• Title/Summary/Keyword: Electrochemical polarization test

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THE ELECTROCHEMICAL STUDY ON CORROSION RESISTANCE OF VARIOUS DENIAL MAGNETIC ATTACHMENTS (수종 치과용 자석유지장치의 부식저항성에 대한 전기화학적 연구)

  • Sohn Byoung-Sup;Chang Ik-Tae;Heo Seong-Joo;Keak Jai-Young
    • The Journal of Korean Academy of Prosthodontics
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    • v.39 no.4
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    • pp.336-350
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    • 2001
  • The purpose of this study was to investigate corrosion tendency and to compare corrosion resistance of three dental magnetic attachments and its keeper alloy by coercive, electrochemical method. By using petentiodynamic polarization technique, magnetic elements and its keeper alloy of Magfit EX600 system(MF, MFK), Dyna ES regular system(DN, DNK) and Shiner SR magnet system(SR, SRK) were corroded electrochemically in 0.9% NaCl electrolytic solution. Open-circuit potential and anodic polarization curve was measured with Potentiostat(model 273 EG&E) and polarization curve was created by current density per square area following scanning of increased series of voltage in the rate of 1.0mV per second. Before and after electrochemical corrosion, the surface roughness test was done. Thereafter the change of mean surface roughness value(Ra) and mean peak value(Rt) of surface roughness was compared one another. In order to observe the corroded surface of each specimen, metallurgical light microscopic(${\times}37.5$) and scanning electron microscopic view(SEM ${\times}100$) was taken and compared one another. Conclusion is followings. 1. All of six covering metal of dental magnetic attachments and its keeper alloy were corroded in various degree after electrochemical corrosion. 2. The corrosion resistance of which used in this experiment is the following in high order; DNK, MFK, DN, MF, SRK and SR. 3. Especially Shiner magnet system and its keeper alloy were more severely corroded after electrochemical corrosion and the change of Ra Rt value were more increased than others. 4 Metallurgical and scanning electron microscopic view showed the pitting corrosion tendency of all experimental alloy but DNK and SR. 5. Covering metal of magnet was more corroded than its keeper alloy.

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Electrochemical Approach on the Corrosion During the Cavitation of Additive Manufactured Commercially Pure Titanium (적층가공 방식으로 제조된 CP-Ti의 캐비테이션 중 부식에 대한 전기화학적 접근)

  • Kim, K.T.;Chang, H.Y.;Kim, Y.S.
    • Corrosion Science and Technology
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    • v.17 no.6
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    • pp.310-316
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    • 2018
  • The effect of passive film on corrosion of metals and alloys in a static corrosive environment has been studied by many researchers and is well known, however few studies have been conducted on the electrochemical measurement of metals and alloys during cavitation corrosion conditions, and there are no test standards for electrochemical measurements 'During cavitation' conditions. This study used commercially additive manufactured(AM) pure titanium in tests of anodic polarization, corrosion potential measurements, AC impedance measurements, and repassivation. Tests were performed in 3.5% NaCl solution under three conditions, 'No cavitation', 'After cavitation', and 'During cavitation' condition. When cavitation corrosion occurred, the passive current density was greatly increased, the corrosion potential largely lowered, and the passive film revealed a small polarization resistance. The current fluctuation by the passivation and repassivation phenomena was measured first, and this behavior was repeatedly generated at a very high speed. The electrochemical corrosion mechanism that occurred during cavitation corrosion was based on result of the electrochemical properties 'No cavitation', 'After cavitation', and 'During cavitation' conditions.

A Study on the Crevice Corrosion Behavior of Chromium Plating (크롬도금의 틈부식 거동에 관한 연구)

  • 곽남인;임우조
    • Journal of the Korean institute of surface engineering
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    • v.36 no.4
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    • pp.324-328
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    • 2003
  • This study was made on the crevice corrosion behavior of chromium plating in fresh water. Under the various crevice, the electrochemical polarization test of chromium plating was carried out. Results are discussed In terms of corrosion potential, polarization resistance, corrosion current density and cathodic control of chromium plating.

Study on the characteristics of acid resistance and thermal shock for epoxy coatings (에폭시계 코팅재의 내산열충격 특성에 관한 연구)

  • Lee, Sang-Yeal;Yun, Byoung-Du
    • Journal of the Korean Society of Fisheries and Ocean Technology
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    • v.43 no.4
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    • pp.362-369
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    • 2007
  • This paper was studied on the characteristics of acid resistance and thermal shock for epoxy coatings in the strong acidic environment. The exhaust gas system, such as a air preheater, desulfurization equipment, for industrial boiler is damaged by dew point corrosion. To protect the acid corrosion, the coating using nonmetal was applied. The electrochemical polarization test, acid resistance and thermal shock test for epoxy coatings were carried out. And the acid resistance and thermal shock characteristics, aspect, and electrochemical anti-corrosion characteristics for epoxy coatings in the strong acidic environment were considered. The main results are as followings: As the epoxy glass flake coating by acidic thermal shock was damaged to the crack, blistering and elution etc., the current density of epoxy glass flake coating is high. But the damage of epoxy metal complex coating by acidic thermal shock was not occurred. Therefore the characteristics of acid resistance and thermal shock for epoxy metal complex coating is better than those for epoxy glass flake coating.

The Effect of Acidic Environments on the Corrosion-Wear of Cr Plating (크롬도금의 부식-마멸에 미치는 산성환경의 영향)

  • 곽남인;임우조
    • Tribology and Lubricants
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    • v.19 no.4
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    • pp.211-216
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    • 2003
  • This paper was studied on the corrosion and corrosion-wear behavior of chromium (Cr) plating in the acidic environments. In the various pH of acidic solutions, the electrochemical polarization test and wear-corrosion test of Cr plating were carried out. And thus potential, corrosion current density and corrosion-wear loss behaviour of Cr plating are investigated.

