• Title/Summary/Keyword: Electrochemical evaluation method

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A study on the application of electrochemical method for degradation evaluation (열화평가에 전기화학적 방법의 응용에 관한 연구)

  • Kwon, Jae-Do;Moon, Yun-Bae;Kim, Sang-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.1
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    • pp.44-51
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    • 1998
  • In order to develop the evaluation methods of degradation for the Ni-Cr-Mo-V steel, which is in use for turbine rotor in nuclear power plant, the degraded materials were prepared by simulated degradation methods. The result of impact test and fatigue crack growth test shows that the FATT(Fracture Appearance Transition Temperature) and fatigue crack growth rate increased with the increase of degradation. And the result of new electrochemical polarization test method was suggested for the evaluating FATT, fatigue crack growth exponent and coefficient C values based on the results of relationship between corrosion current density(Icorr) & FATT, and the m & C and Icorr.

A Corrosion Resistance Evaluation of Welded AISI 304 Stainless Steel by Electrochemical Methods. (전기화학적 방법에 의한 AISI 304 스테인리스강 용접부의 내식성 평가)

  • 백신영;김관휴
    • Journal of Advanced Marine Engineering and Technology
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    • v.14 no.1
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    • pp.83-89
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    • 1990
  • Electrochemical methods have been proposed as non-destructive, rapid and quantitative means for determining the degree of sensitization associated with Chromium depleted zones surrounding precipitates of Cr carbide and formation of secondary phase in stainless steel. In this study, the specimen of AISI 304 stainless steel and its welded sections, which welded by TIG, MIG, $CO_2$ and ARC, were tested corrosion resistance by electrochemical methods in 0.5N HCl and 1N $H_2SO_4$ with or without 0.01N KSCN. The results were confirmed that electrochemical methods could be used as a test method of corrosion resistance evaluation for the welded AISI 304 stainless steel.

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A Study on Recycle of Concreted Organic Waste water by Electroflotation Apparatus for Resource Recycle of Non-Metal (비금속 자원 재활용을 위한 전해부상 장치를 이용한 고농도 유기질 폐수의 재활용에 관한 연구)

  • Kim, Ki-Jun;Nam, Sang-Sung
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.4
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    • pp.653-658
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    • 2012
  • There is an increasing interest in the use of electrochemical methods for the food waste treatment. The technologies using the electrochemical method provide ideal tools for approaching industrial and food wastes problems. Unlike other chemical treatments, the electrochemical systems do not make the volume of the secondary waste increase. The electrochemical methods can be operated with electrochemical apparatus and inorganic agent allow selective separation and recovery and even quieter than others. This study concerns design factors, electrode construction and wastewater treatment process of the electrochemical apparatus. The experiment of color, COD and BOD removal is much effective in using electrochemical method with ultrasonication and ozonation.

A Study on Electrochemical Evaluation Method of Toughness Degradation for 12%Cr Steel (II) (12%Cr강 인성열화도의 전기화학적 평가법에 대한 연구(II))

  • Kim, Chang-Hui;Seo, Hyun-Uk;Yoon, Kee-Bong;Park, Ki-Sung;Kim, Seoung-Tae
    • Proceedings of the KSME Conference
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    • 2001.06a
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    • pp.268-273
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    • 2001
  • Fossil power plants operated in high temperature condition are composed of components such as turbine, boiler, and piping system. Among these components, turbine blades made with 12%Cr steel operate at a temperature above $500^{\circ}C$. Due to the long term service, turbine blades experience material degradation manifested by change in mechanical and microstructural properties. The need to make life assessment and to evaluate material degradation of turbine blade is strongly required but in reality, there is a lack of knowledge in defining failure mechanism and fundamental data for this component. Therefore, in making life assessment of turbine blade, evaluation of material degradation must be a priority. For this purpose, evaluation of toughness degradation is very important. The major cause of toughness degradation in 12Cr turbine blade is reported to be critical corrosion pitting induced by segregation of impurity elements(P etc.), coarsening of carbide, and corrosion, but the of materials for in-service application. In this study, the purpose of research is focused on evaluating toughness degradation with respect to operation time for 12%Cr steel turbine blade under high temperature steam environment and quantitatively detecting the degradation properties which is the cause of toughness degradation by means of non-destructive method, electrochemical polarization.

