• Restorative Dentistry and Endodontics
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• v.33 no.4
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• pp.377-388
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• 2008

The aim of the present study is to compare the corrosion tendency using two kinds of NiTi files in the various environmental conditions through the visual examination and electrochemical analysis. ProTaper Universal S2, 21 mm (Dentsply Maillefer, Ballaigues, Switzerland) and Hero 642, 0.06 tapers, size 25, 21 mm (Micromega, Besancon, France) rotary instruments were tested. The instruments were randomly divided into eighteen groups (n = 5) by the immersion temperature, the type of solution, the brand of NiTi rotary instrument and the presence of mechanical loading. Each file was examined at various magnifications using Scanning Electron Microscope (JEOL, Akishima, Tokyo, Japan) equipped with energy dispersive X-ray microanalysis (EDX). EDX was used to determine the components of the endodontic file alloy in corroded and noncorroded areas. The corrosion resistance of unused and used NiTi files after repeated uses in the human teeth was evaluated electrochemically by potentiodynamic polarization test using a potentiostat (Applied Corrosion Monitoring, Cark-in-Cartmel, UK). Solution temperature and chloride ion concentration may affect on passivity of NiTi files. Under the conditions of this in vitro study, the corrosion resistance is slightly increased after clinical use.

• Journal of the Korean Electrochemical Society
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• v.2 no.3
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• pp.138-143
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• 1999

Recently, miniaturization of large scale integrated circuits (LSI) and printed circuit board (PCB) have become essential with the downsizing of electronic devices. Gold electroplating is applied of conductivity wiring or terminals for improvement of conductivity and corrosion resistance. However, electroplating is not applicable since the circuits are becoming finer and denser. Accordingly, electroless plating is recently highly attractive method because of the simplicity of the operation requiring no external source of current and no elaborate equipment. In this work, we tried to develop a plating technique on electroless Ni/Au plating. First, the electroless Ni plating was deposited on the PCB with agitation in the bath at $85^{\circ}C$. Then the Au layer was deposited on the Ni layer surface by same method at $90^{\circ}C$. The bonderability were tested in order to evaluate the stability of the electroless Ni/Au by gold wire or solder ball test.

• Corrosion Science and Technology
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• v.19 no.1
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• pp.16-22
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• 2020

It is important to realize that benzoate was intercalated into hydrotalcite (HTC-Bz) by the co-precipitation method. In this case, acrylic coating with 0.5 wt% HTC-Bz was deposited on carbon steel using the spin coating method. Next, the HTC-Bz structure was characterized by Field emission scanning electron microscopy (FESEM), X-ray diffraction (XRD), and Fourier transform infrared spectroscopy (FT-IR). In fact, an ultraviolet vision spectroscopy (UV-Vis) was used to determine the benzoate content in HTC-Bz, and the UV absorption ability of HTC-Bz. Using electrochemical techniques, water contact angle measurement, and thermal-gravimetric analysis, we compared the protective properties before and after QUV test, hydrophobicity and the thermal stability of acrylic coating containing HTC-Bz. The obtained results showed that HTC-Bz with a plate-like structure was successfully synthesized; benzoate was intercalated into the interlayer of hydrotalcite with a concentration of 28 wt%. Additionally, it was noted that HTC-Bz has an UV absorption peak at 225 nm. In conclusion, the addition of HTC-Bz enhanced the UV stability, hydrophobicity and the thermal stability of acrylic coating.

• Journal of Welding and Joining
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• v.16 no.6
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• pp.59-68
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• 1998

In this study, effects of solidification modes (primary $\delta$-ferrite, primary ${\gamma}$-austenite) on the pit initiation and propagation in the 304L and 316L austenitic stainless steel weld metals were investigated. The solidification mode of weld metal was controlled by the addition of nitrogen to Ar shielding gas. Through the electrochemical experiments (potentiodynamic anodic polarization and potentiostatic time-current transient test) and metallographic examination (microstructure and elemental distribution), the following results were obtained. The more the volume content of nitrogen in the shielding gas were, the lower critical current density for passivity was observed. In comparison with weldments solidified through the primary $\delta$-ferrite solidification mode and the primary ${\gamma}$-solidification mode, the former showed higher critical pitting potential and a longer incubation time for stable pit initiation than the latter. However, in the pit propagation stage the former exhibited a faster dissolution rate than the latter. These results were believed to ee related to the distribution of alloying elements such as Cr, Mo, Ni and S.

• Journal of the Korean Institute of Gas
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• v.9 no.4 s.29
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• pp.6-10
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• 2005

This paper was studied on the damage behavior of stainless steel (STS 304) for gas boiler with specific resistance. The electrochemical polarization test of STS304 for gas boiler was carried out. And the anodic polarization and damage aspect, such as pitting corrosion, was considered. With being low specific resistance, the passive current density of STS 304 increases, passive region and pitting potential is low. Also, the patting aspect of STS304 In specific resistance $74{\Omega}{\cdot}m$ water little appears, the pitting number increases and the damage behavior, such as pitting aspect, gradually grow bigger with being low specific resistance.