A study on the squeeze casting of Al-7.0Si-0.4Mg alloy for fuel system parts

  • Kim Soon-Ho;Kim Seong-Soo
    • International Journal of Precision Engineering and Manufacturing
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    • v.6 no.3
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    • pp.56-59
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    • 2005
  • Aluminum alloy casting is gaining increased acceptance in automotive and electronic industries and especially, squeeze casting is the most efficient method of mass manufacturing of such parts. In this study, the microstructures and mechanical properties of Al-7.0Si-0.4Mg(AC4C) alloy fabricated by squeeze casting process for development of fuel system parts (fuel rail) are investigated. The microstructure of squeeze cast specimen was composed of eutectic structure aluminum solid solution and $Mg_2Si$ precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg alloy was 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy had good corrosion resistance in electrochemical polarization test.

A Study on the Squeeze Casting of Al-7.0Si-0.4Mg Alloy for Fuel System Parts (Al-7.0Si-0.4Mg 합금 자동차 연료계 부품의 스퀴즈 캐스팅에 관한 연구)

  • 김순호
    • Journal of the Korean Society for Precision Engineering
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    • v.20 no.12
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    • pp.48-54
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    • 2003
  • Alumium alloys casting are gaining increased acceptance in the automotive and electronic industeries and squeeze casting is the most efficient method of manufacturing such mass produced parts. This study has been investigated the microstructures and mechanical properties of Al-7.0Si-0.4Mg (AC4C) alloy fabricated by squeeze casting process for development of Fuel system Parts (Fuel rail). The microstructure of squeeze casted specimen were composed of eutectic structure Alumimim solid solution and $Mg_2$Si precipitates. The tensile strength of as-solid solution treatment Al-7.0Si-0.4Mg ahoy revealed 298.5MPa. It was found that Al-7.0Si-0.4Mg alloy have good corrosion resistance in electrochemical polarization test.

Study on the behavior of the Erosion-Corrosion for Ni-Cr Alloy Sprayed Coating in the Marine Environment (해양환경 중에서 Ni-Cr 용사피복재의 침식-부식 거동에 관한연구)

  • 이상열
    • Journal of Advanced Marine Engineering and Technology
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    • v.23 no.5
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    • pp.695-701
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    • 1999
  • Thermal sprayed Ni-Cr alloy coating on the carbon steel was carried out erosion-corrosion test and electrochemical corrosion test in the marine environment. THe erosion-corrosion behavior and electrochemical corrosion characteristics of substrate(SS400) and thermal sprayed Ni-Cr coating was investigated, The erosion-corrosion control efficiency of Ni-Cr coating to substrate was also estimated quantitatively.

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Mechanical and Electrochemical Characteristics in Welding with Robot on 6061-T6 Al Alloy for Al Ship (로봇으로 용접한 알루미늄 선박용 6061-T6 합금의 기계적, 전기화학적 특성)

  • Kim, Seong-Jong;Jang, Seok-Ki
    • Journal of Advanced Marine Engineering and Technology
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    • v.33 no.2
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    • pp.313-321
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    • 2009
  • The construction of fiber-reinforced plastic (FRP) boats is decreasing trend since the application of international regulations on the control of marine environmental pollution, which recommended the use of environmentally friendly materials. The aluminum alloy used with material for ship is a superior to FRP. It is environmental friendly, easy to recycle, and provides a high added value to fishing boats. However, the welding for Al alloy materials have many problems, such as deformation by welding heat and effect of the working environment. In this paper, it was carried out welding by robot with welding material of ER5183 and ER5556 on 6061-T6 Al alloy for ship. The mechanical and electrochemical characteristics evaluated for specimen welded by robot. The cathodic polarization trend for the base metal and welding metal showed the effects of concentration polarization due to oxygen reduction and activation polarization due to hydrogen generation. The hardnesses of welding zone and heat affected zone are lower than that of base metal. At the result of tensile test, the specimen welded with ER5183 presented excellent property compared with ER5556.

Analysis of electrochemical double-layer capacitors using a Natural Rubber-Zn based polymer electrolyte

  • Nanditha Rajapaksha;Kumudu S. Perera;Kamal P. Vidanapathirana
    • Advances in Energy Research
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    • v.8 no.1
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    • pp.41-57
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    • 2022
  • Electrochemical double-layer capacitors (EDLCs) based on solid polymer electrolytes (SPEs) have gained an immense recognition in the present world due to their unique properties. This study is about preparing and characterizing EDLCs using a natural rubber (NR) based SPE with natural graphite (NG) electrodes. NR electrolyte was consisted with 49% methyl grafted natural rubber (MG49) and zinc trifluoromethanesulfonate ((Zn(CF3SO3)2-ZnTF). It was characterized using electrochemical impedance spectroscopy (EIS) test, dc polarization test and linear sweep voltammetry (LSV) test. NG electrodes were made using a slurry of NG and acetone. EIS test, cyclic voltammetry (CV) test and galvanostatic charge discharge (GCD) test have been done to characterize the EDLC. Optimized electrolyte composition with NR: 0.6 ZnTF (weight basis) exhibited a conductivity of 0.6 x 10-4 Scm-1 at room temperature. Conductivity was predominantly due to ions. The electrochemical stability window was found to be from 0.25 V to 2.500 V. Electrolyte was sandwiched between two identical NG electrodes to fabricate an EDLC. Single electrode specific capacitance was about 2.26 Fg-1 whereas the single electrode discharge capacitance was about 1.17 Fg-1. The EDLC with this novel NR-ZnTF based SPE evidences its suitability to be used for different applications with further improvement.