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Evaluation of the Corrosion Protective Property in Steel applying Spray Metal by using High-frequency Arc Metal Spray Method (고주파 아크 금속용사공법을 이용한 용사금속의 방식성능 평가)

  • Choe, Hong-Bok;Lee, Han-Seung
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2014.05a
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    • pp.94-95
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    • 2014
  • The purpose of this study is to evaluate the corrosion protective property of Al-Mg high-freqeuncy arc metal spray method in comparison to Zn-Sn and Zn-Al alloys by electrochemical method and CASS test. As a result, it appeared that Al-Mg alloy had very higher corrosion protective property through the electrochemical characteristic and the CASS test comparing with the other alloys.

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Corrosion Evaluation of Epoxy-Coated Bars by Electrochemical Impedance Spectroscopy

  • Choi, Oan-Chul;Park, Young-Su;Ryu, Hyung-Yun
    • International Journal of Concrete Structures and Materials
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    • v.2 no.2
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    • pp.99-105
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    • 2008
  • Southern exposure test specimens were used to evaluate corrosion performance of epoxy-coated reinforcing bars in chloride contaminated concrete by electrochemical impedance spectroscopy method. The test specimens with conventional bars, epoxy-coated bars and corrosion inhibitors were subjected 48 weekly cycles of ponding with sodium chloride solution and drying. The polarization resistance obtained from the Nyquist plot was the key parameter to characterize the degree of reinforcement corrosion. The impedance spectra of specimens with epoxy-coated bars are mainly governed by the arc of the interfacial film and the resistance against the charge transfer through the coating is an order of magnitude higher than that of the reference steel bars. Test results show good performance of epoxy-coated bars, although the coatings had holes simulating partial damage, and the effectiveness of corrosion-inhibiting additives. The corrosion rate obtained from the impedance spectroscopy method is equivalent to those determined by the linear polarization method for estimating the rate of corrosion of reinforcing steel in concrete structures.

An Electrochemical Evaluation of the Corrosion Property on the Welded Zone of Sea Water Pipe by each Welding Materials (용접 재료 별 해수 배관 용접부위의 부식 특성에 관한 전기화학적 평가)

  • Kim, Jin-Gyeong;Won, Chang-Uk;Moon, Kyung-Man
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2006.11a
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    • pp.185-188
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    • 2006
  • The sea water pipe of engine room in all kinds of ships is being surrounded with severe corrosive environment. Therefore it's leakage part due to corrosion is inevitably prevented by various welding method. In this case corrosion property of welded zone may be considerably different by each welding materials. In this study corrosion resistance of the welded zone of sea water pipe with some welding materials such as shielded metal arc welding materials, inert gas arc welding materials was investigated with electrochemical method.

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The Evaluation of 2-25Cr-lMo Steels Degradation by the Electrochemical Polarization Method (전기화학적 분극특성을 이용한 2.25Cr-lMo 강의 열화도 평가)

  • 김지수;현양기;이재도;오세규
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2001.05a
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    • pp.314-319
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    • 2001
  • Most parts of facilities in domestic petroleum plants and power plants are needed to be abandoned, repaired or replaced, because in Korea they were built in the 1960s and, they have been used under severe conditions and exposed corrosive environments. 2.25Cr- lMo steels have excellent high-temperature mechanical properties. Therefore, the material have been widely used as heat exchanger tubes, boiler headers and its tubes in such industries. But, those microstructural evolutions in high temperature such as precipitation and carbide coarsening give a reason to degrade the material. Especially, in case of this material, carbides induced embrittlement(CIE) is the primary reason for degrading mechanical properties at over 50$0^{\circ}C$. In this paper, we introduce a electrochemical polarization method for detecting CIE quantitatively.

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