• 제목/요약/키워드: Electrochemical conversion

검색결과 256건 처리시간 0.03초

연료전지 - 그 비전과 전망 (Why Fuel Cell ? - Its Vision and Prospects)

  • 김건택;정진엽
    • 유체기계공업학회:학술대회논문집
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    • 유체기계공업학회 2001년도 유체기계 연구개발 발표회 논문집
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    • pp.367-372
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    • 2001
  • A fuel cell is an electrochemical energy conversion device tint converts hydrogen and oxygen into electricity and heat for hot water and heating room A fuel cell provides a DC voltage tint can be used to power motors, lights or any number if electrical appliances. There are several different types if fuel cells, each using a different chemistry. Some types if fuel cells show promise for use in DC (distributed generation) because fuel cell is very clean and efficient energy device. CETI (Clean Energy Technologies, Inc.) is developing PEMFC and DMFC for residential power generation, portable and battery. It is anticipated tint RPG is advantageous over current power generation by utility In terms if economics assuming the lifetime of major components is at least five years.

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강제 대류를 통한 열소산 구조물의 위상최적화 (Topological Optimization of Heat Dissipating Structure with Forced Convection)

  • 윤길호
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.408-409
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    • 2008
  • This paper presents a new development for topology optimization of heat-dissipating structure with forced convection. To cool down electric devices or machines, two types of convection models have been widely used: Natural convection model with a large Archimedes number and Forced convection with a small Archimedes number. Nowadays, many engineering application areas such as electrochemical conversion device or fuel cell devices adopt the forced convection to transfer generated heat. Therefore, to our knowledge, it becomes an important issue to design flow channels inside which generated heat transfer. Thus, this paper studies optimal topological designs considering fluid-heat interaction. To consider the effect of the advection in the heat transfer problem, the incompressible Navier-stokes equation is solved. This paper numerically studies the coupling phenomena and presents optimal channel design considering forced convection.

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SBM 고분자중합 바인더가 사용된 $TiO_2$ 광전극의 전기화학적 특성 (The electrochemical properties of $TiO_2$ photoanode using SBM co-polymer binders)

  • Jin, En-Mei;Park, Kyung-Hee;Gu, Hal-Bon
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.360-361
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    • 2008
  • A new kind of SBM co-polymer binder as styrene, n-butyl acrylate, and methacrylic acid (SBM) monodisperse co-polymer binder materials basted on $TiO_2$ pastes was synthesized and this $TiO_2$ pastes were applied of dye-sensitized solar cells (DSSCs). The SBM co-polymer binder was prepared by soap-free emulsion copolymerization using a PEG-EEM macromonomer. The photoanodes were characterized by morphology investigated from field emission scanning electron microscopy (FE-SEM). The photoelectrochemical properties of the thin films and the performance of DSSCs were measured by photovoltaic-current density. DSSC based on the emulsion co-polymer binder was obtained conversion efficiency of 7.1% under irradiation of AM 1.5($100mWcm^{-2}$).

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결정질 실리콘 태양전지의 반사방지막 비교 분석 (Comparison & Analysis of Anti-Reflection Coatings for Crystalline Si Solar cells)

  • 조경연;이지훈;이수홍;이규상
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2008년도 하계학술대회 논문집 Vol.9
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    • pp.221-222
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    • 2008
  • In Crystalline Si solar cells, Anti-Reflection Coating is contribute to improvement in energy conversion efficiency due to decrease of optical loss and recombination owing to surface passivation. Porous Si is formed electrochemical etching that uses chemical solution and anodization etching. So It gives that advantage in rapid process time and without high cost equipment. In this paper, We compare Porous Si with $SiO_2$/SiNx ARC and analyze that by anti-reflection coating.

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Composite Ni-TiO2 nanotube arrays electrode for photo-assisted electrolysis

  • Pozio, Alfonso;Masci, Amedeo;Pasquali, Mauro
    • Advances in Energy Research
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    • 제3권1호
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    • pp.45-57
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    • 2015
  • This article is addressed to define a new composite electrode constituted by porous nickel and an array of highly ordered $TiO_2$ nanotubes obtained by a previous galvanostatic anodization treatment in an ethylene glycol solution. The electrochemical performances of the composite anode were evaluated in a photo-electrolyser, which showed good solar conversion efficiency with respect to the UV irradiance together with a reduction of energy consumption. Such a combination of materials makes our system simple and able to work both in dark and under solar light exposure, thus opening new perspectives for industrial-scale applications.

