ITO/Ag/ITO 전극층, WO3/TIC2 유기변색층, Nafion 전해질층을 차례로 도입한 이후 합지 공정을 통하여 총 두께가 50 ㎛ 정도인 다층 박막 ECD 모듈을 제조하였다. 길이가 80 mm 이상인 대면적의 ECD 모듈을 제조하기 위하여 스퍼터링, 바코팅, 열압축 공정을 최적화하였다. 보통 상태에서 54 % 수준의 투과율을 보였으나 DC 3.5 V의 전압을 인가했을 때 24 %까지 떨어졌으며 색 변화는 육안으로도 확인할 수 있었다. 가역적인 색 변화에 의해 외부 태양광을 선택적으로 차단할 수 있으며 냉난방에 필요한 에너지 저감 측면에서 효과적일 것으로 예상된다.

에폭시 개질 한 다관능 아크릴레이트를 포함하는 충격 저항성이 향상된 불포화폴리에스터 SMC (Sheet Molding Compound) 소재제조 및 그의 물성연구 (Improving Charge Injection Characteristics and Electrical Performances of Polymer Field-Effect Transistors by Selective Surface Energy Control of Electrode-Contacted Substrate)

  • 장정범;김태희;김혜진;이원주;서봉국;김용성;김창윤;임충선
    • 접착 및 계면
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    • 제21권3호
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    • pp.101-106
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    • 2020
  • 본 연구에서는 에폭시 수지를 개질 한 변성 아크릴레이트를 합성하였으며, 이를 기존의 유리 섬유 복합소재에 사용하는 SMC 조성물에 5 phr - 15 phr을 첨가하여 SMC 소재를 제조하였다. SMC 프리프레그를 고온고압 (150 ℃, 10 bar)에서 컴프레션 몰딩방법으로 성형하여 유리섬유 복합소재를 제조하였으며, 제조된 복합소재를 가공하여 인장강도, 충격강도 등의 기계적 물성을 연구하였다. 실험 결과 합성된 변성 아크릴레이트를 5 phr을 포함하는 복합소재가 합성 아크릴레이트를 포함하지 않는 binder 샘플보다 인장강도는 약 20%, 충격강도는 약 12% 향상함을 보였으며, 이는 합성 아크릴레이트가 폴리에스터와 반응할 수 있는 4개의 아크릴 기를 가짐으로써 가교반응을 강하게 하면서 기계적 강도가 향상됨을 확인하였다.