• Title/Summary/Keyword: Electrochemical Simulation

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Design of an Adaptive Controller for Steady Voltage Characteristics of the Fuel Cell (연료전지의 정전압 특성을 위한 적응제어기 설계)

  • Hyun, Keun-Ho
    • Proceedings of the KIEE Conference
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    • 2007.11c
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    • pp.51-54
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    • 2007
  • In this paper, the dynamic models of a SOFC are rearranged. It consists of electrochemical model, thermal model, voltage equation and several loss equations. Experiment results of the real SOFC system are shown to evaluate the steady voltage characteristics. Control problems on tracking steady voltage by air flow is discussed and an adaptive controller is designed to withstand to the variation of stack current. Simulation is done to prove the solution of control algorithms.

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Dynamic Modelling and Control of Solid-Oxide Fuel Cell (고체산화 연료전지의 동특성 모델링과 제어)

  • Hyun, Keun-Ho;Son, In-Hwan;Ka, Chul-Hyun
    • Proceedings of the KIEE Conference
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    • 2005.07d
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    • pp.2516-2518
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    • 2005
  • In this paper, the dynamic models of SOFC are suggested. It consists of electrochemical model, thermal model, voltage equation and several loss equations. Control problem on tracking steady voltage by air flow is discussed and an adaptive controller is designed to withstand to the variation of stack current. Simulation is done to prove the solution of control algorithms.

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Introduction of Computer Simulation for BIW Electrocoating Process (BIW 전착도장에서의 컴퓨터 시뮬레이션 적용사례)

  • Sohn, DaeHong;Jung, HiZean;Ahn, SeungHo;Kim, ByungSu;Kim, JungYeon;Choi, ByungSam
    • Corrosion Science and Technology
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    • v.15 no.2
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    • pp.78-83
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    • 2016
  • The e-coating to inhibit induced corrosion can deposit a coating not only on the exterior surface but also on the inside of whole metallic components of body-in-white (BIW). But it is difficult to deposit paint films on the inside area because metallic components are multi layered. It may cause shortness of e-coating thickness. The only way to properly verify e-coating thickness is by performing the use of tear-down prototypes. When paint films' thickness is inadequate, a structural modification on each metallic component is needed. Verification of the thickness improvement for a structural modification requires much manual effort and leads to increasing development time. Recently, the simulation technology has been developed to predict the e-coating thickness in e-coating field. By applying the simulation to BIW, improvement in paint thickness quality and shortening of development period are expected. The paper explains a validated solution that allows simulating the effect of design changes to the e-coating thickness and current density, thereby delivering results within a time frame of a few days.

Analysis of Dynamic Performance of Solid Oxide Fuel Cells (고체산화물 연료전지의 동적 성능 특성 해석)

  • Yang, Jin-Sik;Sohn, Jeong-L.;Ro, Sung-Tack
    • Proceedings of the KSME Conference
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    • 2004.11a
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    • pp.1652-1657
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    • 2004
  • Model for the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reaction in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power and chemical compositions with different levels of load changes are investigated.

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Equifield line simulation and ion migration prediction for concrete under 2-D electric field

  • Liu, Chih-Chien;Kuo, Wen-Ten;Huang, Chun-Yao
    • Computers and Concrete
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    • v.12 no.4
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    • pp.431-442
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    • 2013
  • This study attempted to find a proper method applicable to simulating practical equifield lines of two-dimensional Accelerate Lithium Migration Technique (ALMT), and evaluate the feasibility of using the theoretical ion migration model of one-dimensional ALMT to predict the ion migration behavior of two-dimensional ALMT. The result showed that the electrolyte or carbon plate can be used as matrix to draw equifield line graph similar to that by using mortar as matrix. Using electrolyte electrode module for simulation has advantages of simple production, easy measurement, rapidness, and economy. The electrolyte module can be used to simulate the equifield line distribution diagram in practical two-dimensional electrode configuration firstly. Then, several equifield line zones were marked, and several subzones under one-dimensional ALMT were separated from various equifield line zones. The theoretical free content distribution of alkali in concrete under two-dimensional electric field effect could be obtained from duration analysis.

Computer Modeling of the Power Generation System Using Polymer Electrolyte Fuel Cell (고분자 전해질형 연료전지 발전 시스템의 전산모사)

  • Baek, Young-Soon
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.5
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    • pp.460-466
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    • 2008
  • In this study, a computer modeling work has been performed for the power generation system using polymer electrolyte fuel cell with Aspen Plus general purpose chemical process simulator. Stoichiometric reactor module was used for the modeling of reformer for the production of hydrogen. For the modeling of the electrochemical reaction, Gibbs reactor module built-in Aspen Plus was utilized. SRK equation of state model was selected for the proper simulation of the overall fuel cell system.