고체전해질 전지 반응기를 이용한 일산화탄소의 제거 (Removal of carbon monoxide using a solid electrolyte cell reactor)

  • 신석재;오인환
    • 한국안전학회지
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    • 제11권3호
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    • pp.112-118
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    • 1996
  • When fossil fuels are burned they produce CO gas because of incomplete combustion. If the CO gas reacts with the hemoglobin in the red blood cells, it may result in death or sequelae. Generally, the CO gas is eliminated in the form of the $$$CO_2$ gas by the oxidation reaction over the platinum catalyst. In this study, the electrochemical CO removal was investgated by using the solid electrolyte cell reactor, the type of which was represented as reactants$/Pt/Y_2O_3-ZrO_2/Pt/Air$. If the overpotential was applied to the platinum working electrode, the conversion could be changed with the overpotential applied. It was found that the oxidation rate could be increased 2.8 times higher than that of the normal condition, i. e. under open circuit conditions when $P_{co}/P_{O_2}$ was 0.5 and overpotential was 0.9V. From these results, it is concluded that the reactor used in this study is more efficient than conventional catalytic reactors.

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DSSC광전극의 나노구조 제어 및 투명전극 소재 개발

  • 장현석
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2009년도 제38회 동계학술대회 초록집
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    • pp.28-28
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    • 2010
  • Photoelectrochemical solar cells such as dye-sensitized cells (DSSCs), which exhibit high performance and are cost-effective, provide an alternative to conventional p-n junction photovoltaic devices. However, the efficiency of such cells plateaus at 11-12%, in contrast to their theoretical value of 33%. Improvements in efficiency can only occur through a fundamental understanding of the underlying physics, materials, and device designs of DSSCs. A photoelectrode consisting of semiconducting oxide nanoparticles and a transparent conducting oxide electrode (TCO) is a key component of DSSC and design of photoelectrode materials is one of promising strategies to improving energy conversion efficiency. We introduce monodisperesed $TiO_2$ nanoparticles prepared by forced hydrolysis method and their superiority as photoelectrode materials was characterized with aids of optical and electrochemical analysis. Multi-layered TCO materials are also introduced and their feasibility for use as photoelectrodes is discussed in terms of optical absorption and charge collecting properties.

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MICROSTRUCTURE AND ELECTROCHEMICAL CHARACTERISTICS OF ELECTRODEPOSITED Zn-Ni ALLOY COATINGS

  • Short, N.R.;Hui, Wen-Hua;Dennis, J.K.
    • 한국표면공학회지
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    • 제32권3호
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    • pp.281-288
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    • 1999
  • Electrodeposited Zn-Ni alloy coatings are of particular interest for improving the corrosion resistance of steel in a number of enviornments. Of particular interest is the relationship between composition, structure and corrosion rate. This paper firstly reviews the literature regarding composition-structure relationships of Zn-Ni electrodeposits and compares them with the equilibrium phase diagram. Secondly, research was carried out on a wide range of coatings which were produced in the laboratory and their structure and corrosion rates determined. It was found that unambiguous identification of phases from XRD data can be difficult. Maximum corrosion resistance of deposits is obtained at 12-13% Ni, with a $\gamma$ phase structure and predomination of (600) and (411) reflections. Compatibility is important with regard to chromate conversion coatings.

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Photocatal~ic Hydrogen Evolution with Platinum Loaded Cadmium-Iron-Sulfide Mixed Crystal Powders in Aque-ous Media

  • 조철래;박세진;김하석
    • Bulletin of the Korean Chemical Society
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    • 제21권8호
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    • pp.805-808
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    • 2000
  • Mixed crystal powders based on Cd,Fe, and S have been synthesized by varying the ratio of CdS and $FeS_2in$ order to find a suitable material usefuI for the effectivc conversion of solar energy. Hydrogen gas was evolved only with CdS/Ptby photocatal ytic reaction under white light in an aqueous 1 M sodiumsulfite solution. From electrochemical studies of semiconductor electrodes. itwas shown that the onset potential shifted to the positive direction and that the bandgap energy also decreased as the molar ratio of Fe increased. A hydrogen evolution mechanism in terms of the conduction band potential and hydrogen evolution potential is proposed.

호흡 검출 시스템을 위한 초소형 센서 인터페이스 회로 (Miniaturized Sensor Interface Circuit for Respiration Detection System)

  • Jo, Sung-Hun
    • 한국정보통신학회논문지
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    • 제25권8호
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    • pp.1130-1133
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    • 2021
  • In this paper, a miniaturized sensor interface circuit for the respiration detection system is proposed. Respiratory diagnosis is one of the main ways to predict various diseases. The proposed system consists of respiration detection sensor, temperature sensor, and interface circuits. Electrochemical type gas sensor using solid electrolytes is adopted for respiration detection. Proposed system performs sensing, amplification, analog-to-digital conversion, digital signal processing, and i2c communication. And also proposed system has a small form factor and low-cost characteristics through optimization and miniaturization of the circuit structure. Moreover, technique for sensor degradation compensation is introduced to obtain high accuracy. The size of proposed system is about 1.36 cm2.