• Journal of the Korean Society of Hazard Mitigation
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• v.10 no.1
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• pp.15-22
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• 2010

Chloride-induced corrosion of steel bars in concrete exposed to marine environments has become one of the major causes of deterioration in many important facilities made of reinforced concrete. A study on chloride penetration in concrete has developed through long period exposure test along seawater, assesment of chloride ion diffusion by electrochemical techniques and so on. However, reasonable and exclusive chloride penetration model considering concrete material properties with mixture, degree of hydration, binding capacity has not been established. Therefore, in this paper, chloride penetration analysis of non-steady state is accomplished with material properties of concrete. Comparing with the results of analysis and chloride ponding test, we could accept the effect of binding capacity on chloride penetration in concrete and these results could be applied to a service life prediction of R.C. structures submerged in seawater. Therefore, there are 20~40% differences of service life to SHRP prediction.

• Journal of Conservation Science
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• v.30 no.1
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• pp.95-101
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• 2014

Silver objects tarnish with black from reaction with sulfurous acid or hydrogen sulfide of atmospheric. Blackening of silver objects results from formation of silver sulfide($Ag_2O$) on the surface. Silver sulfide usually is usually removed by conservation treatment. There are several cleaning methods such as chemical, electrochemical and micro-abrasion cleaning, but all of them consume silver. This study investigated the safe and effective parameter of laser cleaning by test on silver coupons. Laser cleaning is a selective process for the removal of specific substances. At first, laser cleaning applied to plain silver coupons, which were not corroded, to find out the safe range of laser energy density. From results, plain silver coupons were not changed at 1064nm below $4.00J/cm^2$ and at 532nm below $2.39J/cm^2$. The corrosion layer(silver sulfide) of artifical corroded silver coupons was removed at 1064nm with $2.39J/cm^2$ by 5~10 pulses and at 532nm with $1.19J/cm^2$ by 5~10 pulses. The removal thickness of corrosion layer was about 13-25nm per a laser pulse using AES analysis. In addition, laser cleaning tested the tarnish silver rings based on the results of silver coupons. As a result of test, the black surface were clean successfully and gave luster of silver, which showed the application possibility of laser cleaning for silver objects.

• Journal of Advanced Marine Engineering and Technology
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• v.38 no.7
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• pp.883-889
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• 2014

It is generated for cavitation erosion due to the local static boiling by pressure differentials in high speed rotating fluid environment. The cavitation is influenced by various elements such as pressure, velocity, temperature, pH of fluid and medium. In particular, the damage of material is accelerated due to the electrochemical corrosion by $C1^-$ and cavitation erosion due to cavities in seawater. In this paper, hence, it investigated for martensite stainless steel the damage behavior with applied current density and cavitation time in natural seawater solution. Less damage depth at the cavitation condition was observed than static condition as a result of galvanostatic experiment. Furthermore, it was shown that dramatic increase of weightloss, damage rate and damage depth after 3 hour of cavitation test.

• Journal of the Korean Institute of Gas
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• v.10 no.1 s.30
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• pp.43-47
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• 2006

This study attempted to examine how the hydrogen embrittlement susceptibility of the STS 444 stainless steel varies under different welding conditions and how its effect on hydrogen embrittlement differs by the impressed current density levels. For doing so, U bend test specimens was used to impress the current density at 5,10, 15, and 20 $mA/cm^2$ in the $0.5M\;H_2SO_4+0.001M\;As_2O_3$ solution with an electrochemical corrosion tester. The hydrogen embrittlement was assessed by observing the time to failure, and then the microphotographs of metal structures were compared to investigate the metal- related structural properties. The study findings suggest that the effect on hydrogen embrittlement for the STS 444 steel significantly depends on both the welding conditions, or variations in the amount of shield gas, and the levels of current density. In particular, as the impressed current density increases, the hydrogen embrittlement increases rapidly.

• The Journal of Advanced Prosthodontics
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• v.6 no.6
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• pp.512-520
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• 2014

PURPOSE. The purpose of this study was to assess the surface characteristics and the biocompatibility of zirconium (Zr) coating on Ti-6Al-4V alloy surface by radio frequency (RF) magnetron sputtering method. MATERIALS AND METHODS. The zirconium films were developed on Ti-6Al-4V discs using RF magnetron sputtering method. Surface profile, surface composition, surface roughness and surface energy were evaluated. Electrochemical test was performed to evaluate the corrosion behavior. Cell proliferation, alkaline phosphatase (ALP) activity and gene expression of mineralized matrix markers were measured. RESULTS. SEM and EDS analysis showed that zirconium deposition was performed successfully on Ti-6Al-4V alloy substrate. Ti-6Al-4V group and Zr-coating group showed no significant difference in surface roughness (P>.05). Surface energy was significantly higher in Zr-coating group than in Ti-6Al-4V group (P<.05). No difference in cell morphology was observed between Ti-6Al-4V group and Zr-coating group. Cell proliferation was higher in Zr-coating group than Ti-6Al-4V group at 1, 3 and 5 days (P<.05). Zr-coating group showed higher ALP activity level than Ti-6Al-4V group (P<.05). The mRNA expressions of bone sialoprotein (BSP) and osteocalcin (OCN) on Zr-coating group increased approximately 1.2-fold and 2.1-fold respectively, compared to that of Ti-6Al-4V group. CONCLUSION. These results suggest that zirconium coating on Ti-6Al-4V alloy could enhance the early osteoblast responses. This property could make non-toxic metal coatings on Ti-6Al-4V alloy suitable for orthopedic and dental implants.