Beams affected by corrosion influence of reinforcement placement in the cracking

  • Ortega, Nestor F.;Rivas, Irene E.;Aveldano, Raquel R.;Peralta, Maria H.
    • Structural Engineering and Mechanics
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    • v.37 no.2
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    • pp.163-175
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    • 2011
  • The results of experimental and numerical investigations on reinforced concrete beams, with different longitudinal rebars affected by corrosive processes are presented in this paper. Different diameters and/or different distributions of longitudinal rebars were employed keeping constant the total section in each analyzed case, (maintaining a constant stirrup diameter and distribution). The rebars were subjected to accelerated corrosion in the experimental study. Electrochemical monitoring of the process, periodic measuring of the cover cracking and gravimetry of the rebars were performed through the test. Some building recommendations are obtained in order to be considered by designers of concrete structures. The numerical simulation was carried out through the application of the Finite Element Method (FEM), employing plane models, and using linear-elastic material model. The cracking process was associated with the evolution of the tensile stresses that were originated. This numerical methodology allows the monitoring of the mechanical behavior until the beginning of the cracking.

A Study on the Dynamic Performance Behavior of Solid Oxide Fuel Cells with Stepwise Load Changes (갑작스런 부하 변동에 따른 고체산화물 연료전지의 동적 성능 거동 특성에 관한 연구)

  • Sohn Jeong Lak;Ro Sung Tack;Yang Jin Sik
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.4 s.235
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    • pp.477-484
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    • 2005
  • Model fer the dynamic simulation of dynamic behaviors of a solid oxide fuel cell (SOFC) is provided. This model is based upon (1) coupled mass and heat transfer characteristics and (2) important chemical reactions such as electrochemical and reforming reactions in high temperature fuel cells such as SOFC. It is found that the thermal inertia of solid materials in SOFC plays an important role to the dynamic behavior of cell temperature. Dynamic characteristics of cell voltage, power, and chemical compositions with different levels of load change are investigated.

Revised Reversible and Totally Irreversible Zones for the Linear Sweep Voltammetry at a Planar Electrode

  • Kwak Juhyoun
    • Bulletin of the Korean Chemical Society
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    • v.15 no.1
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    • pp.57-63
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    • 1994
  • Digital simulation program for one-dimensional geometric systems of electrochemical phenomena was developed. The accuracy of the digital simulation is discussed by comparing with the known solutions. Applying this program to the linear sweep voltammetry at a planar electrode for the electrode reaction, 0 + ne${\to}$R, the accurate current functions for the reversible and totally irreversible charge transfer systems were obtained. Comparing these current functions with the simulated voltammograms for various other values of ${\alpha}$ (0.1 to 1.0) and ${\Lambda}\;(10^{-5}\;to\;10^5)$, the revised zones that are different from those proposed by Matsuda and Ayabe for the reversible and totally irreversible systems are proposed. For ${\alpha}{\ge}$0.1 the reversible zone is in ${\Lambda}{\ge}10^{1.7}$ and the totally irreversible zone is in ${\Lambda}{\le}10^{-1.7}$, where ${\Lambda}=k^{\circ}/ [D_o^{1-{\alpha}}D_R^{\alpha}(nF/RT)v]^{1/2}$.

Numerical Study on Oxygen Depletion Characteristics of Porous Cathodes in Anode-Supported Solid Oxide Fuel Cells (음극지지 고체산화물 연료전지 다공성 양극에서의 산소고갈 특성에 관한 수치해석 연구)

  • Shin, Dongwoo;Nam, Jin Hyun;Kim, Charn-Jung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.41 no.4
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    • pp.257-268
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    • 2017
  • This paper proposes an efficient two-dimensional simulation model for solid oxide fuel cells (SOFCs) based on the electrochemical effectiveness model. The effectiveness model is known to accurately predict the current generation performance of SOFC electrodes, by considering the complex reaction/transport processes that occur within thin active functional layers near the electrolyte. After validation tests, the two-dimensional simulation model was used to calculate the distribution of current density and oxygen concentration transverse to the flow channel in anode-supported SOFCs, with which the oxygen depletion characteristics were investigated in detail. In addition, simulations were also conducted to determine the minimum number of grids required in the transverse direction to efficiently obtain accurate results.